diaquabis[2-(hydroxyimino)propanoato]zinc(II) | 131461-11-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: diaquabis[2-(hydroxyimino)propanoato]zinc(II)
• CAS: 131461-11-5；370590-83-3；835895-61-9
• 化学式: C₆H₁₂N₂O₈Zn
• 分子量: 305.56
• InChiKey: OYGKITPASUEGHN-SMCGPUKBSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  diaquabis[2-(hydroxyimino)propanoato]zinc(II) 以 neat (no solvent) 为溶剂， 生成 zinc(II) oxide
  参考文献：
  名称：

  Towards new precursors for ZnO thin films by single source CVD: the X-ray structures and precursor properties of zinc ketoacidoximates

  摘要：

  Zinc complexes of pyruvic and glyoxylic acid oximes have been investigated as potential precursors for single source chemical vapour deposition (SSCVD) of ZnO thin films. The X-ray crystal structures of the complexes and of their NOW analogues reveal markedly different coordination and intermolecular bonding patterns. These structural differences, in conjunction with ligand substituent changes impart different responses to thermogravimetric analysis (TGA), and sublimation. The glyoxylic acid methyloxime Zn(O2CCHN(OMe))(2) . 2H(2)O has volatility and thermolysis properties suitable for SSCVD of ZnO. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.07.022
• 作为产物：
  描述：

  zinc(II) nitrate hexahydrate 、 盐酸羟胺 、 sodium pyruvate 、 水 在 sodium bicarbonate 作用下， 以 水 为溶剂， 以78%的产率得到diaquabis[2-(hydroxyimino)propanoato]zinc(II)
  参考文献：
  名称：

  Towards new precursors for ZnO thin films by single source CVD: the X-ray structures and precursor properties of zinc ketoacidoximates

  摘要：

  Zinc complexes of pyruvic and glyoxylic acid oximes have been investigated as potential precursors for single source chemical vapour deposition (SSCVD) of ZnO thin films. The X-ray crystal structures of the complexes and of their NOW analogues reveal markedly different coordination and intermolecular bonding patterns. These structural differences, in conjunction with ligand substituent changes impart different responses to thermogravimetric analysis (TGA), and sublimation. The glyoxylic acid methyloxime Zn(O2CCHN(OMe))(2) . 2H(2)O has volatility and thermolysis properties suitable for SSCVD of ZnO. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.07.022