三甲代烯丙基异氰酸酯 | 6291-95-8

• 物质功能分类: 有机原料 - 羧酸类化合物及衍生物
• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 中文名称: 三甲代烯丙基异氰酸酯
• 中文别名: 1,3,5-三(2-甲基-2-丙烯-1-基)-1,3,5-三嗪-2,4,6(1h,3h,5h)-三酮
• 英文名称: Trimethallylisocyanurat
• 英文别名: Trimethylallyl isocyanurate；1,3,5-tris(2-methylprop-2-enyl)-1,3,5-triazinane-2,4,6-trione
• CAS: 6291-95-8
• 化学式: C₁₅H₂₁N₃O₃
• mdl: MFCD00080659
• 分子量: 291.35
• InChiKey: MPJPKEMZYOAIRN-UHFFFAOYSA-N

物化性质

• 熔点：
  85-86 °C
• 沸点：
  402.7±44.0 °C(Predicted)
• 密度：
  1.097±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  21
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  60.9
• 氢给体数：
  0
• 氢受体数：
  3

安全信息

• 危险类别码：
  R20/21/22,R36/37/38
• 危险品运输编号：
  UN 2811
• 海关编码：
  2933699090
• 安全说明：
  S22,S26,S36/37/39

SDS

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Section 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE
Product identifiers
Product name : Triazine-2,4,6(1H,3H,5H)-trione, 1,3,5-tris(2-methyl-
2-propenyl)-
CAS-No. : 6291-95-8
Relevant identified uses of the substance or mixture and uses advised against
Identified uses : Laboratory chemicals, Manufacture of substances

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Section 2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]
Acute toxicity, Oral (Category 4)
Acute toxicity, Inhalation (Category 4)
Classification according to EU Directives 67/548/EEC or 1999/45/EC
Harmful by inhalation, in contact with skin and if swallowed.
Label elements
Labelling according Regulation (EC) No 1272/2008 [CLP]
Pictogram
Signal word Warning
Hazard statement(s)
H302 Harmful if swallowed.
H332 Harmful if inhaled.
Precautionary statement(s) none
Supplemental Hazard none
Statements
According to European Directive 67/548/EEC as amended.
Hazard symbol(s)
R-phrase(s)
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
S-phrase(s)
S36/37 Wear suitable protective clothing and gloves.
Other hazards - none

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Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substances
Formula : C15H21N3O3
Molecular Weight : 291,35 g/mol
Component Concentration
Triazine-2,4,6(1H,3H,5H)-trione, 1,3,5-tris(2-methyl-2-propenyl)-
CAS-No. 6291-95-8 -

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Section 4. FIRST AID MEASURES
Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Most important symptoms and effects, both acute and delayed
To the best of our knowledge, the chemical, physical, and toxicological properties have not been
thoroughly investigated.
Indication of any immediate medical attention and special treatment needed
no data available

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Section 5. FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Carbon oxides, nitrogen oxides (NOx)
Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
Further information
no data available

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Section 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure
adequate ventilation. Avoid breathing dust.
Environmental precautions
Do not let product enter drains.
Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed
containers for disposal.
Reference to other sections
For disposal see section 13.

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Section 7. HANDLING AND STORAGE
Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols.
Provide appropriate exhaust ventilation at places where dust is formed.
Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
Specific end uses
no data available

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Section 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Components with workplace control parameters
Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday.
Personal protective equipment
Eye/face protection
Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested
and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
the standard EN 374 derived from it.
Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected
according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher
level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges.
Use respirators and components tested and approved under appropriate government standards
such as NIOSH (US) or CEN (EU).

