2-phenylallyl acetate | 7534-40-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-phenylallyl acetate
• 英文别名: 2-phenylprop-2-enyl acetate
• CAS: 7534-40-9
• 化学式: C₁₁H₁₂O₂
• 分子量: 176.215
• InChiKey: FXTGIMSXGTUMAN-UHFFFAOYSA-N

物化性质

• 沸点：
  115-116 °C(Press: 9 Torr)
• 密度：
  1.0571 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-phenylallyl acetate 在 吡啶 、 lithium aluminium tetrahydride 、 氯化亚砜 作用下， 以 乙醚 为溶剂， 生成 3-氯丙-1-烯-2-基苯
  参考文献：
  名称：

  Cyclopropanes from Allylic Chlorides via Hydroborination

  摘要：

  DOI：

  10.1021/ja01493a013
• 作为产物：
  描述：

  (+/-)-1-acetoxy-2-phenyl-2-propanol 以 二甲基亚砜 为溶剂， 反应 10.0h， 以50%的产率得到2-phenylallyl acetate
  参考文献：
  名称：

  A Convenient Synthesis of 2-Phenylglycerol

  摘要：

  1,3-Dihydroxyacetone dimer is treated with trimethylsilyl chloride and triethylamine in dichloromethane to provide monomeric ketone having both of its alcohols protected as their di-TMS ethers. The latter is added to phenylmagnesium bromide in ether at -78 degrees C. Work-up by treatment with aqueous ammonium chloride followed by 2 N HCl provides 2-phenylglycerol in 70% yield.

  DOI：

  10.1080/00397910008087018
• 作为试剂：
  描述：

  在 dichloro(1,5-cyclooctadiene)ruthenium(II) 、 2-phenylallyl acetate 、 potassium carbonate 、 三苯基膦 作用下， 以 5,5-dimethyl-1,3-cyclohexadiene 为溶剂， 反应 20.0h， 以90%的产率得到2',2''-Bis(4,5-dihydrooxazol-2-yl)-1,1':3',1'':3'',1'''-quaterphenyl
  参考文献：
  名称：

  Nitrogen-Directed Ortho-Selective Homocoupling of Aromatic Compounds Catalyzed by Ruthenium Complexes

  摘要：

  A nitrogen-directed regioselective homocoupling reaction of aromatic compounds has been found to be catalyzed by a ruthenium complex in the presence of methallyl acetate as a hydrogen scavenger.

  DOI：

  10.1021/ol800439e

文献信息

• AROMATIC AMINE COMPOUND, CURING AGENT FOR EPOXY COMPOUND, CURABLE COMPOSITION, CURED PRODUCT, METHOD FOR PRODUCING CURED PRODUCT, AND METHOD FOR PRODUCING AROMATIC AMINE COMPOUND
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：US20210130284A1

  公开（公告）日：2021-05-06

  An aromatic amine compound capable of satisfactorily forming a cured product having exceptional alkali resistance by reaction with an epoxy compound; a curing agent for an epoxy compound, the curing agent including the aromatic amine compound; a curable composition including the curing agent for an epoxy compound; a cured product of the curable composition; a method for producing the cured product; and a method for producing the abovementioned aromatic amine compound. The aromatic amine compound has a structure such that a specific position in a central skeleton comprising a fused ring such as a fluorene ring is substituted with a side-chain group including two aromatic groups linked by a flexible bond such as an amide bond, at least one amino group is bonded to the end of the side-chain group, and the structure has no hydroxyl groups.

  一种芳香胺化合物，通过与环氧化合物反应能够满意地形成具有异常碱性抗性的固化产品；一种环氧化合物的固化剂，该固化剂包括芳香胺化合物；一种包括环氧化合物的固化剂的可固化组合物；可固化组合物的固化产品；生产所述固化产品的方法；以及生产上述芳香胺化合物的方法。该芳香胺化合物具有这样的结构，即中心骨架中的特定位置包括类似于芴环的融合环，该位置被取代为包括通过柔性键（如酰胺键）连接的两个芳香基的侧链基团，至少一个氨基固定在侧链基团的末端，并且该结构不含羟基。
• 含偕二氟亚甲基的烯烃化合物及其制备方法
  申请人：上海大学

