methyl ethyl telluride

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机含氧阴离子化合物
• 英文名称: methyl ethyl telluride
• 英文别名: MeTeEt；(Methyltellanyl)ethane；methyltellanylethane
• 化学式: C₃H₈Te
• 分子量: 171.697
• InChiKey: NBOXEDJWYMBNIQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.18
• 重原子数：
  4
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  Dichloro-(1-methyltellur-3-buten-1-in)diquecksilberchlorid 、 diethylcalcium 生成 methyl ethyl telluride
  参考文献：
  名称：

  Tscherkasow L. N., Radtschenko S. I., Zh. organ. khimii, 30 (1994) N 3, S 456-457

  摘要：

  DOI：

文献信息

• Cherkasov, L. N.; Radchenko, S. I., Russian Journal of Organic Chemistry, 1994, vol. 30, # 3.2, p. 490 - 491
  作者：Cherkasov, L. N.、Radchenko, S. I.

  DOI：——

  日期：——
• Reaction of tellurium with dichloromethane in the system hydrazine hydrate-alkali
  作者：E. P. Levanova、V. A. Grabel’nykh、N. V. Russavskaya、L. V. Klyba、A. I. Albanov、N. A. Korchevin

  DOI：10.1134/s1070363209110073

  日期：2009.11

  Tellurium reacts with dichloromethane in the system hydrazine hydrate-alkali substituting one chlorine atom by tellurium whereas the second chlorine atom undergoes reductive substitution by hydrogen leading to the formation of methyltellanyl derivatives. Tentative mechanism of reduction is discussed. The discovered reaction allows the preparation of organotellurium compounds containing the MeTe group, including those involving other chalcogens.
• Reaction of 1,1-dichloroethane with tellurium in the system hydrazine hydrate-potassium hydroxide
  作者：E. P. Levanova、V. A. Grabel’nykh、A. V. Kolesnikov、L. V. Klyba、E. R. Zhanchipova、A. I. Albanov、N. V. Russavskaya、N. A. Korchevin

  DOI：10.1134/s1070428009070021

  日期：2009.7

  The reaction of 1,1-dichloroethane with tellurium in the system hydrazine hydrate-potassium hydroxide gave ethyltellanyl derivatives as a result of replacement of one chlorine atom in the substrate by tellurium, and of the other, by hydrogen. Probable mechanisms of reduction of the C-Cl bond and mass spectra of the products were considered. The mass spectra of ditelluroacetals revealed unusual rearrangement of the molecular ion, leading to the formation of Te-Te and new C-C bond.