[Cu(II)(N,N'-o-phenylenebis(3-ethoxysalicylaldimine)]*H2O | 1270936-55-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: [Cu(II)(N,N'-o-phenylenebis(3-ethoxysalicylaldimine)]*H2O
• CAS: 1270936-55-4
• 化学式: C₂₄H₂₂N₂O₄*Cu*H₂O
• 分子量: 484.011
• InChiKey: JBMHBMPRLNKMNP-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  3.31
• 重原子数：
  32.0
• 可旋转键数：
  8.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  120.8
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  calcium perchlorate tetrahydrate 、 [Cu(II)(N,N'-o-phenylenebis(3-ethoxysalicylaldimine)]*H2O 以 甲醇 、 丙酮 为溶剂， 以74%的产率得到[Cu(II)(N,N'-o-phenylenebis(3-ethoxysalicylaldimine)Ca(II)(ClO4)2(H2O)]
  参考文献：
  名称：

  N,N'-o-亚苯基双(3-乙氧基水杨醛亚胺)衍生的铜(II)-主族金属配合物的合成、晶体结构和超分子拓扑结构

  摘要：

  摘要 本研究报告了 11 种铜 (II)-主族金属离子配合物 [CuIILNaI(NO3)(H2O)]·2CH3CN (1)、[CuIIILNaI(N3)(CH3OH) 的合成、晶体结构和超分子拓扑结构。 )]·CH3OH (2), [CuIILNaI(ClO4)(CH3CN)]·0.5CH3CN (3), [CuIILNaI(BF4)(CH3OH)]·H2O (4), [{CuIILNaI(H2O)}2(CuIIL) ](BPh4)2 (5), [CuIILKI(ClO4)(CH3COCH3)] (6), [CuIILCaII(ClO4)2(H2O)] (7), [{CuIILCaII(NO3)(μ-NO3)(H2O) }(CuIIL)]·H2O·CH3COCH3 (8), [(CuIIL)2BaII(NO3)2]·CH3OH (9), [CuIILPbII(NO3)2]·CH3OH (10)

  DOI：

  10.1016/j.molstruc.2011.08.005

文献信息

• Two New Diphenoxo‐Bridged Discrete Dinuclear Cu ^II Gd ^III Compounds with Cyclic Diimino Moieties: Syntheses, Structures, and Magnetic Properties
  作者：Rajesh Koner、Gene‐Hsiang Lee、Yu Wang、Ho‐Hsiang Wei、Sasankasekhar Mohanta

  DOI：10.1002/ejic.200400858

  日期：2005.4

  Two Schiff base compartmental ligands, H 2 L 1 and H 2 L 2 , derived from the condensation of 3-ethoxysalicylaldehyde with 1,2-diaminocyclohexane and orthophenylenediamine, respectively, have been utilized to isolate two diphenoxo-bridged discrete dinuclear Cu I I Gd I I I complexes, [Cu I I (H 2 O)-L 1 Gd I I I (NO 3 ) 3 ] (3) and [Cu I I L 2 Gd I I I (NO 3 ) 3 ] (4). This is the first report on the

  两个席夫碱区室配体 H 2 L 1 和 H 2 L 2 分别源自 3-乙氧基水杨醛与 1,2-二氨基环己烷和邻苯二胺的缩合，已被用于分离两个二苯氧桥连的离散双核 Cu II Gd III络合物，[Cu II (H 2 O)-L 1 Gd III (NO 3 ) 3 ] (3) 和 [Cu IIL 2 Gd III (NO 3 ) 3 ] (4)。这是关于由带环二胺的隔室 Schiff 碱配体衍生的 3d-4f 化合物的首次报告。化合物 3 和 4 分别在三斜 Pi 和正交 Pna2(1) 空间群中结晶，晶胞参数如下 - 3：a = 8.8713(2) A, b = 12.8399(3) A, c = 14.0067( 3) A, a = 80.6649(5)°, β = 77.4059(5)°, γ = 76.8879(5)°, Z = 2；4：a = 9.2210(1) A，b = 16
• Self-assembled [2×1+1×2] heterotetranuclear CuII3MnII/CuII3CoII and [2×2+1×3] heptanuclear CuII7 compounds derived from N,N′-o-phenylenebis(3-ethoxysalicylaldimine): Structures and magnetic properties
  作者：Malabika Nayak、Susanta Hazra、Pascale Lemoine、Rajesh Koner、C. Robert Lucas、Sasankasekhar Mohanta

