tris(3,4,5-trimethoxyphenyl)bismuth dichloride | 895154-85-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: tris(3,4,5-trimethoxyphenyl)bismuth dichloride
• CAS: 895154-85-5
• 化学式: C₂₇H₃₃BiCl₂O₉
• 分子量: 781.44
• InChiKey: RJUBZBVHRIZLRY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -2.19
• 重原子数：
  39
• 可旋转键数：
  9
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  83.1
• 氢给体数：
  0
• 氢受体数：
  11

反应信息

• 作为产物：
  描述：

  磺酰氯 、 tris(3,4,5-trimethoxyphenyl)bismuthane 以 二氯甲烷 为溶剂， 生成 tris(3,4,5-trimethoxyphenyl)bismuth dichloride
  参考文献：
  名称：

  Tris(polymethoxyphenyl)bismuth derivatives: Synthesis and reactivity

  摘要：

  Tris-(polymethoxyphenyl)bismuth diacetate and dichloride derivatives react with C-nucleophiles in basic medium, as well as with N- and O-nucleophiles under copper catalysis to give good to high yields of the corresponding G, N- and O-arylation products. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.01.022

文献信息

• Tris(polymethoxyphenyl)bismuth derivatives: Synthesis and reactivity
  作者：Jean-Pierre Finet、Alexey Yu. Fedorov

  DOI：10.1016/j.jorganchem.2006.01.022

  日期：2006.5

  Tris-(polymethoxyphenyl)bismuth diacetate and dichloride derivatives react with C-nucleophiles in basic medium, as well as with N- and O-nucleophiles under copper catalysis to give good to high yields of the corresponding G, N- and O-arylation products. (c) 2006 Elsevier B.V. All rights reserved.