p-thiophenoxy thiophenol | 52872-99-8

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: p-thiophenoxy thiophenol
• 英文别名: 4-phenylthiobenzenethiol；4-phenylmercaptothiophenol；4-thiodiphenylsulfide；4-phenylsulfanyl-thiophenol；Benzenethiol, 4-(phenylthio)-；4-phenylsulfanylbenzenethiol
• CAS: 52872-99-8
• 化学式: C₁₂H₁₀S₂
• 分子量: 218.343
• InChiKey: FXUDFWSZQAEDCP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  26.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  p-thiophenoxy thiophenol 在 sodium hydroxide 、 氯仿 作用下， 生成 1-benzenesulfinyl-4-methanesulfinyl-benzene
  参考文献：
  名称：

  Leandri; Pallotti, Annali di Chimica, 1956, vol. 46, p. 1069,1074

  摘要：

  DOI：
• 作为产物：
  描述：

  4-溴茴香硫醚 在 吡啶 、 喹啉 、 copper(I) oxide 、 2-丙烷硫醇钠 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 生成 p-thiophenoxy thiophenol
  参考文献：
  名称：

  Functionalized p-phenylene sulfides Synthesis of new molecular wires

  摘要：

  Molecular wires containing p-phenylene sulfide units were synthesized. They could be used in material sciences and in supramolecular chemistry. Wires having 2 to 6 phenyl rings were functionalized at one end by an SH or Sh-le group, and at the other end, by an OH, OMe or OiPr groups. Formation of Ar-S bonds in the chain was achieved by Pd- or Cu-catalyzed couplings of aromatic thiols with aromatic halides. Conditions for a clean chemoselective deprotection of thiols from thiomethyl groups were developed. (C) 1998 Published by Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(97)10624-4

文献信息

• PHOTOACID GENERATOR, AND RESIN COMPOSITION FOR PHOTOLITHOGRAPHY
  申请人：SAN-APRO LTD.

  公开号：US20160368879A1

  公开（公告）日：2016-12-22

  Provided is a non-ionic photoacid generator (A) expressed by general formula (1). R1 and R2 each independently represents an alkyl group having 1-18 carbons or a fluoroalkyl group having 1-18 carbons, an alkenyl group having 2-18 carbons, an alkynyl group having 2-18 carbons, an aryl group having 6-18 carbons, a silyl group, or the like; m and n respectively represent the number of R1s and R2s, each number being an integer from 0 to 3, and the total number (m+n) of R1s and R2s being an integer from 1 to 6. The m number of R1s and the n number of R2s may each be the same or different. R3 represents a hydrocarbon having 1-18 carbons wherein one part or all of the hydrogen may be substituted by fluorine.

  提供的非离子光酸发生剂（A）由通式（1）表示。R1和R2分别独立表示具有1-18个碳原子的烷基基团或具有1-18个碳原子的氟烷基基团，具有2-18个碳原子的烯基基团，具有2-18个碳原子的炔基基团，具有6-18个碳原子的芳基基团，硅基团等；m和n分别表示R1和R2的数量，每个数字为0到3的整数，R1和R2的总数（m+n）为1到6的整数。R1的数量m和R2的数量n可以相同也可以不同。R3表示具有1-18个碳原子的碳氢化合物，其中氢的一部分或全部可以被氟取代。
• SULFONIUM SALT, HEAT- OR PHOTO-ACID GENERATOR, HEAT- OR PHOTO-CURABLE COMPOSITION, AND CURED PRODUCT THEREOF
  申请人：SAN APRO LTD.

  公开号：US20190284134A1

  公开（公告）日：2019-09-19

  The sulfonium salt does not contain a toxic metal and exhibits higher cationic polymerization performance and crosslinking performance than a tetrakis(pentafluorophenyl)borate salt. The heat- or photo-acid generator contains the sulfonium salt. The sulfonium salt is formed of a sulfonium cation selected from a group represented by general formulas (1), (9), (10) and (11) described below and a gallate anion represented by formula (a). The heat- or photo-acid generator contains the sulfonium salt. The heat- or energy ray-curable composition contains the acid generator and a cationically polymerizable compound. A cured product can be obtained by curing the same.

