(4-苄基苯基)-(4-氯苯基)甲酮 | 69677-65-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: (4-苄基苯基)-(4-氯苯基)甲酮
• 英文名称: 4-chloro-4'-benzyl benzophenone
• 英文别名: 4-chloro-4'-benzylbenzophenone；Benzophenone, 4-benzyl-4'-chloro-；(4-benzylphenyl)-(4-chlorophenyl)methanone
• CAS: 69677-65-2
• 化学式: C₂₀H₁₅ClO
• 分子量: 306.791
• InChiKey: ZRIPJJWYODJTLH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  22
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  4-chloro-4'-(chloromethyl)benzophenone 、 三苯基铋 在 四(三苯基膦)钯 、 sodium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 2.0h， 以83%的产率得到(4-苄基苯基)-(4-氯苯基)甲酮
  参考文献：
  名称：

  Threefold and chemoselective couplings of triarylbismuths with benzylic chlorides and iodides using palladium catalysis

  摘要：

  本文描述了对三芳基铋试剂与苄基氯和碘进行三重偶联的钯催化研究。经过优化的实验条件操作简单，使得多种三芳基铋与苄基氯和碘的三重偶联得以实现。这两种优化的实验方案使得不对称二芳基甲烷的合成变得高效。在本研究的过程中，还实现了苄基氯和碘的化学选择性转化。

  DOI：

  10.1039/c3ra46672h

文献信息

• ASYMMETRIC ORGANIC PEROXIDE, CROSSLINKING AGENT COMPRISING THE SAME, AND METHOD OF CROSSLINKING WITH THE SAME
  申请人：NOF CORPORATION

  公开号：EP1233014A1

  公开（公告）日：2002-08-21

  A crosslinking agent comprising an asymmetry organic peroxide having at least one structure unit of (substituted)benzoylcarbonyloxy group represented by the following formula (1) in the molecule thereof. Environmentally friendly crosslinking agents and crosslinked silicone rubber moldings are provided thereby. Specifically, useful crosslinking agents and crosslinking processes for silicone rubber are provided.

  一种交联剂，包括至少具有分子中表示为以下式（1）的（取代）苯甲酰羰氧基结构单元的不对称有机过氧化物。因此提供了环保的交联剂和交联硅橡胶成型品。具体提供了用于硅橡胶的有用交联剂和交联工艺。
• The Dual Role of Benzophenone in Visible-Light/Nickel Photoredox-Catalyzed C−H Arylations: Hydrogen-Atom Transfer and Energy Transfer
  作者：Abhishek Dewanji、Patricia E. Krach、Magnus Rueping

  DOI：10.1002/anie.201901327

  日期：2019.3.11

  A dual catalytic protocol for the direct arylation of non‐activated C(sp3)−H bonds has been developed. Upon photochemical excitation, the excited triplet state of a diaryl ketone photosensitizer abstracts a hydrogen atom from an aliphatic C−H bond. This inherent reactivity was exploited for the generation of benzylic radicals which subsequently enter a nickel catalytic cycle, accomplishing the benzylic

  已经开发了用于未活化的C（sp 3）-H键直接芳基化的双重催化方案。在光化学激发下，二芳基酮光敏剂的激发三重态从脂肪族CH键中提取氢原子。利用这种固有的反应性来产生苄基，其随后进入镍催化循环，从而完成苄基芳基化。
• Pd-catalyzed chemoselective threefold cross-coupling of triarylbismuths with benzylic bromides
  作者：Maddali L. N. Rao、Ritesh J. Dhanorkar

  DOI：10.1039/c3ra40413g

  日期：——

  for the chemoselective cross-coupling of functionalized benzylic bromides with triarylbismuth reagents. Under the established conditions, catalyzed by palladium in the presence of K3PO4 base in DMA at 90 °C for 1 h, the threefold arylations using triarylbismuth reagents proceeded smoothly with electronically diverse benzylic bromides. All the coupling reactions furnished the corresponding functionalized

  对于功能化的苄基溴化物与三芳基铋试剂的化学选择性交叉偶联，证​​明了一种有效的钯催化方案。在既定条件下，钯在DMA中在90°C下在DMA中存在K 3 PO 4碱的条件下催化1 h，使用三芳基铋试剂进行的三重芳基化反应可通过电子形式多样的苄基溴顺利进行。所有偶联反应均以高收率提供了相应的官能化二芳基甲烷。
• Curable composition
  申请人：——

  公开号：US20030166756A1

  公开（公告）日：2003-09-04

  The invention relates to a curable composition comprising a crosslinking silyl-containing vinyl polymer. The curable composition of the invention can be utilized, for example, as sealants such as elastic sealants for building and construction, electric or electronic part materials such as solar battery backside sealants, electric insulating materials such as insulating sheath of wire or cable, pressure sensitive adhesives, adhesives, and paints. A curable composition which comprises the following two components: (A) a vinyl polymer (I) having at least one crosslinking functional group and (B) heavy or ground calcium carbonate (II) having a specific surface area of not smaller than 1.5 m 2 /g but not larger than 50 m 2 /g.

  本发明涉及一种可固化组合物，其中包括交联硅基含有乙烯基的聚合物。该发明的可固化组合物可用作密封剂，例如用于建筑和构造的弹性密封剂，用作电子部件材料，如太阳能电池背面密封剂，用作绝缘材料，如电线或电缆的绝缘套等，还可用作压敏胶，粘合剂和涂料。该可固化组合物包括以下两个组分：（A）至少具有一个交联功能基团的乙烯基聚合物（I）和（B）重质或地面碳酸钙（II），其比表面积不小于1.5 m2/g但不大于50 m2/g。
• BIOFILM-INHIBITORY COATINGS THAT RELEASE SALICYCLIC ACID BY HYDROLISIS
  申请人：Hortelano Edwin R.

  公开号：US20110256187A1

  公开（公告）日：2011-10-20

  The present invention relates to coating compositions for modulating biofilm growth on a surface, the composition comprising the reaction product of: A) an ethylenically unsaturated compound, having at least one group with the following structure: and B) an ethylenically unsaturated compound.

  本发明涉及用于调节表面生物膜生长的涂层组合物，该组合物包括以下反应产物： A）具有至少一个具有以下结构的基团的乙烯不饱和化合物： B）乙烯不饱和化合物。