2-叔丁基-4-环己基苯酚 | 62737-78-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 2-叔丁基-4-环己基苯酚
• 英文名称: 2-t-butyl-4-cyclohexylphenol
• 英文别名: 2-tert-butyl-4-cyclohexylphenol
• CAS: 62737-78-4
• 化学式: C₁₆H₂₄O
• 分子量: 232.366
• InChiKey: PJNMKAQCMGXVNI-UHFFFAOYSA-N

物化性质

• 沸点：
  327.1±21.0 °C(Predicted)
• 密度：
  0.985±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-叔丁基-4-环己基苯酚 、 氯化烟碱盐酸盐 在 吡啶 作用下， 生成 吡啶盐酸盐
  参考文献：
  名称：

  Certain substituted phenyl esters of nicotinic acid, compositions and

  摘要：

  新型降脂烟酸盐和相关酯类化合物，作为苯氧有机化合物，以及其药物组合物和治疗高脂血症的方法被披露。

  公开号：

  US04321268A1
• 作为产物：
  描述：

  对环己基苯酚 生成 2-叔丁基-4-环己基苯酚
  参考文献：
  名称：

  Drugs Fut 1987, 12, 349

  摘要：

  DOI：

文献信息

• Certain 4-(1-piperidino)-phenyl-nicotinates
  申请人：Merz & Company

  公开号：US04412998A1

  公开（公告）日：1983-11-01

  Novel hypolipidemic nicotinates and related esters, being phenoxy organic compounds, are disclosed, as well as pharmaceutical compositions thereof and method of treating hyperlipidemia therewith.

  本发明揭示了一种新型的降脂尼古丁酸盐和相关酯类化合物，其为苯氧有机化合物，以及其制药组合物和用于治疗高脂血症的方法。
• Leptospermum plant named ‘RUYLEPLAR’
  申请人：de Ruyver Kurt

  公开号：USPP032581P2

  公开（公告）日：2020-12-08

  A new and distinct variety of Leptospermum plant named ‘RUYLEPLAR’ which is characterized by the combination of a conical growth habit, an abundance of red-purple foliage on dark red stems, excellent heat and drought tolerance, and the stability of all characteristics from generation to generation.

  一种新的、独特的Leptospermum植物品种，名为“RUYLEPLAR”，其特点是锥形生长习性、深红色茎上丰富的红紫色叶片、优异的耐热和耐旱能力，以及所有特征从一代到下一代的稳定性。
• METHOD FOR PRODUCING 4,4''-DIHYDROXY-M-TERPHENYLS
  申请人：Honshu Chemical Industry Co., Ltd.

  公开号：EP2851359A1

  公开（公告）日：2015-03-25

  To achieve the object of providing a new method of manufacturing 4,4"-dihydroxy-m-terphenyl, the present invention provides a method of manufacturing 4,4"-dihydroxy-m-terphenyl expressed by General Formula (4) below, characterized in that such method uses a 2-cyclohexene-1-one expressed by General Formula (1) below or 3-hydroxycyclohexane-1-one expressed by General Formula (2) below, and phenol expressed by General Formula (3) below as materials and implements Step (A), Step (B), and Step (C) below, in this order, or Step (D) and Step (C) below, in this order: (In the formulas, each R2 independently represents an alkyl group, alkoxy group, aromatic hydrocarbon group, or halogen atom, while m independently indicates 0 or an integer of 1 to 4, where R2 substitution does not occur in the third position when m is 1 or greater, and when m is 2 or greater, R2's may be identical or different, and R2 substitution does not occur in two positions of the same carbon atom. In addition, R2 and m in General Formula (1) may be identical to or different from R2 and m in General Formula (2), respectively.) (In the formula, each R1 independently represents an alkyl group, alkoxy group, aromatic hydrocarbon group, halogen atom, or hydroxyl group, while n indicates 0 or an integer of 1 to 4, where R1's may be identical or different when n is 2 or greater.) Step (A): Step to obtain a 1,1,3-trisphenol by causing the 2-cyclohexene-1-one or 3-hydroxycyclohexane-1-one and phenol to react with each other in the presence of a catalyst. Step (B): Step to obtain a bis(4-hydroxyphenyl)cyclohexene by causing the 1,1,3-trisphenol to undergo breakdown reaction. Step (C): Step to obtain a 4,4"-dihydroxy-m-terphenyl by dehydrogenating the bis(4-hydroxyphenyl)cyclohexene. Step (D): Step to obtain a bis(4-hydroxyphenyl)cyclohexene by causing the 2-cyclohexene-1-one or 3-hydroxycyclohexane-1-one and phenol to react with each other in the presence of a catalyst. (In the formula, each R1 and n is independently the same as the corresponding items in General Formula (3), respectively, while R2 and m are the same as the corresponding items in General Formula (1) or General Formula (2), respectively.)

