bis[2-decyl-(S)-(+)-2-(6-hydroxy-2-naphthyl)propionate] | 881231-53-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: bis[2-decyl-(S)-(+)-2-(6-hydroxy-2-naphthyl)propionate]
• CAS: 881231-53-4
• 化学式: C₃₆H₄₂O₆
• 分子量: 570.726
• InChiKey: DQISZGKWEOAKBJ-UIOOFZCWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.52
• 重原子数：
  42.0
• 可旋转键数：
  15.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.39
• 拓扑面积：
  93.06
• 氢给体数：
  2.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  bis[2-decyl-(S)-(+)-2-(6-hydroxy-2-naphthyl)propionate] 、 4'-正癸氧基联苯-4-羧酸 在 4-二甲氨基吡啶 、 N,N'-二环己基碳二亚胺 作用下， 以 二氯甲烷 为溶剂， 反应 24.0h， 生成 bis{2-decyl-(S)-(+)-2-(6-[4-(4'-decyloxyphenyl)-benzoyloxy]-2-naphthyl)-propionate}
  参考文献：
  名称：

  Odd–even effect on SmC* formation in chiral liquid crystal dimers

  摘要：

  A homologues series of chiral symmetric dimer was prepared from (S)-2-(6-methoxy-2-naphthyl)propionic acid. Structural effects on the mesomorphic and physiochemical properties were investigated in terms of variation in spacer length between two mesogenic units. The mesophase textures and their corresponding transition temperatures were identified by polarised optical microscopy and DSC measurements. The prepared dimeric compounds exhibit BP, N*, SmA* and SmC*/SmB* mesophase sequence. An odd-even effect was observed in forming tilted smectic phases with various length of spacers. Compounds containing even numbers of methylene spacer form SmC* mesophase, whereas odd spacers exhibited SmB* textures. Spontaneous polarisation was measured and maximum of 33.5 nC/cm(-1) was observed for BDPNP-6. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2005.08.030
• 作为产物：
  描述：

  1,10-癸二醇 在 4-二甲氨基吡啶 、 三溴化硼 、 N,N'-二环己基碳二亚胺 作用下， 以 二氯甲烷 为溶剂， 反应 3.0h， 生成 bis[2-decyl-(S)-(+)-2-(6-hydroxy-2-naphthyl)propionate]
  参考文献：
  名称：

  Odd–even effect on SmC* formation in chiral liquid crystal dimers

  摘要：

  A homologues series of chiral symmetric dimer was prepared from (S)-2-(6-methoxy-2-naphthyl)propionic acid. Structural effects on the mesomorphic and physiochemical properties were investigated in terms of variation in spacer length between two mesogenic units. The mesophase textures and their corresponding transition temperatures were identified by polarised optical microscopy and DSC measurements. The prepared dimeric compounds exhibit BP, N*, SmA* and SmC*/SmB* mesophase sequence. An odd-even effect was observed in forming tilted smectic phases with various length of spacers. Compounds containing even numbers of methylene spacer form SmC* mesophase, whereas odd spacers exhibited SmB* textures. Spontaneous polarisation was measured and maximum of 33.5 nC/cm(-1) was observed for BDPNP-6. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2005.08.030

文献信息

• Synthesis and mesomorphic behavior of symmetrical chiral liquid crystal dimers incorporating ester linked biphenyl- naphthyl cores and terminal vinyl group
  作者：Lakshmi C. Kasi Viswanath、Sengodan Senthil

  DOI：10.1080/15421406.2017.1386518

  日期：2017.10.13

  ABSTRACT A series of symmetrical chiral, liquid crystal dimeric molecules possessing ester- linked, biphenyl-naphthyl cores with varied spacer lengths and terminal vinyl groups have been synthesized using Naproxen as the synthetic precursor. The synthesized symmetrical chiral dimers were characterized by 1H NMR spectroscopy, and their liquid crystalline behavior was confirmed by DSC and HOPM studies.

  摘要 使用萘普生作为合成前体合成了一系列对称的手性液晶二聚分子，这些分子具有酯连接的联苯-萘基核，具有不同的间隔长度和末端乙烯基。合成的对称手性二聚体通过 1 H NMR 光谱表征，其液晶行为通过 DSC 和 HOPM 研究证实。根据手性链长度的变化研究了对介晶和物理化学性质的结构影响。合成的二聚化合物表现出 SmX*、SmC*、SmA*、N*、BPI* 和 BPII* 中间相序列。在二聚体中观察到奇偶效应，中间相的持续时间随着间隔长度的增加而减少。