  公开号：CN106588807B

  公开（公告）日：2020-04-03

  本发明涉及一系列含偕二氟亚甲基烯烃化合物及其制备方法，该烯烃化合物的结构式为：其中R1为：CH3CO2CH2‑,‑CnH2n+1(n＝1,2,3,4,5)或‑H；R2为：‑H,R3为：‑H,‑CnH2n+1(n＝4,5,6,7,8),(其中R为：‑H,‑OCH3,‑Br,‑Cl,‑F,‑NO2或‑CH3)。本发明用2‑一溴二氟甲基‑1,3‑苯并恶唑和烯烃在铜盐、配体和弱碱盐的作用下发生反应，生成一系列含偕二氟亚甲基的烯烃化合物。本发明原料易得，操作简便，反应条件温和，构型专一，对活性基团具有很好的耐受性，产率在25‑96％。
• Nickel-Catalyzed Reductive Allylation of Ketones with Allylic Carbonates
  作者：Wei Deng、Hegui Gong、Chenglong Zhao、Zhuozhen Tan、Zhuye Liang

  DOI：10.1055/s-0033-1339111

  日期：——

  Nickel-catalyzed efficient umpolung allylation of ketones with allylic carbonates in the presence of zinc powder is developed, which accommodates a variety of allylic and ketone substrates. Although chiral ligand is necessary for the transformation, no enantioselectivity was observed. Nickel-catalyzed efficient umpolung allylation of ketones with allylic carbonates in the presence of zinc powder is developed

  摘要 开发了在锌粉存在下，镍与酮的碳酸烯丙酯进行的镍催化的有效的烯丙基烯丙基化反应，可容纳各种烯丙基和酮的底物。尽管手性配体对于转化是必需的，但是未观察到对映选择性。 开发了在锌粉存在下，镍与酮的碳酸烯丙酯进行的镍催化的有效的烯丙基烯丙基化反应，可容纳各种烯丙基和酮的底物。尽管手性配体对于转化是必需的，但是未观察到对映选择性。
• Regioselective Acetoxylation of Terminal Olefins Using a Palladium(II)-Thiadiazole Catalyst
  作者：Xiaohan Li、Bin Sun、Jiadi Zhou、Can Jin、Chuangming Yu

  DOI：10.1002/ejoc.201900128

  日期：2019.4.24

  We have presented the first palladium(II)‐thiadiazole‐ligand catalytic system, employing 1,3,4‐thiadiazole derivative as ligand to achieve the esterification of terminal olefin with excellent regio‐ and stereoselectivity. This work is significant in that it represented the first application of 1,3,4‐thiadiazole in organic synthesis. Furthermore, it was also featured by its satisfied yields, mild reaction

  我们介绍了第一个钯（II）-噻二唑-配体催化体系，采用1,3,4-噻二唑衍生物作为配体，以优异的区域和立体选择性实现末端烯烃的酯化。这项工作意义重大，因为它代表了1,3,4-噻二唑在有机合成中的首次应用。此外，它还具有令人满意的产率，温和的反应条件。
• Highly Enantioselective, Base-Free Synthesis of α-Quaternary Succinimides through Catalytic Asymmetric Allylic Alkylation
  作者：Tao Song、Stellios Arseniyadis、Janine Cossy

  DOI：10.1002/chem.201800920

  日期：2018.6.7

  The synthesis of diversely substituted five‐membered ring succinimide derivatives is reported featuring a direct, base‐free, palladium‐catalyzed asymmetric allylic alkylation. The method allows a straightforward access to the desired heterocyclic scaffold bearing an all‐carbon α‐quaternary stereogenic center in high yields and good to excellent enantioselectivities. To further demonstrate the synthetic

  据报道，具有不同取代基的五元环琥珀酰亚胺衍生物的合成具有直接的，无碱的，钯催化的不对称烯丙基烷基化作用。该方法可以直接获得所需的杂环骨架，该骨架具有全碳α-季立体中心，且收率高，对映选择性极好。为了进一步证明该方法的合成效用，使用选择性转化将烯丙基化的产物进一步转化为各种通用的手性构件，包括手性吡咯烷和螺环衍生物。