1-Ethoxyvinyl trichloroacetate | 90724-35-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 1-Ethoxyvinyl trichloroacetate
• 英文别名: 1-Aethoxyvinyl-trichloracetat
• CAS: 90724-35-9
• 化学式: C₆H₇Cl₃O₃
• 分子量: 233.479
• InChiKey: FMQZVSJBUAFIMC-UHFFFAOYSA-N

物化性质

• 沸点：
  196.4±40.0 °C(Predicted)
• 密度：
  1.402±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.41
• 重原子数：
  12.0
• 可旋转键数：
  3.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  35.53
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  1-Ethoxyvinyl trichloroacetate 生成 4,4,4-trichloro-3-oxo-2-trichloroacetyl-butyric acid ethyl ester
  参考文献：
  名称：

  The South African polymict eucrite Macibini

  摘要：

  Abstract— The polymict eucrite Macibini is a fragmental breccia, predominantly composed of eucritic materials with minor proportions (maximum 2 vol%) of diogenitic material. Hence, it is intermediate between the Yamato‐74159‐type polymict eucrites, which contain negligible amounts of magnesian orthopyroxene, and the howardites. The present study provides mineralogical and bulk compositional data for the meteorite breccia and for six clasts. These clasts include both volcanic and igneous rocks and a variety of impact‐generated rocks. A broad range of degrees of postcrystallization metamorphism affected these materials before the final aggregation of the breccia.Clast A is a fragment of unequilibrated eucrite with subophitic texture. The edges of the zoned pyroxenes in this clast are composed of a host of Fe‐rich augite containing vermicules (blebs) and lamellae composed of a mixture of Fe‐rich olivine and silica. Similar features occur as fragments in lunar breccias and are attributed by some workers to the breakdown of pyroxferroite, an Fe‐rich pyroxenoid. However, textures and compositions of these augite‐olivine‐silica intergrowths in clast A suggest that, in this case, they are the result of decomposition in a series of steps of Fe‐rich subcalcic augite.Among the fragments of impact‐generated material in Macibini is clast 2, an earlier‐formed clastic breccia that was lithified before being broken apart and included in the meteorite breccia. Clast 3 is an impact‐melt breccia that is composed of rock and mineral fragments in a devitrified groundmass. Clast C is also an impact‐melt breccia that has a coarser‐grained, hornfelsic groundmass that resulted from extensive metamorphism after formation.

  DOI：

  10.1111/j.1945-5100.2000.tb01519.x
• 作为产物：
  描述：

  乙氧基乙炔 、 三氯乙酸 在 [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 作用下， 以 四氢呋喃 为溶剂， 以73%的产率得到1-Ethoxyvinyl trichloroacetate
  参考文献：
  名称：

  通过线性方法全合成抗肿瘤抗生素（+/-）-弗雷德里卡霉素A。

  摘要：

  描述了通过（苯硫基）乙炔-钴络合物的氧化性分子内[4 + 2]环加成反应，外消旋腓特烈霉素A（1）的总合成的线性方法，该方法适用于天然存在的1的不对称总合成。这项工作的重点是与1-乙氧基乙烯基氯乙酸酯的芳香族Pummerer型反应，该反应可将氧官能团引入高度官能化的，拥挤的多芳族ABC环部分的内部B环中。

  DOI：

  10.1002/1521-3765(20001103)6:21<3897::aid-chem3897>3.0.co;2-1

文献信息

• Wasserman,H.H.; Wentland,S.H., Journal of the Chemical Society, Section D: Chemical Communications, 1969, p. 1216 - 1217
  作者：Wasserman,H.H.、Wentland,S.H.

  DOI：——

  日期：——
• Zwanenburg,B., Recueil des Travaux Chimiques des Pays-Bas, 1963, vol. 82, p. 593 - 601
  作者：Zwanenburg,B.

  DOI：——

  日期：——