(E)-benzylidenemethanamine | 5694-20-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (E)-benzylidenemethanamine
• 英文别名: cis-Cinnamylamin；(Z)-2-phenylethenamine
• CAS: 5694-20-2；83148-11-2
• 化学式: C₈H₉N
• 分子量: 119.166
• InChiKey: UWRZIZXBOLBCON-SREVYHEPSA-N

物化性质

• 沸点：
  221.3±19.0 °C(Predicted)
• 密度：
  1.013±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  9
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

安全信息

• 海关编码：
  2933990090

反应信息

• 作为反应物：
  描述：

  (E)-benzylidenemethanamine 、 高邻苯二甲酸酐 在 四氯化钛 、 N,N-二异丙基乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 0.41h， 以65%的产率得到(3S*,4S*)-2-methyl-1-oxo-3-phenyl-1,2,3,4-tetrahydroisoquinoline-4-carboxylic acid
  参考文献：
  名称：

  高邻苯二甲酸酐与亚胺之间反应的反式立体选择性。

  摘要：

  在TiCl4和二异丙基乙胺存在下，高邻苯二甲酸酐与亚胺之间的反应是反式选择性的。在这些条件下，使用高手性亚胺的反应可以是高度非对映选择性的，因此可以合成对映体纯的1,2,3,4-四氢-1-氧代喹啉-4-羧酸。

  DOI：

  10.1021/ol801757r

文献信息

• FUNGICIDAL OXADIAZOLES
  申请人：Bayer Aktiengesellschaft

  公开号：EP3752492B1

  公开（公告）日：2022-12-21
• APTAMERS AND DIAGNOSTIC METHODS FOR DETECTING THE EGF RECEPTOR
  申请人：Quest Diagnostics Investments Incorporated

  公开号：US20150086996A1

  公开（公告）日：2015-03-26

  The present invention provides aptamers that specifically bind to the EGF receptor in a sample, and diagnostic and analytical methods using those aptamers. In some embodiments, the aptamers include a 3′ cap. In some embodiments, the 3′ cap is an inverted deoxythymidine. In some embodiments the aptamers include a spacer and at least one moiety selected from the group consisting of binding pair member and a detectable label, wherein the spacer is attached to the 5′-end of the aptamer and the moiety is attached the 5′ end of the spacer. In some embodiments the spacer is hexaethylene glycol. In some embodiments, the binding pair member biotin. In some embodiments the detectable label is a fluorophore.
• US9651556B2
  申请人：——

  公开号：US9651556B2

  公开（公告）日：2017-05-16
• [EN] AMINOANTHRACENE DERIVATIVE AND AN ORGANIC ELECTROLUMINESCENT ELEMENT EMPLOYING THE SAME<br/>[FR] DÉRIVÉ D'AMINOANTHRACÈNE ET ÉLÉMENT ÉLECTROLUMINESCENT ORGANIQUE L'EMPLOYANT
  申请人：DOOSAN CORP

  公开号：WO2010147318A2

  公开（公告）日：2010-12-23

  본 발명은 신규 아미노 안트라센 유도체 및 이를 이용한 유기 전계 발광 소자에 관한 것으로, 보다 구체적으로는 소자 특성이 우수한 안트라센 모이어티(moiety)와 형광 특성이 우수한 플루오렌 등의 모이어티(moiety)가 서로 결합된 코어, 예를 들면 인데노안트라센 코어를 가지면서, 상기 코어에 화학식 2로 표시되는 아민기가 하나 이상 치환된 아미노 안트라센 유도체, 및 상기 아미노 안트라센 유도체를 발광층 물질로 이용하여 효율, 구동 전압 및 수명 등의 특성이 향상된 유기 전계 발광 소자에 관한 것이다.
• [EN] COMPOSITIONS AND METHODS FOR DETECTING MICROORGANISMS<br/>[FR] COMPOSITIONS ET PROCÉDÉS DE DÉTECTION DE MICROORGANISMES
  申请人：SOMALOGIC INC

  公开号：WO2015126769A1

  公开（公告）日：2015-08-27

  Described herein are compositions and methods for detecting the presence or absence of a microorganism in a sample comprising contacting the sample with an aptamer capable of binding to a cell-surface protein of the microorganism to form a complex, contacting the mixture with a second aptamer capable of binding to the first cell-surface protein or a second cell-surface protein of the microorganism; and performing an assay to detect the second aptamer, wherein detecting the second aptamer indicates that the microorganism is present in the sample, and wherein not detecting the second aptamer indicates that the microorganism is absent from the sample.