1,3-二癸基硫脲 | 7614-64-4

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫脲类
• 中文名称: 1,3-二癸基硫脲
• 英文名称: N,N'-di-n-decylthiourea
• 英文别名: N,N'-Didecyl-thioharnstoff；N,N'-didecylthiourea；Thiourea, N,N'-didecyl-；1,3-didecylthiourea
• CAS: 7614-64-4
• 化学式: C₂₁H₄₄N₂S
• 分子量: 356.66
• InChiKey: KVPJJDWEFYTGMD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9
• 重原子数：
  24
• 可旋转键数：
  18
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.95
• 拓扑面积：
  56.2
• 氢给体数：
  2
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1,3-二癸基硫脲 、 2-溴乙胺氢溴酸盐 以 乙醇 为溶剂， 生成
  参考文献：
  名称：

  抗辐射化合物VII

  摘要：

  假设2-甲基巯基乙基胍（MEG）的单-N-烷基和N，N'-二烷基衍生物已被合成为潜在的辐射防护剂，并假设增加了MEG的脂溶性将改善其辐射防护能力。通过使溴乙胺与适当的烷基化的硫脲反应，得到相应的氨基乙基异硫脲溴化氢溴酸盐，将其在碱性溶液中重排为所需的MEG衍生物，从而获得化合物。与MEGBr本身不同，烷基MEG氢溴酸盐可从水溶液中分离出来。转化为三硫代碳酸酯通常得到具有更好的结晶性质的产物。NMR分析证实了MEG的三硫代碳酸酯的结构。

  DOI：

  10.1002/jps.2600540413
• 作为产物：
  描述：

  二硫化碳 、 十二烷基伯胺 生成 1,3-二癸基硫脲
  参考文献：
  名称：

  抗辐射化合物VII

  摘要：

  假设2-甲基巯基乙基胍（MEG）的单-N-烷基和N，N'-二烷基衍生物已被合成为潜在的辐射防护剂，并假设增加了MEG的脂溶性将改善其辐射防护能力。通过使溴乙胺与适当的烷基化的硫脲反应，得到相应的氨基乙基异硫脲溴化氢溴酸盐，将其在碱性溶液中重排为所需的MEG衍生物，从而获得化合物。与MEGBr本身不同，烷基MEG氢溴酸盐可从水溶液中分离出来。转化为三硫代碳酸酯通常得到具有更好的结晶性质的产物。NMR分析证实了MEG的三硫代碳酸酯的结构。

  DOI：

  10.1002/jps.2600540413

文献信息

• FUNCTIONALIZED HIGHLY BRANCHED MELAMINE-POLYAMINE POLYMERS
  申请人：Peretolchin Maxim

  公开号：US20120252987A1

  公开（公告）日：2012-10-04

  The present invention relates to a method for producing amphiphilic functionalized highly branched melamine-polyamine polymers by condensing melamine and optionally a melamine derivate having at least one different amine having at least two primary amino groups and optionally also with urea and/or at least one urea derivative and/or with at least one at least difunctional diisocyanate or polyisocyanate and/or at least one carbolic acid having at least two carboxyl groups or at least one derivative thereof, optionally quaternizing a portion of the amino groups of the polymer thereby obtained, reacting the polymer thus obtained with at least one compound capable of undergoing a condensation or addition reaction with amino groups, and optionally quaternizing at least part of the amino groups of the polymer obtained in the first step. The invention further relates to the amphiphilic functionalized highly branched melamine-polyamine polymers that can be obtained by the method according to the invention, and to the use thereof as surface active agents.

  本发明涉及一种通过将三聚氰胺和至少一种具有至少两个主要氨基的不同氨基的三聚氰胺衍生物以及可能还包括尿素和/或至少一种尿素衍生物和/或至少一种至少双官能团二异氰酸酯或多异氰酸酯和/或至少一种至少具有两个羧基的羧酸或其衍生物缩合，从而制备含有两性功能化的高支化三聚氰胺-多胺聚合物的方法。可选地，对所获得的聚合物的部分氨基进行季铵化，然后将所获得的聚合物与至少一种能够与氨基发生缩合或加成反应的化合物反应，并可选地对第一步中获得的聚合物的部分氨基进行季铵化。本发明还涉及通过本发明的方法可以获得的含有两性功能化的高支化三聚氰胺-多胺聚合物，以及将其用作表面活性剂的用途。
• [3-substituted-2-(substituted imino)-4-oxo-5-thiazolidinylidene]acetic
  申请人：Warner-Lambert Company

  公开号：US04775677A1

  公开（公告）日：1988-10-04

  The present invention provides novel [3-substituted-2-(substituted imino)-4-oxo-5-thiazolidinylidene]acetic acids, and novel pharmaceutical compositions and methods of use thereof. The novel acids of the invention are leukotriene antagonists having activity useful for treating asthma, allergies, cardiovascular diseases, migraines, and inflammation.