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Section 9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
a) Appearance Form: solid
b) Odour no data available
c) Odour Threshold no data available
d) pH no data available
e) Melting point/freezing no data available
point
f) Initial boiling point and no data available
boiling range
g) Flash point no data available
h) Evaporation rate no data available
i) Flammability (solid, gas) no data available
j) Upper/lower no data available
flammability or
explosive limits
k) Vapour pressure no data available
l) Vapour density no data available
m) Relative density no data available
n) Water solubility no data available
o) Partition coefficient: n- no data available
octanol/water
p) Autoignition no data available
temperature
q) Decomposition no data available
temperature
r) Viscosity no data available
s) Explosive properties no data available
t) Oxidizing properties no data available
Other safety information
no data available

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Section 10. STABILITY AND REACTIVITY
Reactivity
no data available
Chemical stability
no data available
Possibility of hazardous reactions
no data available
Conditions to avoid
no data available
Incompatible materials
Strong oxidizing agents
Hazardous decomposition products
Other decomposition products - no data available

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Section 11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity
no data available
Inhalation: no data available
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
no data available
Specific target organ toxicity - single exposure
no data available
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Potential health effects
Inhalation
Harmful if inhaled. May cause respiratory tract irritation.
Ingestion Harmful if swallowed.
Skin May be harmful if absorbed through skin. May cause skin irritation.
Eyes May cause eye irritation.
Signs and Symptoms of Exposure
To the best of our knowledge, the chemical, physical, and toxicological properties have not been
thoroughly investigated.
Additional Information
RTECS: Not available

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Section 12. ECOLOGICAL INFORMATION
Toxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
Results of PBT and vPvB assessment
no data available
Other adverse effects
no data available

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Section 13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material
with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.

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Section 14. TRANSPORT INFORMATION
UN number
ADR/RID: 2811 IMDG: 2811 IATA: 2811
UN proper shipping name
ADR/RID: TOXIC SOLID, ORGANIC, N.O.S. (Triazine-2,4,6(1H,3H,5H)-trione, 1,3,5-tris(2-methyl-2-
propenyl)-)
IMDG: TOXIC SOLID, ORGANIC, N.O.S. (Triazine-2,4,6(1H,3H,5H)-trione, 1,3,5-tris(2-methyl-2-
propenyl)-)
IATA: Toxic solid, organic, n.o.s. (Triazine-2,4,6(1H,3H,5H)-trione, 1,3,5-tris(2-methyl-2-propenyl)-)
Transport hazard class(es)
ADR/RID: 6.1 IMDG: 6.1 IATA: 6.1
Packaging group
ADR/RID: III IMDG: III IATA: III
Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
Special precautions for user
no data available

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Section 15. REGULATORY INFORMATION
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
Safety, health and environmental regulations/legislation specific for the substance or mixture
no data available
Chemical Safety Assessment
no data available

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Section 16. OTHER INFORMATION
Further information
Copyright 2012 Co. LLC. License granted to make unlimited paper copies for internal use
only.
The above information is believed to be correct but does not purport to be all inclusive and shall be
used only as a guide. The information in this document is based on the present state of our knowledge
and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Corporation and its Affiliates shall not be held
liable for any damage resulting from handling or from contact with the above product. See
and/or the reverse side of invoice or packing slip for additional terms and conditions of sale.

反应信息

• 作为反应物：
  描述：

  三甲代烯丙基异氰酸酯 在 间氯过氧苯甲酸 作用下， 以 二氯甲烷 为溶剂， 反应 4.0h， 以135.7 g的产率得到1-allyl-3,5-bis(2-methylglycidyl)isocyanurate
  参考文献：
  名称：

  Photosensitive resin composition for color filter and uses thereof

  摘要：

  本发明涉及一种用于彩色滤光片的感光树脂组合物及其用途。该感光树脂组合物包括碱溶性树脂（A）、含有乙烯基不饱和基团的化合物（B）、光引发剂（C）、颜料（D）和有机溶剂（E）。根据本发明的感光树脂组合物可以提高图案的线性度，具有高精细度和彩色滤光片的耐显影性。

  公开号：

  US09568823B2
• 作为产物：
  描述：

  tri(methylallyl)cyanurate 在 CuCl₂*2H₂O 作用下， 以 甲苯 为溶剂， 以76.7%的产率得到三甲代烯丙基异氰酸酯
  参考文献：
  名称：

