molybdenum(VI) dichloride dioxide | 21974-63-0

• 分子结构分类: 有机化合物
• 英文名称: molybdenum(VI) dichloride dioxide
• CAS: 21974-63-0；51819-69-3
• 化学式: Cl₂MnO₂
• 分子量: 157.843
• InChiKey: NJQIFQZKRYNHTE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  1.14
• 重原子数：
  5.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  34.14
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  molybdenum(VI) dichloride dioxide 、 (4-硝基苯基)-磷酸 、 四-2-吡啶基吡嗪 、 copper(II) sulfate 以 硝基苯 为溶剂， 生成
  参考文献：
  名称：

  Solid state coordination chemistry of molybdenum oxides: Construction of bimetallic organic–inorganic hybrid materials from Keggin clusters and copper-imine building blocks

  摘要：

  The unexpected hydrolysis of organophosphonic acid ligands under hydrothermal reaction conditions yielded four bimetallic oxide materials incorporating Keggin type polyanions. The one-dimensional [Cu4O(Htpyprz)(tpyPrz)(2)Cl-4] [Mo12PO40] (1), [Cu-6(4-pyrtet)(2)(4-Hpyrtet)(4)][(MoMo11PO40)-Mo-V-P-V-P-I]center dot 2.5H(2)O (2.2.5H(2)P), and [Cu-3(OH)(4-pyrtet)(2)(4-Hpyrtet)(2)(H2O)(2)] [Mo12PO40]center dot 10.5H(2)O (3.10.5H(2)O) and the two-dimensional [Cu-3(OH)(4-pyrtet)(3)(4-H(2)pyrtet)(H2O)] [Mo12PO40]center dot 7.5H(2)O (4.7.5H(2)O) (tpyprz = tetra-4-pyridyl pyrazine; 4-Hpyrtet = 4-pyridyltetrazole) demonstrate the variety of ways in which Keggin clusters may influence the configuration of the secondary metal-ligand substructure. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.08.007