  本发明提供了新颖的[3-取代-2-(取代亚胺)-4-氧代-5-噻唑烯基]乙酸，以及新颖的药物组合物和使用方法。该发明的新颖酸是白三烯拮抗剂，具有用于治疗哮喘、过敏、心血管疾病、偏头痛和炎症的活性。
• INHIBITOR COMPOSITION FOR RACKS WHEN USING CHROME FREE ETCHES IN A PLATING ON PLASTICS PROCESS
  申请人：ENTHONE, INCORPORATED

  公开号：EP3059277A1

  公开（公告）日：2016-08-24

  The invention relates to an aqueous inhibition composition for the inhibition of electrochemical metal plating on polymer surfaces, said inhibition composition comprising an inhibition agent selected from the group of compounds having at least one sulfur and at least one nitrogen atom as well as to a method for the inhibition of an insulated surface of a rack area. The inventive inhibition composition is capable to provide a solution for prohibiting unintended metallization on insulated areas of the racks when non-chromic etching is utilized for plating on plastics processes.

  本发明涉及一种用于抑制聚合物表面电化学金属电镀的水性抑制组合物，所述抑制组合物包含一种选自至少有一个硫原子和至少有一个氮原子的化合物组的抑制剂，还涉及一种抑制机架绝缘表面的方法。本发明的抑制剂组合物能够提供一种解决方案，当在塑料电镀工艺中使用非变色蚀刻法时，禁止在机架的绝缘区域出现意外金属化。
• Functionalized highly branched melamine-polyamine polymers
  申请人：Peretolchin Maxim

  公开号：US10077336B2

  公开（公告）日：2018-09-18

  The present invention relates to a method for producing amphiphilic functionalized highly branched melamine-polyamine polymers by condensing melamine and optionally a melamine derivate having at least one different amine having at least two primary amino groups and optionally also with urea and/or at least one urea derivative and/or with at least one at least difunctional diisocyanate or polyisocyanate and/or at least one carbolic acid having at least two carboxyl groups or at least one derivative thereof, optionally quaternizing a portion of the amino groups of the polymer thereby obtained, reacting the polymer thus obtained with at least one compound capable of undergoing a condensation or addition reaction with amino groups, and optionally quaternizing at least part of the amino groups of the polymer obtained in the first step. The invention further relates to the amphiphilic functionalized highly branched melamine-polyamine polymers that can be obtained by the method according to the invention, and to the use thereof as surface active agents.

  本发明涉及一种生产两亲官能化高支化三聚氰胺-聚胺聚合物的方法，该方法通过缩合三聚氰胺和可选的三聚氰胺衍生物，该三聚氰胺衍生物具有至少一种不同的胺，该胺具有至少两个伯氨基，并且可选地还与尿素和/或至少一种尿素衍生物和/或与至少一种至少双官能度的二异氰酸酯或多异氰酸酯和/或至少一种具有至少两个羧基的石碳酸或其至少一种衍生物缩合、将由此得到的聚合物的部分氨基进行季铵化，将由此得到的聚合物与至少一种能与氨基发生缩合或加成反应的化合物反应，并将第一步中得到的聚合物的至少部分氨基进行季铵化。本发明还涉及通过本发明方法可获得的两亲官能化高支化三聚氰胺-聚胺聚合物，以及将其用作表面活性剂。
• Two-component initiator system (amine-free) with very good storage stability and particular suitability for acid systems
  申请人：Utterodt Andreas

  公开号：US20070040151A1

  公开（公告）日：2007-02-22

  A two-component initiator system having accelerators for curing polymerizable materials comprising the following components: (a) a hydroperoxide compound containing one or more hydroperoxide groups that are bound to a tertiary carbon; (b) a thiourea derivative; and (c) as accelerator, a copper compound which is soluble in the preparation is preferably free of amine and is particularly suited for polymerizable dental compositions.