N,N'-bis-(2,2,6,6-tetramethylpiperidin-4-yl)-N,N'-bis-{2,4-bis-{n-butyl-(2,2,6,6-tetramethylpiperidin-4-yl)amino}-[1,3,5]triazin-6-yl}hexane-1,6-diamine | 210988-99-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N'-bis-(2,2,6,6-tetramethylpiperidin-4-yl)-N,N'-bis-{2,4-bis-{n-butyl-(2,2,6,6-tetramethylpiperidin-4-yl)amino}-[1,3,5]triazin-6-yl}hexane-1,6-diamine
• 英文别名: N2,N2'-(Hexane-1,6-diyl)bis(N4,N6-dibutyl-N2,N4,N6-tris(2,2,6,6-tetramethylpiperidin-4-yl)-1,3,5-triazine-2,4,6-triamine)；2-N-[6-[[4,6-bis[butyl-(2,2,6,6-tetramethylpiperidin-4-yl)amino]-1,3,5-triazin-2-yl]-(2,2,6,6-tetramethylpiperidin-4-yl)amino]hexyl]-4-N,6-N-dibutyl-2-N,4-N,6-N-tris(2,2,6,6-tetramethylpiperidin-4-yl)-1,3,5-triazine-2,4,6-triamine
• CAS: 210988-99-1
• 化学式: C₈₂H₁₅₆N₁₈
• 分子量: 1394.26
• InChiKey: PQFLQZYVHUGIJP-UHFFFAOYSA-N

物化性质

• 密度：
  1.091g/cm3 at 20℃
• LogP：
  5.5 at 20℃ and pH6.6

计算性质

• 辛醇/水分配系数(LogP)：
  17.1
• 重原子数：
  100
• 可旋转键数：
  31
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.93
• 拓扑面积：
  169
• 氢给体数：
  6
• 氢受体数：
  18

反应信息

• 作为反应物：
  描述：

  N,N'-bis-(2,2,6,6-tetramethylpiperidin-4-yl)-N,N'-bis-{2,4-bis-{n-butyl-(2,2,6,6-tetramethylpiperidin-4-yl)amino}-[1,3,5]triazin-6-yl}hexane-1,6-diamine 在 sodium tungstate (VI) dihydrate 、 双氧水 、 苄基三甲基氯化铵 、 溶剂黄146 、 乙醛 、 copper(l) chloride 作用下， 以 水 、 甲苯 为溶剂， 生成 N,N'-bis-(2,2,6,6-tetramethyl-1-methoxypiperidin-4-yl)-N,N'-bis-{2,4-bis-{n-butyl-(2,2,6,6-tetramethyl-1-methoxypiperidin-4-yl)amino}-[1,3,5]triazin-6-yl}-hexane-1,6-diamine
  参考文献：
  名称：

  [EN] STERICALLY HINDERED AMINE STABILIZER
  [FR] AGENT STABILISANT AMINÉ STÉRIQUEMENT ENCOMBRÉ

  摘要：

  本发明涉及具有以下式I或II的含氧受位阻胺类化合物：(II)，其中，例如，F2、R3、R5、R6、R8、R9、R11、R12、R13、R14为正丁基；Z1至Z10为丙氧基，R1、R4、R7、R10、R13为2,2,6,6-四甲基-1-丙氧基-哌啶-4-基。还公开了包含具有式I或II的化合物和易于氧化、热降解或光诱导降解的有机材料的组合物。可选地，还包含进一步添加剂。

  公开号：

  WO2011029744A1
• 作为产物：
  描述：

  三聚氯氰 、 N,N’-双-(2,2,6,6-四甲基-4-哌啶基)1,6-己二胺 、 N-丁基-2,2,6,6-四甲基-4-哌啶胺 在 sodium hydroxide 作用下， 以 水 、 甲苯 为溶剂， 反应 1.0h， 以69%的产率得到N,N'-bis-(2,2,6,6-tetramethylpiperidin-4-yl)-N,N'-bis-{2,4-bis-{n-butyl-(2,2,6,6-tetramethylpiperidin-4-yl)amino}-[1,3,5]triazin-6-yl}hexane-1,6-diamine
  参考文献：
  名称：

  [EN] STERICALLY HINDERED AMINE STABILIZER
  [FR] AGENT STABILISANT AMINÉ STÉRIQUEMENT ENCOMBRÉ

  摘要：

  本发明涉及具有以下式I或II的含氧受位阻胺类化合物：(II)，其中，例如，F2、R3、R5、R6、R8、R9、R11、R12、R13、R14为正丁基；Z1至Z10为丙氧基，R1、R4、R7、R10、R13为2,2,6,6-四甲基-1-丙氧基-哌啶-4-基。还公开了包含具有式I或II的化合物和易于氧化、热降解或光诱导降解的有机材料的组合物。可选地，还包含进一步添加剂。

