glycerine carbonate butyrate

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: glycerine carbonate butyrate
• 英文别名: 3-butyroxy-1,2-propylene carbonate；(2-oxo-1,3-dioxolan-4-yl)methyl butyrate；(2-Oxo-1,3-dioxolan-4-yl)methyl butanoate
• 化学式: C₈H₁₂O₅
• 分子量: 188.18
• InChiKey: LZALYHRBYYGKKQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  13
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  61.8
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  羟甲基二氧杂戊环酮 、 丁酰氯 以 吡啶 为溶剂， 生成 glycerine carbonate butyrate
  参考文献：
  名称：

  The telomerisation of 1,3-butadiene and carbon dioxide: process development and optimisation in a continuous miniplant

  摘要：

  1,3-丁二烯和二氧化碳的端聚反应是最早利用二氧化碳作为C1构建单元进行均相催化反应之一。 本文中， 我们描述了在小规模的工厂中应用这一端聚反应进行连续生产的过程开发。通过对工厂设备多次优化以结合平行的实验室批次实验， 工厂的整体空间时间产率得到显著提升。

  DOI：

  10.1039/b608552k

文献信息

• Synthesis of Functionalized Cyclic Carbonates by One-Pot Reactions of Carbon Dioxide, Epibromohydrin, and Phenols, Thiophenols, or Carboxylic Acids Catalyzed by Ionic Liquids
  作者：Shi Wu、Yongya Zhang、Binshen Wang、Elnazeer H. M. Elageed、Liangzheng Ji、Haihong Wu、Guohua Gao

  DOI：10.1002/ejoc.201601315

  日期：2017.1.18

  The one-pot reactions of CO2, epibromohydrin, and phenols, thiophenols, or carboxylic acids catalyzed by 1-butyl-3-[(3-hydroxyphenyl)methyl]imidazolium bromide were investigated. Three kinds of cyclic carbonates with ether, thioether, or ester groups were synthesized under mild reaction conditions in good-to-high yields. Reaction-mechanism studies indicated that the proton exchange between the alkoxide

  研究了由 1-丁基-3-[(3-羟基苯基)甲基] 溴化咪唑鎓催化的 CO2、表溴醇和苯酚、苯硫酚或羧酸的一锅法反应。在温和的反应条件下以良好到高的收率合成了三种具有醚、硫醚或酯基团的环状碳酸酯。反应机理研究表明，表溴醇与 1-溴-3-苯氧基-2-丙醇的开环反应形成的醇盐之间的质子交换在该合成路线中起着至关重要的作用。催化剂1-丁基-3-[(3-羟基苯基)甲基]溴化咪唑鎓在反应过程中转化为相应的环状碳酸酯官能化离子液体。这种转化不影响其在反应中的催化性能。
• PROCESS FOR THE PRODUCTION OF GLYCEROL CARBONATE ESTERS
  申请人：Westfechtel Alfred

  公开号：US20080255373A1

  公开（公告）日：2008-10-16

  The invention relates to a process for the production of glycerol carbonate esters corresponding to formula (I): in which R is hydrogen or an alkyl or alkenyl group containing 1 to 23 carbon atoms, which may be linear or branched, characterized in that a compound corresponding to formula (II): in which Y is a group —O—CO—Z and Z is hydrogen or an alkyl or alkenyl group containing 1 to 3 carbon atoms, which may be linear or branched, is transesterified with dimethyl carbonate or diethyl carbonate and an alkyl ester corresponding to formula (IV): in which R is as defined above and X is an alkyl or alkenyl group containing 1 to 8 carbon atoms, which may be linear or branched, with the proviso that the group R of compound (IV) is different from the group Z of compound (II), in the presence of a transesterification catalyst.

  该发明涉及一种生产与式（I）对应的甘油碳酸酯的方法：其中R为氢或含有1至23个碳原子的烷基或烯基基团，可以是直链或支链，其特征在于将与式（II）对应的化合物：其中Y为基团—O—CO—Z，Z为氢或含有1至3个碳原子的烷基或烯基基团，可以是直链或支链，与二甲基碳酸酯或乙基碳酸酯和与式（IV）对应的烷基酯进行酯交换反应：其中R如上所述，X为含有1至8个碳原子的烷基或烯基基团，可以是直链或支链，但化合物（IV）的基团R与化合物（II）的基团Z不同，在酯交换催化剂存在下进行。
• Poly(hydroxyurethane): catalytic applicability for the cyclic carbonate synthesis from epoxides and CO₂
  作者：Suguru Motokucho、Hiroshi Morikawa

  DOI：10.1039/d0cc04463f

  日期：——

  developed a synthetic methodology using poly(hydroxyurethane) as an organocatalyst for the chemical fixation of CO2 into epoxides, leading to the formation of five-membered cyclic carbonates with remarkably high selectivity and yields. The catalyzed reaction was applicable to various epoxides.

  我们已经开发出一种使用聚（羟基氨基甲酸酯）作为有机催化剂将CO 2化学固定在环氧化物中的合成方法，从而导致五元环状碳酸酯的形成具有极高的选择性和产率。催化反应适用于各种环氧化物。
• POLY (ALKYL CARBONATE) ADHESIVES
  申请人：Trustees of Boston University

  公开号：US20200056038A1

  公开（公告）日：2020-02-20

  The invention provides polymer compositions, compounds, processes, and methods of use of the polymers for biodegradable consumer plastics, adhesives, e.g., bioadhesives, pressure sensitive adhesives and thermos-responsive adhesives.
• [EN] PATTERN FORMING METHOD, COMPOUND USED THEREIN, ACTINIC RAY-SENSITIVE OR RADIATION-SENSITIVE RESIN COMPOSITION, RESIST FILM, MANUFACTURING METHOD OF ELECTRONIC DEVICE, AND ELECTRONIC DEVICE<br/>[FR] PROCÉDÉ DE FORMATION DE MOTIFS, COMPOSÉ UTILISÉ DANS CE PROCÉDÉ, COMPOSITION DE RÉSINE SENSIBLE AUX RAYONS ACTINIQUES OU SENSIBLE AU RAYONNEMENT, FILM DE RÉSERVE, PROCÉDÉ DE FABRICATION D'UN DISPOSITIF ÉLECTRONIQUE, ET DISPOSITIF ÉLECTRONIQUE
  申请人：FUJIFILM CORP

  公开号：WO2014119698A1

  公开（公告）日：2014-08-07

  There is provided an actinic ray-sensitive or radiation-sensitive resin composition comprising: (A) a resin having a group capable of decomposing by an action of an acid to produce a polar group, (C1) a compound containing a group capable of generating a first acidic functional group upon irradiation with an actinic ray or radiation and a group capable of generating a second acidic functional group different from the first acidic functional group upon irradiation with an actinic ray or radiation, and (C2) at least one compound containing two or more groups selected from the group consisting of the groups capable of generating the structures represented by the specific formulae upon irradiation with an actinic ray or radiation.