| 1021396-05-3

• CAS: 1021396-05-3
• 化学式: C₅₈H₁₀₈Cl₅LiN₂O₄Si₂Y₂
• 分子量: 1315.7
• InChiKey: GFRQUMLJTLSVSU-UHFFFAOYSA-I

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 trimethylsilylmethyllithium 以 正己烷 、 甲苯 为溶剂， 以56%的产率得到[Y(CH₂Si(CH₃)3)2((CH₃)2CH)2C₆H₃N(Si(CH(CH₃)2)3)(CH₂Si(CH₃)3Li(OC₄H₈)2)]
  参考文献：
  名称：

  Synthesis and characterization of yttrium complexes bearing a bulky arylamido ancillary ligand

  摘要：

  Reaction of anhydrous YCl3 with 1 equiv. of arylamido lithium 2,6-(Pr2C6H3NSiPr3Li)-Pr-i-Pr-i in THF gave an anionic mono-arylamido-ligated yttrium dichloride complex {[2,6-(Pr2C6H3NSiPr3)-Pr-i-Pr-i]YCl2(THF)}(2)[LiCl(THF)(2)] (1). Alkylation of 1 with 4 equiv. of LiCH2SiMe3 a. orded an anionic arylamido-ligated yttrium tris(alkyl) complex [2,6-(Pr2C6H3NSiPr3)-Pr-i-Pr-i]Y(CH2SiMe3)(3)Li(THF)(2) (2). Both complexes were characterized by NMR, elementary analysis, and X-ray structural determination. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.08.010
• 作为产物：
  描述：

  四氢呋喃 、 、 氯化钇 以 四氢呋喃 为溶剂， 以90%的产率得到
  参考文献：
  名称：

  Synthesis and characterization of yttrium complexes bearing a bulky arylamido ancillary ligand

  摘要：

  Reaction of anhydrous YCl3 with 1 equiv. of arylamido lithium 2,6-(Pr2C6H3NSiPr3Li)-Pr-i-Pr-i in THF gave an anionic mono-arylamido-ligated yttrium dichloride complex {[2,6-(Pr2C6H3NSiPr3)-Pr-i-Pr-i]YCl2(THF)}(2)[LiCl(THF)(2)] (1). Alkylation of 1 with 4 equiv. of LiCH2SiMe3 a. orded an anionic arylamido-ligated yttrium tris(alkyl) complex [2,6-(Pr2C6H3NSiPr3)-Pr-i-Pr-i]Y(CH2SiMe3)(3)Li(THF)(2) (2). Both complexes were characterized by NMR, elementary analysis, and X-ray structural determination. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.08.010