monodecyl maleate | 6994-83-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: monodecyl maleate
• 英文别名: maleic acid monodecyl ester；Mono-n-decylmaleat；Monodecyl-maleinat；Mono-decylmaleat；Monodecylmaleat；n-Decyl-maleat；1-Decyl (2Z)-2-butenedioate；(Z)-4-decoxy-4-oxobut-2-enoic acid
• CAS: 6994-83-8
• 化学式: C₁₄H₂₄O₄
• 分子量: 256.342
• InChiKey: VPTNWGPGDXUKCY-KHPPLWFESA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  18
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  63.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  monodecyl maleate 在 sodium disulfite 作用下， 反应 24.0h， 生成 2-Sulfo-succinic acid 1-decyl ester
  参考文献：
  名称：

  The properties of a family of two-headed surfactant systems: the 4-alkyl-3-sulfosuccinates 2. Surface properties of alkyl sulfosuccinate micelles

  摘要：

  研究了一类双头表面活性剂——烷基磺酸琥珀酸盐的胶束性质，利用荧光、紫外光谱和酸碱滴定，以表面活性剂链长为函数。使用吡啶和离子探针8-苯胺基-1-萘磺酸铵盐（ANS）研究了胶束内部的极性。利用吡啶I₁/I₃比值来探测胶束中栅栏层中探针的微环境。使用酸碱滴定确定了两个阴离子头基的pK_a值。通过测量疏水指示剂7-羟基香豆素在磺酸琥珀酸盐胶束界面的pK_a值获得表面电位测量。所有这些结果被用来检验烷基磺酸琥珀酸盐胶束的表面性质和胶束内部的极性。关键词：胶束化、pK_a、表面电位、表面电荷密度、7-羟基香豆素、吡啶。

  DOI：

  10.1139/v99-008
• 作为产物：
  描述：

  马来酸酐 、 癸醇 反应 0.33h， 生成 monodecyl maleate
  参考文献：
  名称：

  The properties of a family of two-headed surfactant systems: the 4-alkyl-3-sulfosuccinates 2. Surface properties of alkyl sulfosuccinate micelles

  摘要：

  研究了一类双头表面活性剂——烷基磺酸琥珀酸盐的胶束性质，利用荧光、紫外光谱和酸碱滴定，以表面活性剂链长为函数。使用吡啶和离子探针8-苯胺基-1-萘磺酸铵盐（ANS）研究了胶束内部的极性。利用吡啶I₁/I₃比值来探测胶束中栅栏层中探针的微环境。使用酸碱滴定确定了两个阴离子头基的pK_a值。通过测量疏水指示剂7-羟基香豆素在磺酸琥珀酸盐胶束界面的pK_a值获得表面电位测量。所有这些结果被用来检验烷基磺酸琥珀酸盐胶束的表面性质和胶束内部的极性。关键词：胶束化、pK_a、表面电位、表面电荷密度、7-羟基香豆素、吡啶。

  DOI：

  10.1139/v99-008

文献信息

• Fluorocompound, silver halide photographic light-sensitive material, surfactant, and water-based coating composition employing same
  申请人：——

  公开号：US20020197571A1

  公开（公告）日：2002-12-26

  A fluorocompound denoted by general formula (1) below 1 (wherein R 1 denotes a substituted or unsubstituted alkyl group having a total of at least six carbon atoms, with R 1 not being an alkyl group substituted with a fluorine atom; R f denotes a perfluoroalkyl group having not more than six carbon atoms; either X 1 or X 2 denotes a hydrogen atom and the other denotes SO 3 M; M denotes a cation; and n denotes an integer of not less than 1) was disclosed. A silver halide photographic light-sensitive material having at least one layer comprising a light-sensitive silver halide emulsion layer on a support and comprising a compound denoted by general formula (1) above was also disclosed.

  通式（1）中表示的一种氟化合物（其中R1表示具有至少六个碳原子的取代或未取代烷基基团，R1不是取代有氟原子的烷基基团；Rf表示不超过六个碳原子的全氟烷基基团；X1或X2表示氢原子，另一个表示SO3M；M表示阳离子；n表示不少于1的整数）已被披露。还披露了一种包含至少一层感光银卤化物乳胶层的银卤化物感光材料，该层位于支撑物上，并包含上述通式（1）中表示的化合物。
• [EN] NEW PROPANOATES AND PROCESSES FOR PREPARING THE SAME<br/>[FR] NOUVEAUX PROPANOATES ET LEURS PROCÉDÉS DE PRÉPARATION
  申请人：DUPONT ELECTRONIC POLYMERS L P

  公开号：WO2010024841A1

  公开（公告）日：2010-03-04

  A process for preparing proponates which comprises the steps of (i) supplying a solution of methanol containing 4-hydroxyphenylmethylcarbinol, (ii) subjecting said solution to an acid catalyzed displacement reaction for a sufficient period of time and under suitable conditions of temperature and pressure to convert substantially all of said carbinol to 4-hydroxyphenylmethylcarbinol methyl ether in solution, (iii) replacing the methanol in said ether containing solution with a second solvent and (iv) reacting the ether containing ethyl lactate solution with a suitable acid catalyst for a sufficient period of time and under suitable conditions of temperature and pressure to form said propanoates. New compositions of matter which comprise the propanoates, prepared in the above manner, have application in the electronic chemicals market such as in a photoresist composition.

