4,4'-dithiopyridine

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 4,4'-dithiopyridine
• 英文别名: 2-,4'-dipyridyl disulphide；2-(Pyridin-4-yldisulfanyl)pyridine
• 化学式: C₁₀H₈N₂S₂
• 分子量: 220.319
• InChiKey: OUPNLPSYWWWHRA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  76.4
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  二氯甲烷 、 苯甲酸铵 、 4,4'-dithiopyridine 、 copper(II) nitrate trihydrate 以 甲醇 为溶剂， 以29.7%的产率得到[[Cu2(O2CPh)4(μ-4,4'-dithiopyridine)]0.5(CH3OH)]n
  参考文献：
  名称：

  Catalytic transesterification reactions of one-dimensional coordination polymers containing paddle-wheel-type units connected by various bridging ligands

  摘要：

  The paddle-wheel dinuclear unit consists of two Cu-II ions bridged by four benzoate ligands, and these paddle-wheel [Cu-2(O2CPh)(4)] units are connected by various bridging ligands to form one-dimensional chained compounds formulated as [Cu-2(O2CPh)(4)(mu-L)] (L = 2,4-bpe (1), 3,3'-dipicam (3), 2,5-Me(2)pyz (4), pyz (5), 4,4'-bpy (6), and 4-pds (7)). The compound 2, formulated as [[Cu-2(O2CPh)(4)][Cu(O2CPh)(2)](mu-bpp)(2)], consists of alternating units of [Cu-2(O2CPh)(4)] and [Cu(O2CPh)(2)] connected by via bpp. Compounds 1-5 and 7 efficiently catalyzed the transesterification of a variety of esters, while it has been reported that Cu-containing complexes or coordination polymers do not usually show catalytic activities for the transesterification reactions. Among these compounds, 2 was most effective. It has been proposed that in the transesterification reaction, a mononuclear type of Cu complex might be the major species of compound 2 in solution, while for all other compounds, a paddle-wheel unit might be the major reactive species. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2013.03.043