  为了实现提供一种制造 4,4"-二羟基间三联苯的新方法的目的，本发明提供了一种制造由下式（4）表示的 4,4"-二羟基间三联苯的方法、其特征在于，该方法使用以下通式(1)表示的2-环己烯-1-酮或以下通式(2)表示的3-羟基环己烷-1-酮和以下通式(3)表示的苯酚作为材料，并依次实施步骤(A)、步骤(B)和步骤(C)，或依次实施步骤(D)和步骤(C)： (在公式中，每个 R2 独立地代表烷基、烷氧基、芳香族烃基或卤素原子，而 m 独立地表示 0 或 1 至 4 的整数，其中当 m 为 1 或更大时，R2 取代不会发生在第三个位置，而当 m 为 2 或更大时，R2 可以相同或不同，R2 取代不会发生在同一碳原子的两个位置。此外，通式（1)中的 R2 和 m 可分别与通式（2)中的 R2 和 m 相同或不同)。 (式中，每个 R1 独立地代表烷基、烷氧基、芳香烃基、卤素原子或羟基，而 n 表示 0 或 1 至 4 的整数，其中当 n 为 2 或更大时，R1 的可能相同或不同)。 步骤 (A)：使 2-环己烯-1-酮或 3-羟基环己烯-1-酮和苯酚在催化剂存在下相互反应，从而获得 1,1,3-三苯酚的步骤。 步骤 (B)：使 1,1,3-三苯酚发生分解反应，得到双（4-羟基苯基）环己烯的步骤。 步骤(C)：通过双（4-羟基苯基）环己烯的脱氢反应，得到 4,4"-二羟基间三联苯。 步骤(D)：在催化剂存在下，使 2-环己烯-1-酮或 3-羟基环己烯-1-酮与苯酚相互反应，得到双（4-羟基苯基）环己烯的步骤。 (式中，各 R1 和 n 分别独立地与通式(3)中的相应项目相同，而 R2 和 m 分别与通式(1)或通式(2)中的相应项目相同)。
• Fabric care compositions
  申请人：——

