ethyl((1,1,1,3,3,3-hexafluoro-2-methylpropan-2-yl)oxy)zinc | 1016965-10-8

• 分子结构分类: 有机化合物 - 有机卤素化合物
• 英文名称: ethyl((1,1,1,3,3,3-hexafluoro-2-methylpropan-2-yl)oxy)zinc
• CAS: 1016965-10-8
• 化学式: C₆H₈F₆OZn
• 分子量: 275.509
• InChiKey: SKJHJXJWQOJCHM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.32
• 重原子数：
  14.0
• 可旋转键数：
  3.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.23
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  吡啶 、 ethyl((1,1,1,3,3,3-hexafluoro-2-methylpropan-2-yl)oxy)zinc 以 乙醚 为溶剂， 以88%的产率得到[EtZn(pyridine)(μ-OCMe(CF3)2)]2
  参考文献：
  名称：

  Synthesis of ethyl zinc fluoroalkoxide complexes and the crystal structure of [EtZn(py){μ-OCH(CF3)2}]2

  摘要：

  Fluorinated alkoxide complexes of zinc were synthesized for possible use as precursors to fluorine-doped ZnO films. Diethyl zinc reacted with fluorinated alcohols to form [EtZn(ORf)](n) (R-f = CH(CF3)(2), CMe2CF3, CMe(CF3)(2)) compounds. The [EtZn(ORf)](n) compounds reacted with excess pyridine to yield the pyridine adducts [EtZn(py)(mu-ORf)](2). The X-ray structure of [EtZn(py) {mu-OCH(CF3)(2)}](2) showed that it has virtual C-i symmetry. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.10.010
• 作为产物：
  描述：

  1,1,1,3,3,3-六氟-2-甲基-2-丙醇 、 diethylzinc 以 正己烷 为溶剂， 以80%的产率得到ethyl((1,1,1,3,3,3-hexafluoro-2-methylpropan-2-yl)oxy)zinc
  参考文献：
  名称：

  Synthesis of ethyl zinc fluoroalkoxide complexes and the crystal structure of [EtZn(py){μ-OCH(CF3)2}]2

  摘要：

  Fluorinated alkoxide complexes of zinc were synthesized for possible use as precursors to fluorine-doped ZnO films. Diethyl zinc reacted with fluorinated alcohols to form [EtZn(ORf)](n) (R-f = CH(CF3)(2), CMe2CF3, CMe(CF3)(2)) compounds. The [EtZn(ORf)](n) compounds reacted with excess pyridine to yield the pyridine adducts [EtZn(py)(mu-ORf)](2). The X-ray structure of [EtZn(py) {mu-OCH(CF3)(2)}](2) showed that it has virtual C-i symmetry. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.10.010