  DOI：10.1016/j.poly.2007.12.010

  日期：2008.3

  copper(II) compound [CuIIL1⊂(H2O)] (1) derived from the hexadentate Schiff base compartmental ligand N,N′-o-phenylenebis(3-ethoxysalicylaldimine) (H2L1) has been characterized from its IR spectrum as an inclusion product. Reaction of 1 with Cu(ClO4)2 · 6H2O leads to the formation of an interesting [2 × 2 + 1 × 3] heptanuclear copper(II) complex [CuIIL1CuII(H2O)3}2 CuIIL1}3](ClO4)4 · 2CH3COCH3 (2), in which

  摘要从六齿席夫碱隔室配体N，N'-邻苯撑双（3-乙氧基水杨醛亚胺）（H2L1）衍生得到单核铜（II）化合物[CuIIL1⊂（H2O）]（1），其红外光谱为包容产品。1与Cu（ClO4）2·6 的反应导致形成有趣的[2×2 + 1×3]七核铜（II）络合物[CuIIL1CuII（ ）3} 2 CuIIL1} 3]（ ） 4·2CH3COCH3（2），其中两个单酚氧桥联的双核[CuIIL1CuII（ ）3] 2+阳离子单元是自组装的，并通过三个单核[CuIIL1]络合物单元通过配位水分子之间形成的氢键网共结晶。和苯氧/乙氧基氧。1与Co（ ）2·6 或Mn（ ）2·6 的相似反应产生[2×1 +1×2]异四核配合物[CuIIL1MII（ ）3} CuIIL1} 2]（ ）2 · ·CH3COCH3（M = Co（3），M = Mn（4
• Exploration of heterometallic systems containing silver(I) in acyclic Schiff base ligands: Finite and infinite self-assemblies as a result of silver(I)–carbon bond and silver(I)⋯silver(I) interaction
  作者：Arpita Biswas、Suraj Mondal、Leena Mandal、Arpita Jana、Priyanka Chakraborty、Sasankasekhar Mohanta

  DOI：10.1016/j.ica.2014.01.045

  日期：2014.4

  The work in this report describes the syntheses and crystal structures of nine copper(II)-silver(I) compounds derived from some single-compartment N(imine)(2)O(phenoxo)(2) or double-compartment N(imine)(2)O(phenoxo)(2)-O(phenoxo)(2)O(methoxy/ethoxy)(2) acyclic Schiff base ligands. The nine compounds are [Cu-II(ClO4)(Lsal-enAgI)}(2)Cu-II(ClO4)(Lsal-enAgI)(H2O)}](n) (1), [(CuLsal-pnAgI)-L-II(ClO4)](n) (2), [(CuLsal-pnAgI)-L-II(NO3)}(2)] (3), [((CuLacpn-en)-L-II)(2)Ag-I(MeCN)(2)](ClO4) (4), [(CuLOMe-enAgI)-L-II(NO3)}(2)] (5), [(CuLOMe-pnAgI)-L-II(NO3)}(2)] (6), [(CuLOMe-pnAgI)-L-II(NO3)}(2)]center dot 2H(2)O (7), [(CuLOEt-enAgI)-L-II(NO3)}(2)] (8) and [(CuLOEt-opAgI)-L-II(MeOH)}(2)](ClO4)(2) (9), where the superscripts in the ligand symbols mean the following: (i) sal, acpn, OMe and OEt indicate that the aldehyde counterpart is salicylaldehyde, 2-hydroxyacetophenone, 3-methoxysalicylaldehyde and 3-ethoxysalicylaldehyde, respectively; (ii) en, pn and op indicate that the diamine counterpart is ethylenediamine, 1,3-diaminopropane and o-phenylenediamine, respectively. Copper(II) in all these compounds occupies a N2O2 compartment and the two phenoxo oxygen atoms in all cases bridge one copper(II) and one silver(I) centers. Compound 4 is a trinuclear (CuAgCuII)-Ag-II-Cu-I system. Compounds 3 and 5-9 are dimer-of-dinuclear compounds, in which the dimerization takes place due to interdinuclear Cu-O(nitrate) and Ag center dot center dot center dot Ag interactions in 3, 5 and 6 and due to Ag-pi (eta(1)-/eta(2)-) bonds in 7-9. Compounds 2 and 1 are one-dimensional coordination polymers due to Ag-pi (eta(2)-)/Ag-pi (eta(3)-) bonds. CSD search/ analysis reveals some definite significant aspects in both the Ag-pi and Ag-pi (eta(3)-) bonds. CSD search/analysis reveals some definite significant aspects in both the Ag-pi and Ag center dot center dot center dot Ag bonded systems in the present investigation. (C) 2014 Elsevier B. V. All rights reserved.