phenyl 4-vinylphenyl sulfide | 100715-86-4

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: phenyl 4-vinylphenyl sulfide
• 英文别名: 4-vinylphenyl phenyl sulfide；phenyl(4-vinylphenyl)sulfane；Phenyl-(4-vinyl-phenyl)-sulfid；1-Ethenyl-4-phenylsulfanylbenzene
• CAS: 100715-86-4
• 化学式: C₁₄H₁₂S
• 分子量: 212.315
• InChiKey: OBPNYYCAFJDQJO-UHFFFAOYSA-N

物化性质

• 沸点：
  351.9±21.0 °C(Predicted)
• 密度：
  1.10±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  phenyl 4-vinylphenyl sulfide 、 9,9-didecyl-2-iodo-7-nitro-9H-fluorene 在 palladium diacetate 、 三乙胺 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 150.0 ℃ 、1.72 MPa 条件下， 以99%的产率得到(E)-(4-(2-(9,9-didecyl-7-nitro-9H-fluoren-2-yl)vinyl)phenyl)(phenyl)sulfane
  参考文献：
  名称：

  Characterization of novel sulfonium photoacid generators and their microwave-assisted synthesis

  摘要：

  微波辅助合成三芳基锍盐光酸发生器（PAGs）的反应时间比传统热条件快 90 至 420 倍，新型锍 PAGs 的光量子产率为 0.01 至 0.4。

  DOI：

  10.1039/b815831b
• 作为产物：
  描述：

  1-(4-(phenylthio)phenyl)ethanol 生成 phenyl 4-vinylphenyl sulfide
  参考文献：
  名称：

  Dielectric compositions

  摘要：

  公开号：

  US02636022A1

文献信息

• A highly efficient heterogeneous copper-catalyzed Chan-Lam coupling between thiols and arylboronic acids leading to diaryl sulfides under mild conditions
  作者：Yang Lin、Mingzhong Cai、Zhiqiang Fang、Hong Zhao

  DOI：10.1016/j.tet.2016.04.063

  日期：2016.6

  coupling reaction between thiols and arylboronic acids was achieved in EtOH at room temperature in the presence of 5 mol % of MCM-41-immobilized 1,10-phenanthroline-copper(II) complex [MCM-41-1,10-Phen-CuSO4] with n-Bu4NOH (40% aq) as base under O2 atmosphere, yielding a variety of unsymmetrical diaryl sulfides in good to excellent yields under mild and green conditions. The new heterogeneous copper complex

  硫醇与芳基硼酸之间的异质Chan-Lam偶联反应是在室温下，在5％摩尔MCM-41固定的1,10-菲咯啉-铜（II）络合物[MCM-41-1，在O 2气氛下，以n -Bu 4 NOH（40％aq）为碱的10-Phen-CuSO 4 ]，在温和和绿色条件下以良好或优异的收率产生各种不对称的二芳基硫化物。新的多相铜络合物可以很容易地通过简单的方法由市售的廉价试剂制备，并通过简单过滤反应溶液进行回收并循环至少八次而不会显着降低催化活性。
• A Robust Pd-Catalyzed C–S Cross-Coupling Process Enabled by Ball-Milling
  作者：Andrew C. Jones、William I. Nicholson、Harry R. Smallman、Duncan L. Browne

  DOI：10.1021/acs.orglett.0c02418

  日期：2020.10.2

  operationally simple mechanochemical C–S coupling of aryl halides with thiols has been developed. The reaction process operates under benchtop conditions without the requirement for a (dry) solvent, an inert atmosphere, or catalyst preactivation. The reaction is finished within 3 h. The reaction is demonstrated across a broad range of substrates; the inclusion of zinc metal has been found to be critical in

  已经开发出了一种操作简单的芳基卤化物与硫醇的机械化学化学偶联方法。该反应过程在台式条件下进行，不需要（干燥）溶剂，惰性气氛或催化剂预活化。反应在3小时内完成。该反应已在多种底物上得到证实。已经发现，在某些情况下，尤其是对于烷基硫醇的偶联，锌金属的加入是至关重要的。
• Curable mixtures of polyepoxides and amine-terminated graft polymer dispersions
  申请人：BASF WYANDOTTE CORPORATION

  公开号：EP0059369A1

  公开（公告）日：1982-09-08

  Curable mixtures of polyepoxides and amine-terminated polymers are employed. The amine-terminated polymers are prepared by the in situ free radical polymerization of ethylenically unsaturated monomer or monomers in amine-terminated polyoxyalkylene polyether polymers.

  胺封端聚合物是通过乙烯不饱和单体或胺封端聚氧亚烷基聚醚聚合物中的单体原位自由基聚合制备的。
• Method for the preparation of graft polymer dispersions having broad particle size distribution without wildly fluctuating viscosities
  申请人：BASF Corporation

  公开号：EP0365986A2

  公开（公告）日：1990-05-02

  A method for preparing graft polymer dispersions having broad particle size distribution without wildly fluc­tuating viscosities is disclosed. The method comprises: (a) preparing intermediate graft polyol disper­sions containing 30 percent by weight or less solids to achieve a broad distribution of partial sizes in a continuous process by feeding a suffi­cient amount of an ethylenically unsaturated mon­omer and a free radical initiator into a flow re­actor at a temperature sufficient to promote poly­merization, and (b) charging the intermediate graft polymer dis­persion of (a) to a semi-batch reactor as seeds for further grafting to increase the solids content of the dispersion to above 30 percent by weight by feeding an effective amount of an ethylenically unsaturated monomer and a free radical initiator into the semi-batch reactor at a temperature suf­ficient to promote the growth of the seeds, whereby the seed particles generally grow larger but retain the characteristic of broad size distribution. The graft polymer so formed is useful in the production of polyurethanes.

  本发明公开了一种制备接枝聚合物分散体的方法，该分散体具有较宽的粒度分布，且粘度不会剧烈波动。该方法包括 (a) 在足以促进聚合的温度下，将足量的乙烯基不饱和单体和自由基引发剂送入流动反应器中，制备固体含量为 30% （重量百分比）或更少的中间接枝多元醇分散体，以便在连续工艺中实现广泛的部分尺寸分布，以及 (b) 在半间歇反应器中加入适量的乙烯基不饱和单体和自由基引发剂，在足以促进种子生长的温度下，将(a)中的中间接枝聚合物分散体作为种子加入半间歇反应器中，以进一步接枝，从而将分散体的固体含量提高到 30%以上（按重量计），种子颗粒一般会变大，但仍保持宽尺寸分布的特性。这样形成的接枝聚合物可用于生产聚氨酯。
• Integral skin polyurethane foam
  申请人：BASF CORPORATION

  公开号：EP0451559A2

  公开（公告）日：1991-10-16

  A process for preparing a flexible, low density, integral skin polyurethane foam wherein water is used as the sole blowing and density controlling agent. The process entails reacting an isocyanate component with a compound containing isocyanate reactive groups and further containing ether linkages, a polyurethane promoting catalyst, an alcohol, a surfactant, a chain extender and optional additives. The reaction is carried out at molded densities of from 15 pcf to 30 pcf in molds preheated to about 90°F to about 130°F.

  一种制备柔性低密度自结皮聚氨酯泡沫塑料的工艺，其中水被用作唯一的发泡剂和密度控制剂。该工艺需要将异氰酸酯成分与含有异氰酸酯反应基团并进一步含有醚键的化合物、聚氨酯促进催化剂、醇、表面活性剂、扩链剂和可选添加剂进行反应。反应在模塑密度为 15 pcf 至 30 pcf 的模具中进行，模具预热至约 90°F 至约 130°F。