  公开号：

  WO2011029744A1

文献信息

• Coordination-polymeric triethanolamineperchlorato(triflato)metal inner complexes as additives for synthetic polymers
  申请人：Wehner Wolfgang

  公开号：US20090105387A1

  公开（公告）日：2009-04-23

  Stabilizer system for chlorinated polymers, especially PVC, comprising at least one coordination-polymeric triethanolamineperchlorato(triflato)metal inner complex comprising the monomer unit of the formula (A) The stabilizer system may additionally comprise substituted cyanoacetylureas or/and 6-aminouracils or/and 3-aminocrotonic esters or/and hydantoins or/and monomeric or polymeric dihydropyridines or alkaline earth metal hydroxides or/and hydrotalcites or/and dawsonites or/and zeolites or/and glycidyl compounds or/and cyanamides or/and cyanoguanidines or/and melamines. In addition, phosphites or/and sterically hindered amines or/and NOR-HALS compounds may be present.

  氯化聚合物的稳定剂体系，特别是PVC，包括至少一种配位聚合三乙醇胺高氯酸盐（三氟乙酸盐）金属内部络合物，该络合物包括式（A）的单体单位。稳定剂系统还可以包括取代的氰乙酰脲或/和6-氨基尿嘧啶或/和3-氨基巴豆酸酯或/和恒化酮或/和单体或聚合二氢吡啶或碱土金属氢氧化物或/和水滑石或/和道森石或/和沸石或/和环氧丙烷化合物或/和氰胺或/和氰基脲或/和三聚氰胺。此外，磷酸酯或/和立体阻隔胺或/和NOR-HALS化合物也可能存在。
• STERICALLY HINDERED AMINE STABILIZER
  申请人：Menozzi Edoardo

  公开号：US20120232197A1

  公开（公告）日：2012-09-13

  The present invention relates to oxygen-substituted sterically hindered amines of the formulae I or II: (II), wherein, for example, F 2 , R 3 , R 5 , R 6 , R 8 , R 9 , R 11 , R 12 , R 13 , R 14 are n-butyl; Z 1 to Z 10 are propoxy and R 1 , R 4 , R 7 , R 10 , R 13 are 2,2,6,6-tetramethyl-1-propoxy-piperidin-4-yl. Compositions comprising compounds of formulae I or II and an organic material, which is susceptible to oxidative, thermal or light-induced degradation, are further disclosed. Optionally, further additives are contained.

  本发明涉及公式I或II的含氧立体阻碍胺化合物：（II），其中，例如，F2，R3，R5，R6，R8，R9，R11，R12，R13，R14为正丁基；Z1至Z10为丙氧基，而R1，R4，R7，R10，R13为2,2,6,6-四甲基-1-丙氧基哌啶-4-基。此外，还公开了包含公式I或II化合物和易于氧化、热降解或光诱导降解的有机材料的组合物。可选地，还包含其他添加剂。
• Stabilizer System for Halogenated Polymers
  申请人：Wehner Wolfgang

  公开号：US20090306257A1

  公开（公告）日：2009-12-10

  The stabilizer system for chlorine-containing polymers, in particular PVC, comprises at least one linear or cyclic acylureide (A-1) and/or a polyaminocrotonic ester (A-2) and a polyepoxypropyl alcohol ether (B-1) and/or a cyanamide (derivative) (B-2). The stabilizer system may additionally comprise a sterically hindered amine (D) or a tertiary ethanolamine (E) and/or a perchlorate (C-1), perfluoroalkanesulfonate (C-2) and/or sulfate ester (C-3) salt. A typical example is a combination of N,N′-dimethyl-6-iminobarbituric acid as component (A-1), trisepoxypropylglycerol as component (B-1) or dicyandiamide as component (B-2). This combination additionally comprises sodium or potassium perchlorate as component (C-1). Further variants of the invention are the preparation of the stabilizer system, polymer compositions comprising the stabilizer system and utility articles thereof, such as window profiles or wire sheaths.
• POLYURETHANE FOAM OR POLYETHER POLYOL STABILIZED WITH A BENZOFURANONE-PHOSPHITE DERIVATIVE
  申请人：BASF SE

  公开号：US20210246256A1

  公开（公告）日：2021-08-12

  The invention relates to a composition, which comprises the components (a) a polyurethane foam or a polyether polyol; and (b) a compound of formula (I) wherein R 1 is H or C 1 -alkyl. A process for manufacturing the aforementioned composition, the use of a component (b) for stabilizing component (a) against degradation and a specific additive mixture comprising component (b) and as component (c) a first further additive, which is a specific aromatic amine, are described.
• US8895647B2
  申请人：——

  公开号：US8895647B2

  公开（公告）日：2014-11-25