  一种制备丙酸酯的方法，包括以下步骤：(i)提供含有4-羟基苯甲基碳醇的甲醇溶液，(ii)将该溶液在酸催化的位移反应下，在适当的温度和压力条件下足够长的时间内转化几乎全部的碳醇为溶液中的4-羟基苯甲基碳醇甲醚，(iii)用第二溶剂取代所述醚所含甲醇的溶液，(iv)在适当的温度和压力条件下，用适当的酸催化剂反应所述醚含乙酸乙酯溶液足够长的时间，以形成所述丙酸酯。按照上述方法制备的新物质组成包括丙酸酯，在电子化学品市场上具有应用，例如在光刻胶组合物中。
• Fluorocompound, silver halide photographic light-sensitive material, surfactant, and water-based coating composition empolying same
  申请人：Fuji Photo Film Co. Ltd.

  公开号：US20040044244A1

  公开（公告）日：2004-03-04

  A fluorocompound denoted by general formula (1) below Formula (1) 1 (wherein R 1 denotes a substituted or unsubstituted alkyl group having a total of at least six carbon atoms, with R 1 not being an alkyl group substituted with a fluorine atom; R f denotes a perfluoroalkyl group having not more than six carbon atoms; either X 1 or X 2 denotes a hydrogen atom and the other denotes SO 3 M; M denotes a cation; and n denotes an integer of not less than 1) was disclosed. A silver halide photographic light-sensitive material having at least one layer comprising a light-sensitive silver halide emulsion layer on a support and comprising a compound denoted by general formula (1) above was also disclosed.

  公式（1）表示的氟化合物如下： 公式（1）1 （其中R1表示具有至少六个碳原子的取代或未取代的烷基基团，R1不是被氟原子取代的烷基基团；Rf表示不超过六个碳原子的全氟烷基基团；X1或X2表示氢原子，另一个表示SO3M；M表示阳离子；n表示不小于1的整数）。该氟化合物被揭示。 还揭示了一种银卤化物感光材料，其至少包括一层感光银卤化物乳液层在支撑体上，并包括上述一般式（1）表示的化合物。
• Free-Radical Curable Functional Macromonomers Prepared from Anhydride
  申请人：Parent J. Scott

  公开号：US20130066020A1

  公开（公告）日：2013-03-14

  A functional macromonomer, which is an isobutylene-rich polymer that homopolymerizes when initiated by a free-radical initiator, is described that has an acrylate moiety substituted by at least one substituent that bears a functional moiety. Methods of making functional macromonomers by ring-opening various anhydrides and methods of curing functional macromonomers are described. Cured products are halo-free thermosets that have only small amounts of initiator-derived byproducts and substantially no residual unreacted functionality, which is beneficial for chemical and physical stability.

  本文描述了一种功能性大分子单体，该单体是一种异丁烯富含的聚合物，当由自由基引发剂引发时，可以同聚合成聚合物，其丙烯酸酯基团被至少带有一个含有功能基团的取代基所取代。本文还描述了通过开环各种酐类制备功能性大分子单体的方法以及固化功能性大分子单体的方法。固化后的产物是无卤素热固性材料，仅含有少量引发剂衍生物，并且基本没有残留未反应的功能性，这对于化学和物理稳定性是有益的。
• HEMOLYSIS INHIBITOR AND MEDICAL RESIN COMPOSITION, MEDICAL IMPLEMENT, AND BLOOD-PRESERVING FLUID CONTAINING THE SAME
  申请人：KAO CORPORATION

  公开号：EP0334956A1

  公开（公告）日：1989-10-04

  A hemolysis inhibitor comprising a polycarboxylic acid ester, an ether compound and/or a monocarboxylic acid ester and a medical resin composition, medical implement, and blood-preserving fluid containing it. These compounds can prevent hemolysis of blood in contact therewith because of their erythrocytes-protecting activity.

  一种由聚羧酸酯、醚化合物和/或单羧酸酯组成的溶血抑制剂，以及含有它的医用树脂组合物、医用器械和血液保存液。这些化合物具有保护红细胞的活性，可防止与之接触的血液发生溶血。