  硫铵盐不含有毒金属，表现出比四(五氟苯基)硼酸盐更高的阳离子聚合性能和交联性能。热或光酸发生剂含有硫铵盐。硫铵盐由下面描述的通用公式(1)、(9)、(10)和(11)所代表的一组硫铵阳离子和由公式(a)代表的镓酸根阴离子形成。热或光酸发生剂含有硫铵盐。热或能量射线固化组合物含有酸发生剂和阳离子聚合性化合物。通过固化可以获得固化产品。
• Synthesis and Properties of <i>s</i><i>ym</i>-Pentasubstituted Derivatives of Corannulene
  作者：Gunther H. Grube、Eric. L. Elliott、Ralph J. Steffens、Carissa S. Jones、Kim K. Baldridge、Jay S. Siegel

  DOI：10.1021/ol027565f

  日期：2003.3.1

  heteroatom derivatives of sym-pentasubstituted corannulenes have been synthesized from sym-pentachlorocorannulene. These units form potential building blocks for future work on superstructures based on corannulene. Absorption/emission properties follow expected trends from the parent 1. sym-Pentasubstitution gives rise to variations in the chemical dynamics of bowl inversion. van der Waals attraction

  由对五氯并戊烯基合成了对五取代的环戊烯基的烷基，芳基和炔基以及杂原子衍生物。这些单元构成了未来在基于Corannulene的上层建筑上开展工作的潜在基石。吸收/发射特性遵循母体1.的预期趋势。sym-Pentasubstitution引起碗倒置化学动力学的变化。范德华引力被用来解释10中碗倒置的异常高的障碍。
• SULFONIUM SALT, PHOTOACID GENERATOR, PHOTOCURABLE COMPOSITION, AND CURED PRODUCT THEREOF
  申请人：SAN-APRO LTD.

  公开号：US20190300476A1

  公开（公告）日：2019-10-03

  A sulfonium salt is formed of a sulfonium cation selected from a group indicated by general formulas (1), (2), and (3) and a gallate anion represented by formula (a). A photoacid generator is characterized in that said sulfonium salt is contained therein. An energy-ray curable composition contains the acid generator and a cationic polymerizable compound. A cured product is formed by curing these substances.

  一种磺胺盐由通式（1）、（2）和（3）所示的一组磺胺阳离子以及由式（a）表示的没食子酸根阴离子组成。一种光酸发生剂的特征在于其中含有该磺胺盐。一种能量射线固化组合物包含该酸发生剂和一个阳离子可聚合化合物。通过固化这些物质形成一个固化产物。
• SULFONATE COMPOUND, PHOTOACID GENERATOR, AND RESIN COMPOSITION FOR PHOTOLITHOGRAPHY
  申请人：SAN-APRO LIMITED

  公开号：US20170233336A1

  公开（公告）日：2017-08-17

  Provided are: a non-ionic photoacid generator containing a sulfonate compound having a high photosensitivity to i lines, exhibiting excellent heat-resistance stability, and exhibiting excellent solubility in a hydrophobic material; and a resin composition for photolithography containing the same. The present invention is a sulfonate compound characterized by being represented by general formula (1). [In formula (1), R1 represents an aryl group having 6 to 18 carbon atoms or a heterocyclic hydrocarbon group having 4 to 20 carbon atoms. R2 represents a hydrogen atom, an alkyl group having 1 to 18 carbon atoms, an alkenyl group having 2 to 18 carbon atoms, an alkynyl group having 2 to 18 carbon atoms, or an aryl group having 6 to 18 carbon atoms. R3 represents a hydrocarbon group having 1 to 18 carbon atoms (in which some or all hydrogen atoms may be substituted with fluorine).]

  提供的是：一种非离子光酸发生剂，含有对i线具有高光敏度的磺酸化合物，表现出优异的耐热稳定性，并在疏水材料中表现出优异的溶解性；以及含有该化合物的光刻树脂组合物。本发明是一种磺酸化合物，其特征在于由通式（1）表示。[在式（1）中，R1表示具有6至18个碳原子的芳基基团或具有4至20个碳原子的杂环烃基团。R2表示氢原子，具有1至18个碳原子的烷基基团，具有2至18个碳原子的烯基基团，具有2至18个碳原子的炔基基团或具有6至18个碳原子的芳基基团。R3表示具有1至18个碳原子的烃基团（其中一些或全部氢原子可以被氟代替）。]