trinonyl citrate | 16544-71-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: trinonyl citrate
• 英文别名: Citronensaeure-trinonylester；Trinonyl 2-hydroxypropane-1,2,3-tricarboxylate
• CAS: 16544-71-1
• 化学式: C₃₃H₆₂O₇
• 分子量: 570.851
• InChiKey: OCSWENNWPSUAGH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.8
• 重原子数：
  40
• 可旋转键数：
  32
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.91
• 拓扑面积：
  99.1
• 氢给体数：
  1
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  柠檬酸三甲酯 、 1-壬醇 在 N,N,N-三甲基甲铵甲基碳酸酯 作用下， 以 四氢呋喃 为溶剂， 反应 15.0h， 以79%的产率得到trinonyl citrate
  参考文献：
  名称：

  碳酸四甲基铵甲酯催化的无金属酯交换反应

  摘要：

  不含环境的无金属碳酸四甲基铵甲酯可有效用作各种酯和醇在普通有机溶剂中的化学选择性，可扩展性和可重复使用的酯交换反应的催化剂。原位生成的高活性物质四甲基铵醇盐可大大避免在≤110°C时自分解，并可重复使用。特别地，可以使用使常规金属盐催化剂失活的螯合底物，例如氨基醇，二醇，三醇，糖衍生物，生物碱，α-氨基酸酯等。还展示了100克规模的生物柴油生产。

  DOI：

  10.1039/c7gc03858e

文献信息

• PLASTICIZER COMPOSITION, RESIN COMPOSITION, AND PREPARATION METHODS THEREFOR
  申请人：LG CHEM, LTD.

  公开号：US20180142078A1

  公开（公告）日：2018-05-24

  The present invention relates to a plasticizer composition, a resin composition, and preparation methods therefor, and can provide: a plasticizer capable of improving physical properties such as plasticizing efficiency, migration, tensile strength, elongation, stress migration and light resistance, which are required in sheet formulation, when used as a plasticizer of a resin composition by improving inferior physical properties generated because of structural limitations; and a resin composition containing the same.

  本发明涉及一种增塑剂组合物、树脂组合物及其制备方法，能够提供：一种增塑剂，能够改善塑化效率、迁移性、拉伸强度、延展性、应力迁移和耐光性等在片材配方中所需的物理性能，当作为树脂组合物的增塑剂时，通过改善由于结构限制而产生的劣质物理性能；以及含有该增塑剂的树脂组合物。
• PLASTICIZER COMPOSITION, RESIN COMPOSITION AND METHOD FOR PREPARING THEREOF
  申请人：LG CHEM, LTD.

  公开号：US20170369656A1

  公开（公告）日：2017-12-28

  The present invention relates to a plasticizer composition, a resin composition and a method for preparing thereof. The present invention can provide a plasticizer composition, which can improve properties required to the plasticizer composition contained in a vinyl chloride-based resin composition, such as plasticizing efficiency, volatile loss, and migration resistance, to a level equal to or better than the existing plasticizer composition, and a resin composition comprising thereof.

  本发明涉及一种增塑剂组合物、树脂组合物及其制备方法。本发明可以提供一种增塑剂组合物，该组合物可以改善聚氯乙烯基树脂组合物中所含增塑剂组合物所需的性能，如增塑效率、挥发损失和迁移抵抗性，使其达到或超过现有增塑剂组合物的水平，以及包含该组合物的树脂组合物。
• PLASTICIZER COMPOSITION, RESIN COMPOSITION, AND METHODS FOR PREPARING SAME
  申请人：LG Chem, Ltd.

  公开号：EP3281977A1

  公开（公告）日：2018-02-14

  The present invention relates to a plasticizer composition, a resin composition, and methods for preparing the same. The present invention can provide: a plasticizer composition capable of improving physical properties required for a plasticizer composition contained in a vinyl chloride-based resin composition, such as plasticizing efficiency, weight loss on heating, and migration resistance, to equivalent or higher levels compared with existing plasticizer compositions, and a resin composition comprising the same.

  本发明涉及一种增塑剂组合物、一种树脂组合物及其制备方法。本发明可提供：一种增塑剂组合物，与现有增塑剂组合物相比，该组合物能够将氯乙烯基树脂组合物中所含增塑剂组合物所需的物理性质（如增塑效率、加热失重和抗迁移性）提高到同等或更高水平；以及一种包含该增塑剂组合物的树脂组合物。
• PLASTICIZER COMPOSITION, AND RESIN COMPOSITION COMPRISING SAME
  申请人：LG Chem, Ltd.

  公开号：EP3293226A1

  公开（公告）日：2018-03-14

  Provided are a plasticizer composition, a resin composition and a method of preparing the same. Particularly, a plasticizer capable of improving physical properties such as plasticizer efficiency, migration, tensile strength, elongation rate, stress migration and light resistance, which are required for sheet formulations, when used as a plasticizer for a resin composition by improving poor physical properties generated due to a structural limitation thereof, and a resin composition including the same are provided.

  本发明提供了一种增塑剂组合物、一种树脂组合物及其制备方法。特别是提供了一种增塑剂，当作为树脂组合物的增塑剂使用时，通过改善由于其结构限制而产生的不良物理性质，能够改善片材配方所需的增塑效率、迁移性、拉伸强度、伸长率、应力迁移和耐光性等物理性质，并提供了包含该增塑剂的树脂组合物。
• PLASTICIZER COMPOSITION AND RESIN COMPOSITION
  申请人：LG CHEM, LTD.

  公开号：EP3670592A1

  公开（公告）日：2020-06-24

  Provided are a plasticizer composition and a resin composition, and a preparation method thereof, wherein the present invention may provide a plasticizer, which may improve physical properties, such as plasticizing efficiency, migration, tensile strength, elongation rate, stress resistance, and light resistance, required for a sheet formulation when used as a plasticizer of a resin composition, by improving poor physical properties that have been ascribed to structural limitations, and a resin composition including the plasticizer.

  本发明提供了一种增塑剂组合物和一种树脂组合物及其制备方法，其中本发明可提供一种增塑剂，当用作树脂组合物的增塑剂时，该增塑剂可通过改善归因于结构限制的不良物理性质来改善片材配方所需的物理性质，例如增塑效率、迁移性、拉伸强度、伸长率、抗应力性和耐光性。