acetic acid-(5-hydroxy-6β-methyl-5α-cholestanyl-(3β)-ester) | 14150-16-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 类固醇和类固醇衍生物
• 英文名称: acetic acid-(5-hydroxy-6β-methyl-5α-cholestanyl-(3β)-ester)
• 英文别名: (10R)-5t-Hydroxy-3c-acetoxy-6c.10r.13c-trimethyl-17c-((R)-1.5-dimethyl-hexyl)-(8cH.9tH.14tH)-hexadecahydro-1H-cyclopenta[a]phenanthren；Essigsaeure-(5-hydroxy-6β-methyl-5α-cholestanyl-(3β)-ester)；3β-Acetoxy-6β-methyl-5α-cholestanol-(5)；[(3S,5S,6R,8S,9S,10R,13R,14S,17R)-5-hydroxy-6,10,13-trimethyl-17-[(2R)-6-methylheptan-2-yl]-1,2,3,4,6,7,8,9,11,12,14,15,16,17-tetradecahydrocyclopenta[a]phenanthren-3-yl] acetate
• CAS: 14150-16-4
• 化学式: C₃₀H₅₂O₃
• 分子量: 460.741
• InChiKey: IGAULGJWIRWJIY-RRVKQOIUSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.9
• 重原子数：
  33
• 可旋转键数：
  7
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.97
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  acetic acid-(5-hydroxy-6β-methyl-5α-cholestanyl-(3β)-ester) 在 potassium hydrogensulfate 、 乙酸酐 作用下， 生成 3β-acetoxy-6-methylcholest-5-ene
  参考文献：
  名称：

  Julia,S.; Decouvelaere,B., Bulletin de la Societe Chimique de France, 1963, p. 2476 - 2480

  摘要：

  DOI：
• 作为产物：
  描述：

  cholesterol 在 过氧化氢苯甲酰 、 乙醚 、 氯仿 、 苯 作用下， 生成 acetic acid-(5-hydroxy-6β-methyl-5α-cholestanyl-(3β)-ester)
  参考文献：
  名称：

  Interlocking Directorates: An Example of Tacit Knowledge Transfer

  摘要：

  This paper illustrates tacit knowledge flows between American and Canadian metropolitan areas. Using the spatial distribution of interlocking in Canada and the United States a spatial component is added to the resource dependency paradigm. Using a poisson regression model. components of cities that initiate and attract interlocking, and thus knowledge transfer, can be identified. From the results, the authors propose the concept of a "knowledge threshold" essential for the transfer of tacit knowledge. In Canada the "knowledge threshold" encompasses the entire country while it is more regionally based in the United States.

  DOI：

  10.2747/0272-3638.23.2.154