2-全氟辛基乙基乙酸酯 | 37858-04-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 2-全氟辛基乙基乙酸酯
• 英文名称: CF3(CF2)7CHCH2
• 英文别名: 1H,1H,2H,2H-Perfluorodecyl acetate；3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl acetate
• CAS: 37858-04-1
• 化学式: C₁₂H₇F₁₇O₂
• 分子量: 506.159
• InChiKey: CPOHLPPQNCULDC-UHFFFAOYSA-N

物化性质

• 熔点：
  -20℃
• 沸点：
  189℃
• 密度：
  1.6429
• 闪点：
  >95℃
• 溶解度：
  氯仿（微溶）、甲醇（微溶）

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  31
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  19

安全信息

• 海关编码：
  2915390090

反应信息

• 作为产物：
  描述：

  乙烯 、 N,N-二甲基乙酰胺 、 (全氟正辛基)苯基碘鎓三氟甲烷磺酸盐 在 水 作用下， 以50%的产率得到2-全氟辛基乙基乙酸酯
  参考文献：
  名称：

  Reactions of RfI(Ph)OSO2CF3 with alkenes and alkadienes

  摘要：

  DOI：

  10.1016/s0040-4039(00)87051-3

文献信息

• Process for preparing fluorinated alkyl carboxylate esters
  申请人：Andrews Allen Mark

  公开号：US20070123731A1

  公开（公告）日：2007-05-31

  A process for preparing fluorinated alkyl carboxylate esters comprises reaction of a silver carboxylate or silver carboxylate precursor, such as silver (I) iodide with a fluorinated alkyl iodide and a carboxylic acid. Preferably the fluorinated alkyl iodide has the general formula CF 3 (CF 2 ) n CH 2 CH 2 I, wherein n is an integer in the range of from 1 to 29 and the carboxylic acid is acetic acid, acrylic acid or methacrylic acid.

  制备氟代烷基羧酸酯的过程包括将银羧酸盐或银羧酸盐前体（例如碘化银（I））与氟代烷基碘化物和羧酸反应。最好的情况是，氟代烷基碘化物具有一般式CF3(CF2)nCH2CH2I，其中n是1至29范围内的整数，而羧酸是乙酸、丙烯酸或甲基丙烯酸。
• Synthése de fluoroalkyl éthanl : RFCH2CHO
  作者：Ph. Laurent、H. Blancou、A. Commeyras

  DOI：10.1016/s0040-4039(00)92222-6

  日期：1992.4

  Aldehydes RFCH2CHO (R(F) is a linear perfluoroalkyl chain) have been obtained in the addition reaction of R(F)I to vinyl acetate in the presence of zinc. RFCH2CHIOAc is formed as an intermediate in the course of the reaction. Under appropriate conditions, RFCH2CHO and its acylal or acetal derivatives are obtained in good yields.
• UMEMOTO, TERUO;KURIU, YURIKO;NAKAYAMA, SHIN-ICHI, TETRAHEDRON LETT., 1982, 23, N 11, 1169-1172
  作者：UMEMOTO, TERUO、KURIU, YURIKO、NAKAYAMA, SHIN-ICHI

  DOI：——

  日期：——
• ANTIMICROBIAL SURFACE COATINGS
  申请人：Cao Zhengbing

  公开号：US20150315389A1

  公开（公告）日：2015-11-05

  The subject invention discloses curable polymeric N-halamine precursors which are useful for forming an antimicrobial surface coating on an object or article of manufacture. The present invention more specifically reveals a cross-linkable, water soluble polymer which is particularly useful for coating substrates and which can be activated to provide such substrates with antimicrobial and/or odor reducing characteristics, said cross-linkable polymer being comprised of amine, amide, or imide group containing repeat units and epoxide or methylol group containing repeat units, wherein the ratio of amine, amide or imide group containing repeat units to epoxide or methylol group containing repeat units is at least 2:1.
• Reactions of RfI(Ph)OSO2CF3 with alkenes and alkadienes
  作者：Teruo Umeoto、Yuriko Kuriu、Shin-ichi Nakayama

  DOI：10.1016/s0040-4039(00)87051-3

  日期：1982.1