  Klenovich; Pashkina; Likhterov, Journal of applied chemistry of the USSR, 1987, vol. 60, # 3 pt 2, p. 621 - 623

  摘要：

  DOI：

文献信息

• COMPOUNDS HAVING A STABILIZING EFFECT, METHOD FOR PRODUCING SAID COMPOUNDS, COMPOSITION CONTAINING SAID STABILIZING COMPOUNDS, METHOD FOR STABILIZING AN ORGANIC COMPONENT, AND USE OF STABILIZING COMPOUNDS
  申请人：FRAUNHOFER-GESELLSCHAFT ZUR FÖRDERUNG DER ANGEWANDTEN FORSCHUNG E. V.

  公开号：US20200361879A1

  公开（公告）日：2020-11-19

  The invention relates to compounds of a new type which have a stabilizing effect and in particular provide stabilization with respect to oxidative thermal and/or actinic decomposition of or damage to organic materials. The compounds are represented by general formula I specified below. The invention further relates to a method for producing such compounds, to compositions containing said compound, to a method for stabilizing organic compounds by means of the stabilizing compounds, and to the use of the stabilizing compounds to stabilize organic materials.

  该发明涉及一种新型化合物，具有稳定作用，特别是在有机材料受氧化热解和/或光化学分解或损伤方面提供稳定作用。该化合物由下面指定的一般式I表示。该发明还涉及一种制备这种化合物的方法，含有该化合物的组合物，通过稳定化合物稳定有机化合物的方法，以及使用稳定化合物稳定有机材料的用途。
• CROSS-LINKING AGENT FOR CROSS-LINKABLE ELASTOMERS AND APPLICATION THEREOF
  申请人：Yamaura Mabuko

  公开号：US20130053520A1

  公开（公告）日：2013-02-28

  The object of the present invention to provide a cross-linking agent for a cross-linkable elastomer which is excellent in the heat resistance and rapid in the cross-linking rate in comparison with triallyl isocyanurate (TAIC). The present invention relates to a cross-linking agent for a cross-linkable elastomer comprising a triazine derivative represented by the general formula (I) or prepolymer thereof. (In the formula (I), at least two of X, Y and Z are each independently a diallylamino group, a mono-allyl amino group or allyl-methylamino group, and the rest is a hydrogen atom or a hydrocarbon group which may be substituted.)

  本发明的目的是提供一种用于可交联弹性体的交联剂，与三烯基异氰酸酯（TAIC）相比，在耐热性和交联速率方面均具有优异的性能。本发明涉及一种交联剂，其包括由通式（I）表示的三嗪衍生物或其预聚物。（在式（I）中，至少有两个X、Y和Z中的每一个独立地是二烯丙氨基基团、单烯丙氨基基团或烯丙基甲基氨基基团，其余的是氢原子或可能被取代的碳氢基团。）
• TRIAZINE DERIVATIVES AND APPLICATION THEREOF
  申请人：Yamaura Mabuko

  公开号：US20130023629A1

  公开（公告）日：2013-01-24

  The object of the present invention is to provide a novel triazine derivative which is excellent in the heat resistance and rapid in the cross-linking rate, and can be suitably used as a crosslinking agent. The present invention relates to a triazine derivative represented by the general formula (I). (In the formula (I), Y and X are each independently, represents a diallylamino group, mono-allylamino group, allyloxy group or methallyloxy group; and Z represents an allyloxy group or methallyloxy group)

  本发明的目的是提供一种新型的三嗪衍生物，其具有良好的耐热性和快速的交联速率，并可适当用作交联剂。本发明涉及一种由通式（I）表示的三嗪衍生物。（在式（I）中，Y和X分别独立地表示二烯基氨基，单烯基氨基，烯丙氧基或甲基烯丙氧基；Z表示烯丙氧基或甲基烯丙氧基）
• CROSS-LINKING AGENT FOR CROSS-LINKABLE ELASTOMER AND APPLICATION THEREOF
  申请人：Yamaura Mabuko

