Diethyl 2-(Hydroxyimino)succinate | 131401-52-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: Diethyl 2-(Hydroxyimino)succinate
• 英文别名: diethyl (2Z)-2-(hydroxyimino)butanedioate；diethyl (2Z)-2-hydroxyiminobutanedioate
• CAS: 131401-52-0
• 化学式: C₈H₁₃NO₅
• 分子量: 203.195
• InChiKey: IPZFGOBLSYOLKY-TWGQIWQCSA-N

物化性质

• 沸点：
  309.4±44.0 °C(Predicted)
• 密度：
  1.20±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  14
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  85.2
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  Diethyl 2-(Hydroxyimino)succinate 在 sodium amalgam 作用下， 生成 DL-天门冬氨酸
  参考文献：
  名称：

  Piutti, Gazzetta Chimica Italiana, 1887, vol. 17, p. 520

  摘要：

  DOI：
• 作为产物：
  描述：

  丁二酸,苯甲酰-,二乙基酯 在 nitrogen oxides 作用下， 生成 Diethyl 2-(Hydroxyimino)succinate
  参考文献：
  名称：

  Schmidt,J.; Dieterle, Justus Liebigs Annalen der Chemie, 1910, vol. 377, p. 53 Anm.

  摘要：

  DOI：

文献信息

• A Novel and Efficient Method for the Preparation of α-Hydroxyimino Carbonyl Compounds from α,β-Unsaturated Carbonyl Compounds with Butyl Nitrite and Phenylsilane Catalyzed by a Cobalt(II) Complex
  作者：Koji Kato、Teruaki Mukaiyama

  DOI：10.1246/bcsj.64.2948

  日期：1991.10

  Various α,β-unsaturated carbonyl compounds, such as α,β-unsaturated esters, α,β-unsaturated ketones, α,β-unsaturated nitriles, and α,β-unsaturated amides, were directly converted to the corresponding a-hydroxyimino carbonyl compounds in high yields on treatment with butyl nitrite and phenylsilane in the presence of a catalytic amount of N,N′-bis(2-ethoxycarbonyl-3-oxobutylidene)ethylenediaminatocobalt(II)

  α,β-不饱和酯、α,β-不饱和酮、α,β-不饱和腈、α,β-不饱和酰胺等多种α,β-不饱和羰基化合物直接转化为相应的α-羟基亚氨基羰基在温和条件下，在催化量的 N,N'-双（2-乙氧基羰基-3-氧代丁二烯）乙二氨基钴 (II) 配合物存在下，用亚硝酸丁酯和苯基硅烷处理高产率的化合物。
• A Novel Method for the Preparation of 2-Hydroxyiminocarboxylic Acid Esters. Cobalt(II) Catalyzed α-Oximation of α,β-Unsaturated Esters with Butyl Nitrite and Phenylsilane
  作者：Koji Kato、Teruaki Mukaiyama

  DOI：10.1246/cl.1990.1917

  日期：1990.10

  Various α,β-unsaturated esters are directly converted to the corresponding 2-hydroxyiminocarboxylic acid esters with butyl nitrite and phenylsilane in high yields by use of N,N′-bis(2-ethoxycarbonyl-3-oxobutylidene)ethylenediaminato cobalt(II) complex as catalyst under mild condition.

  通过使用 N,N'-双（2-乙氧基羰基-3-氧代丁叉基）乙二氨基钴（II）配合物，各种 α,β-不饱和酯与亚硝酸丁酯和苯基硅烷以高产率直接转化为相应的 2-羟基亚氨基羧酸酯在温和条件下作为催化剂。
• COMPOSITION FOR REGULATING PLANT GROWTH, METHOD FOR TREATING PLANTS THEREWITH, AND ACTIVE INGREDIENT THEREOF
  申请人：Gorbunov Sergei Valeryevich

  公开号：US20190119193A1

  公开（公告）日：2019-04-25

  A composition for regulating plant growth, the active ingredient of which is an ester of oxaloacetic acid or a salt thereof, or derivatives thereof, wherein the ester of oxaloacetic acid has the formula set forth below, where R 1 and R 2 are independently selected from a series of C 1 -C 18 alkyl groups, and wherein the content of the active ingredient corresponds to a concentration of from 10 −11 M to 10 −3 M. The active ingredients and compositions for regulating plant growth allow for treating plants in order to stimulate the growth thereof and achieve such advantages as increased yields, improved plant quality, improved nutrient absorption and enhanced stress resistance, while allowing such advantages to be achieved using a relatively small amount of an active ingredient(s) which is/are biodegradable and environmentally friendly.

  一种用于调节植物生长的组合物，其活性成分为草酰乙酸酯或其盐或其衍生物，其中草酰乙酸酯的化学式如下，其中R1和R2分别选自一系列C1-C18烷基基团，且活性成分的含量相当于10−11M至10−3M的浓度。这种用于调节植物生长的活性成分和组合物可用于处理植物，以刺激其生长并实现增产、改善植物质量、改善营养吸收和增强抗压能力等优点，同时使用相对较少的活性成分（它们是可生物降解和环保的）即可实现这些优点。
• Ebert, Justus Liebigs Annalen der Chemie, 1885, vol. 229, p. 65,76
  作者：Ebert

  DOI：——

  日期：——
• Hamlin; Hartung, Journal of Biological Chemistry, 1942, vol. 145, p. 352
  作者：Hamlin、Hartung

  DOI：——

  日期：——