  公开号：US20040063597A1

  公开（公告）日：2004-04-01

  A non-liquid, liquid, liquid-gel or gelled fabric care composition and method of use comprising: (a) one or more fabric care enzymes, the fabric care enzymes effective for aiding in preventing pilling fuzzing, staining and other deterioration of fabric fibers during the wash process; (b) one or more UV protectants, the one or more UV protectants for brightening and preventing light caused photo fading or other damage to fabrics; (c) one or more surface active dispersing, emulsifying and/or solubilizing agent, the one or more surface active dispersing, emulsifying and/or solubilizing agent principally comprised of surfactants, co-surfactants, hydrotropes and solvents selected to solubilize or stabilize the composition; (d) one or more dye-transfer inhibitors, anti-redeposition agents or dye sequestrants, the one or more dye-transfer inhibitors, anti-redeposition agents or dye sequestrants to prevent re-deposition of dyes which have become transient from other fabrics; (e) one or more dye, pigment and fabric color fixative or finish protectant, the dye, pigment and fabric color fixative or finish protectant to lock-in dyes and pigments to prevent their loss in quantity or quality during soaking or washing; (f) optionally, one or more textile lubricant and/or textile softening agent, the lubricant and/or textile softening agent to coat the textiles and reduce inter-fiber and fiber surface friction; (g) one or more hardness and metal ion sequestrants and crystal growth inhibitors, the hardness and metal ion sequestrants and crystal growth inhibitors to bind free ions to prevent formation of insoluble precipitate compounds; (h) one or more chlorine and/or active oxygen scavengers or neutralizers which act to neutralize oxidizing agents, i.e., those species with oxidation potential; and (i) optionally, one or more from the following: handling, storage, processing agents to modify elastic and viscous phase properties, anti-foaming or frothing agents, anti-microbial, anti-bacterial or anti-fungal agents, pH buffer, adjustment, aesthetic dyes and/or fragrances.

  一种非液体、液体、液体凝胶或胶状织物护理组合物及其使用方法，包括 (a) 一种或多种织物护理酵素，这种织物护理酵素可有效防止织物纤维在洗涤过程中起球、起毛、染色和其他变质； (b) 一种或多种紫外线保护剂，这种或多种紫外线保护剂可增亮和防止光对织物 造成的褪色或其他损害； (c) 一种或多种表面活性分散剂、乳化剂和/或增溶剂，其中一种或多种表面活性分散剂、乳化剂和/或增溶剂主要由表面活性剂、助表面活性剂、水化剂和溶剂组成，用于增溶或稳定组合物； (d) 一种或多种染料转移抑制剂、防再沉积剂或染料螯合剂，其中一种或多种染料转移抑制剂、防再沉积剂或染料螯合剂可防止从其他织物上转移的染料再沉积； (e) 一种或多种染料、颜料和织物固色剂或整理保护剂，这些染料、颜料和织物固色剂或整理保护剂可锁住染料和颜料，防止它们在浸泡或水洗过程中数量或质量下降； (f) 可选的一种或多种纺织品润滑剂和/或纺织品柔软剂，润滑剂和/或纺织 品柔软剂用于包裹纺织品，减少纤维间和纤维表面的摩擦； (g) 一种或多种硬度和金属离子螯合剂和晶体生长抑制剂，硬度和金属离子螯 合剂和晶体生长抑制剂用于结合游离离子，防止形成不溶性沉淀化合物； (h) 一种或多种氯和/或活性氧清除剂或中和剂，其作用是中和氧化剂，即具有 氧化潜能的物质；以及 (i) 可选的一种或多种下列物质：处理剂、储存剂、改变弹性和粘性相性质的加工 剂、消泡剂或起泡剂、抗微生物剂、抗菌剂或抗真菌剂、 pH 缓冲剂、调节 剂、美观染料和/或香料。
• Dry-cleaning processes and components therefor
  申请人：Akbarian H. Fatemeh

  公开号：US20050049163A1

  公开（公告）日：2005-03-03

  A dispensable fluid pre-treatment composition for use in dry-cleaning of textile article processes comprising about 0.01-5.0% each of one or more surfactants selected from the group consisting of anionic surfactants and nonionic surfactants, about 0.01-2.0% amine oxide, about 0.0-1.0% preservative, about 0.01-4.0% alkali metal borate, about 50.0-99.99% fluid solvent, and dispenser for controllably dispensing the composition onto a textile article.

  一种用于纺织品干洗工艺中的可分配流体预处理组合物，包括约 0.01-5.0% 的一种或多种表面活性剂（选自阴离子表面活性剂和非离子表面活性剂组成的组）、约 0.01-2.0% 的氧化胺、约 0.0-1.0% 的防腐剂、约 0.01-4.0% 的碱金属硼酸盐、约 50.0-99.99% 的流体溶剂，以及用于将组合物可控地分配到纺织品上的分配器。