Monononylmaleat | 15420-84-5

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: Monononylmaleat
• 英文别名: n-Nonyl-maleat；(Z)-4-nonoxy-4-oxobut-2-enoic acid
• CAS: 15420-84-5
• 化学式: C₁₃H₂₂O₄
• 分子量: 242.315
• InChiKey: ZUWTZMUABDXFJW-KTKRTIGZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  17
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.69
• 拓扑面积：
  63.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  Monononylmaleat 在 sodium hydroxide 、 sodium hydrogen sulfate 作用下， 生成 disodium 4-nonyl-3-sulfanatosuccinate
  参考文献：
  名称：

  A nuclear magnetic resonance investigation of the micellar properties of two-headed surfactant systems: the disodium 4-alkyl-3-sulfonatosuccinates. 1. Equilibrium micellar properties

  摘要：

  DOI：

  10.1139/cjc-76-9-1266
• 作为产物：
  描述：

  马来酸酐 、 1-壬醇 反应 0.33h， 生成 Monononylmaleat
  参考文献：
  名称：

  The properties of a family of two-headed surfactant systems: the 4-alkyl-3-sulfosuccinates 2. Surface properties of alkyl sulfosuccinate micelles

  摘要：

  研究了一类双头表面活性剂——烷基磺酸琥珀酸盐的胶束性质，利用荧光、紫外光谱和酸碱滴定，以表面活性剂链长为函数。使用吡啶和离子探针8-苯胺基-1-萘磺酸铵盐（ANS）研究了胶束内部的极性。利用吡啶I₁/I₃比值来探测胶束中栅栏层中探针的微环境。使用酸碱滴定确定了两个阴离子头基的pK_a值。通过测量疏水指示剂7-羟基香豆素在磺酸琥珀酸盐胶束界面的pK_a值获得表面电位测量。所有这些结果被用来检验烷基磺酸琥珀酸盐胶束的表面性质和胶束内部的极性。关键词：胶束化、pK_a、表面电位、表面电荷密度、7-羟基香豆素、吡啶。

  DOI：

  10.1139/v99-008

文献信息

• STYRENIC COPOLYMER AND PRODUCTION THEREOF
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0511407A1

  公开（公告）日：1992-11-04

  A styrenic copolymer having at least one structural unit represented by general formula (I) and either a structural unit represented by general formula (II) or a structural unit represented by general formula (IX), the content of the unit (II) or the unit (IX) being 0.01 to 99.9 mole %. In these formulae each symbol is as defined in the specification. This copolymer is highly syndiotactic in the stereoregularity of the chain composed of the structural units (I) and is excellent in the adhesion and compatibility with other resins.

  一种苯乙烯共聚物，至少有一个结构单元由通式(I)和一个结构单元由通式(II)或一个结构单元由通式(IX)表示，单元(II)或单元(IX)的含量为 0.01 至 99.9 摩尔%。在这些式子中，每个符号都与说明书中的定义相同。这种共聚物由结构单元（I）组成的链具有高度的立体均匀性，与其他树脂的粘合性和相容性极佳。
• Stabilizers for high nitrile multipolymers
  申请人：THE STANDARD OIL COMPANY

  公开号：EP0751177A2

  公开（公告）日：1997-01-02

  A melt processable high nitrile multipolymer such as an acrylonitrile olefinically unsaturated multipolymer, which is stabilized by admixing with a maleic acid or its derivatives, maleic anhydride, maleamides, maleates or combinations thereof.

  通过与马来酸或其衍生物、马来酸酐、马来酰胺、马来酸盐或其混合物混合而稳定的可熔融加工的高腈多聚物，如丙烯腈烯烃不饱和多聚物。
• POROUS FILM AND SECONDARY CELL ELECTRODE
  申请人：Zeon Corporation

  公开号：EP2282364A1

  公开（公告）日：2011-02-09

  The invention intends to provide a porous film which is formed on a surface of an electrode used for such as a secondary battery and the like, which has excellent binding property and is capable to contribute for improving a cyclic characteristic of the battery. A porous film according to the present invention comprises water soluble polymer, inorganic filler and water insoluble polymer comprising 0.5 to 40mass% of monomer unit including hydrophilic group selected from the group consisting of carboxylate group, hydroxyl group and sulfonic acid group.

  本发明旨在提供一种多孔薄膜，该薄膜形成于二次电池等所用电极的表面，具有极佳的结合性能，并有助于改善电池的循环特性。 根据本发明，多孔薄膜包括 水溶性聚合物、无机填料和水不溶性聚合物，其中水不溶性聚合物包含 0.5 至 40mass% 的单体单元，单体单元中的亲水基团选自羧酸基、羟基和磺酸基组成的组。
• SLURRY FOR SECONDARY BATTERY POROUS MEMBRANE, SECONDARY BATTERY POROUS MEMBRANE, SECONDARY BATTERY ELECTRODE, SECONDARY BATTERY SEPARATOR, AND SECONDARY BATTERY
  申请人：Zeon Corporation

  公开号：EP2626930A1

  公开（公告）日：2013-08-14

  A secondary battery porous membrane, manufactured by a slurry for secondary battery porous membrane, which is superior in coating priority and dispersibility of non-conductive organic particles, which improves cycle characteristic of the obtained secondary battery, which has high flexibility and can prevent powder falls, and which has less content of moisture amount; and non-conductive organic particles, which can be suitably used as a secondary battery porous membrane and has less content of metallic foreign particles. The slurry for secondary battery porous membrane comprises; a binder including a polymerized unit of vinyl monomer having a hydrophilic acid group, a non-conductive organic particle having a functional group, cross-linkable with the hydrophilic acid group and a solvent.

  一种二次电池多孔膜，由一种二次电池多孔膜用浆料制造，该浆料在非导电有机颗粒的涂布优先性和分散性方面具有优势，可改善所得二次电池的循环特性，具有高柔韧性，可防止粉末掉落，且水分含量较少；以及非导电有机颗粒，可适当用作二次电池多孔膜，且金属异物颗粒含量较少。用于二次电池多孔膜的浆料包括：粘合剂（包括具有亲水性酸基的乙烯基单体聚合单元）、具有官能团的非导电有机颗粒（可与亲水性酸基交联）和溶剂。
• SECONDARY BATTERY POSITIVE ELECTRODE
  申请人：Zeon Corporation

  公开号：EP2639863A1

  公开（公告）日：2013-09-18

  A positive electrode for secondary cell comprising a current collector which is comprised of aluminum or an aluminum alloy and a positive electrode active material layer, wherein the positive electrode active material layer contains a positive electrode active material, a water-based binder, an organic phosphonic acid compound, and a polyvalent metal compound is provided. According to the present invention, a positive electrode for secondary cell which is high in initial capacity and excellent in rate characteristics and high temperature cycle characteristics can be provided.

  本发明提供了一种用于二次电池的正极，包括由铝或铝合金构成的集流器和正极活性材料层，其中正极活性材料层包含正极活性材料、水基粘结剂、有机膦酸化合物和多价金属化合物。根据本发明，可以提供一种初始容量高、速率特性和高温循环特性优异的二次电池正极。