  公开号：US20130041111A1

  公开（公告）日：2013-02-14

  The object of the present invention is to provide a cross-linking agent for a cross-linkable elastomer which is rapid in the cross-linking rate in comparison with triallyl isocyanurate (TAIC). The present invention relates to a cross-linking agent for a cross-linkable elastomer comprising a bis-isocyanurate derivative represented by the general formula (I). (In the formula, X represents the C1 to C12 alkenylene group or C1 to C12 alkylene group, which may contain a carbonyl group, an ether bond or an ester bond in the main chain, and further a substituent in the side chain; at least two of Y 1 , Y 2 , Y 3 and Y 4 are each independently an allyl group which may be substituted, and the rest is a hydrogen atom or a hydrocarbon group which may be substituted.)

  本发明的目的是提供一种用于可交联弹性体的交联剂，其交联速率与三异氰酸三烯丙酯（TAIC）相比更快。本发明涉及一种交联剂，其包括由通式（I）表示的双异氰酸酯衍生物，用于可交联弹性体。（在公式中，X代表C1到C12的烯基或C1到C12的烷基，可能在主链中含有羰基、醚键或酯键，并且在侧链中进一步含有取代基；Y1、Y2、Y3和Y4中至少有两个是各自独立的烯丙基，可以被取代，其余是氢原子或可以被取代的碳氢基。）
• Peroxide-curable brominated or iodinated fluoroelastomer composition containing an N,N,N',N'-tetrasubstituted 1,8-diaminonaphthalene
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0187893A2

  公开（公告）日：1986-07-23

  A peroxide-curable fluoroelastomer composition which comprises a fluoroelastomer whose interpolymerized units consist essentially of units derived from vinylidene fluoride, units derived from at least one other fluorine-containing monomer copolymerizable therewith, said monomer being a compound which contains 2-7 carbon atoms, contains no bromine atoms or iodine atoms, and contains at least as many fluorine atoms as carbon atoms, and said fluoroelastomer contains up to 3 mole percent of units derived from a bromine-containing olefin or 0.1-2 mole percent of units derived from an iodine-containing olefin, and from about 0.05-2 parts per 100 parts fluoroelastomer of an N,N,N',N'- tetra-substituted 1,8-diaminonaphthalene having the formula: wherein Ri, R2, R3 and R4 are independently alkyl groups of 1-6 carbon atoms, phenyl or benzyl, R1 and R2 and/or R3 and R4 can be joined to form a 5- or 6-membered heterocyclic ring in which a carbon atom can be replaced by an oxygen or a sulfur atom, R, and R3 and/or R2 and R4 can be joined to form a heterocyclic ring of 6-20 carbon atoms in which a carbon atom can be replaced by an oxygen or a sulfur atom, X and Y are independently an alkyl group or an alkoxy group containing 1-4 carbon atoms and n is 0-3.

  一种过氧化物固化型氟弹性体组合物，它包含一种氟弹性体，其互聚单元主要由衍生自偏氟乙烯的单元、衍生自至少一种可与之共聚的其他含氟单体的单元组成，所述单体是一种含有 2-7 个碳原子的化合物，不含溴原子或碘原子，且含有至少与碳原子数量相同的氟原子，所述氟弹性体含有高达 3 摩尔%的衍生自含溴烯烃的单元或 0.每 100 份氟弹性体中含有约 0.05-2 份 N,N,N',N'-四取代的 1,8-二氨基萘，其式如下： 其中 Ri、R2、R3 和 R4 独立地为 1-6 个碳原子的烷基、苯基或苄基，R1 和 R2 和/或 R3 和 R4 可连接形成 5 或 6 元杂环，其中一个碳原子可被氧原子或硫原子取代，R、和 R3 和/或 R2 和 R4 可连接形成 6-20 个碳原子的杂环，其中一个碳原子可被氧原子或硫原子取代，X 和 Y 独立地为含 1-4 个碳原子的烷基或烷氧基，n 为 0-3。