四氟环氧乙烷 | 694-17-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 环氧化物
• 中文名称: 四氟环氧乙烷
• 英文名称: Tetrafluorooxirane
• 英文别名: perfluoroethylene epoxide；tetrafluoroethane epoxide；tetrafluoroethylene oxide；epoxytetrafluoroethylene；perfluoroethylene oxide；tetrafluoro-oxirane；2,2,3,3-tetrafluorooxirane
• CAS: 694-17-7
• 化学式: C₂F₄O
• 分子量: 116.015
• InChiKey: LOUICXNAWQPGSU-UHFFFAOYSA-N

物化性质

• 熔点：
  -118 °C
• 沸点：
  -63.5 °C
• 密度：
  1.63±0.1 g/cm3(Predicted)
• 保留指数：
  254

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  7
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  5

安全信息

• 海关编码：
  2910900090

反应信息

• 作为反应物：
  描述：

  四氟环氧乙烷 以 neat (no solvent) 为溶剂， 生成 二氟卡宾
  参考文献：
  名称：

  Kinetics of the Thermal Decomposition of Tetrafluoroethylene Oxide

  摘要：

  The thermal stability of gaseous tetrafluoroethylene oxide has been examined between 40° and 140°C. In this range of temperatures two distinct modes of decomposition have been observed. At higher temperature a unimolecular process takes place with the formation of carbonyl fluoride, tetrafluoroethylene, and perfluorocyclopropane. Isomerization occurs through a heterogeneous reaction on the wall in the low-temperature range leading to trifluoroacetyl fluoride. The unimolecular behavior is treated according to the Rice—Ramsperger—Kassel theory. A kinetic scheme, which is in agreement with the experimental results, is proposed for the formation of the products.

  DOI：

  10.1063/1.1697062
• 作为产物：
  描述：

  四氟乙烯 在 氧气 作用下， 以 gas 为溶剂， 生成 四氟环氧乙烷
  参考文献：
  名称：

  Mezentsev, A. I.; Poluektov, V. A., Russian Journal of Physical Chemistry, 1983, vol. 57, # 7, p. 1014 - 1016

  摘要：

  DOI：

文献信息

• Some approaches to the synthesis of fluorinated alcohols and esters. I. Completely fluorinated esters from the hunsdiecker reaction of silver F-alkanoates with iodine
  作者：Neal O. Brace

  DOI：10.1016/s0022-1139(00)82668-8

  日期：1981.10

  A completely fluorinated ester of the type RFCO2CF2RF′ was obtained from reaction of silver 3,6,9-trioxa-F-undecanoate and iodine with a diluent at 130°. This new substance resembled closely the previously prepared 1,1-dichloro-F-alkyl esters and was hydrolytically and thermally labile. Substitution products, RFCOY (Y = nucleophile) and pyrolysis products, RFCOF and RF′COF were isolated and characterized

  由3,6,9-三氧杂-F-十一酸银和碘与稀释剂在130°C下反应制得R F CO 2 CF 2 R F '型的完全氟化酯。这种新物质非常类似于先前制备的1,1-二氯-F-烷基酯，并且水解和热不稳定。取代产物，R ˚F COY（Y =亲核）和热解产物，R ˚F COF和R ˚F 'COF进行分离和表征。似乎酰基次碘酸盐和碘代-F-烷烃通过S E i型过程反应生成了完全氟化的酯。
• FIVE-MEMBERED CYCLIC ANION USE THEREOF AS AN ELECTROLYTE
  申请人：CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE

  公开号：US20150315155A1

  公开（公告）日：2015-11-05

  A pentacyclic anion salt is provided for use thereof in electrolyte compositions. The compound has an inorganic, organic or organometallic cation M of valency m (1≦m≦3) and m anions corresponding to the formula (I) in which R f is a —CFZ′Z″ group in which Z′ is F or a perflouroalkyl group having from 1 to 3 carbon atoms, and Z″ is an H, F or Cl group, an optionally fluorinated or perfluorinated alkoxy group having from 1 to 5 carbon atoms, an optionally fluorinated or perfluorinated oxaalkoxy group having 1 to 5 carbon atoms or an optionally fluorinated or perfluorinated alkyl group having from 1 to 5 carbon atoms; Z″ being other than F when Z′ is F. An electrolyte composition comprises said salt in solution in a liquid solvent or a polymer solvent.

  提供一种五环阴离子盐，用于在电解质组合物中使用。该化合物具有一个无机、有机或有机金属阳离子M，其价数为m（1≦m≦3），以及与公式（I）对应的m个阴离子，其中Rf是一个—CFZ′Z″基团，其中Z′是F或具有1至3个碳原子的全氟烷基基团，Z″是一个H、F或Cl基团，一个可选择氟化或全氟烷氧基团，具有1至5个碳原子，一个可选择氟化或全氟氧烷氧基团，具有1至5个碳原子，或一个可选择氟化或全氟烷基基团，具有1至5个碳原子；当Z′为F时，Z″不是F。电解质组合物包括所述盐溶解在液体溶剂或聚合物溶剂中。
• Thermal gas-phase reaction of perfluorobuta-1,3-diene with NO2
  作者：Joanna Czarnowski

  DOI：10.1016/j.jfluchem.2007.12.001

  日期：2008.4

  temperature range 312.9–333.4 K were CF2CFCF(NO2)CF2(NO2) (I), CF2(NO2)CFCFCF2(NO2) (II), CF2CFCF(NO2)C(O)F (III) and CF2(NO2)CFCFC(O)F (IV) and FNO. The formation of these compounds was detected performing infrared and Raman spectra. The infrared spectrum shows a band at 1785 cm−1, characteristic to the terminal –CFCF2 group and the Raman spectrum shows a band located at 1733 cm−1, corresponding to

  使用常规的静态系统，已经研究了NO 2与全氟丁-1,3-二烯CF 2 CFCFCF 2（C 4 F 6）的反应，其反应温度为312.9、323.0、333.4、396.0和418.0K。在312.9–333.4 K温度范围内形成的产物为CF 2 CFCF（NO 2）CF 2（NO 2）（I），CF 2（NO 2）CFCFCF 2（NO 2）（II），CF 2 CFCF（NO 2）C（O）F（III）和CF 2（NO 2CFCFC（O）F（IV）和FNO。通过红外光谱和拉曼光谱检测到这些化合物的形成。红外光谱在1785 cm -1处显示一个波段，这是末端–CFCF 2组的特征，拉曼光谱在1733 cm -1处显示一个波段，对应于–CFCF–组。它表明，在此温度范围内，NO 2最初仅攻击CF 2 CFCFCF 2的一个双键。由于在此过程中形成的中间自由基CF 2 CFCFCF 2（NO 2）本
• Maksimov, B. N., Russian Journal of Organic Chemistry, 1994, vol. 30, # 12, p. 1935 - 1940
  作者：Maksimov, B. N.

  DOI：——

  日期：——
• Fluorine-containing imines. 1. New cycloaddition reactions of acylimines of fluoroketones
  作者：Z. V. Safronova、L. A. Simonyan、Yu. V. Zeifman、N. P. Gambaryan

  DOI：10.1007/bf00950995

  日期：1979.8