1,4-Bis<2-<2-<2-<2-(4-hydroxyphenoxy)-ethoxy>ethoxy>ethoxy>ethoxy>benzol | 134940-40-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 1,4-Bis<2-<2-<2-<2-(4-hydroxyphenoxy)-ethoxy>ethoxy>ethoxy>ethoxy>benzol
• 英文别名: 1,4-bis<2-<2-<2-<2-(hydroxyphenoxy)ethoxy>ethoxy>ethoxy>ethoxy>benzene；1,4-bis<2-(2-(2-(2-(4-hydroxyphenoxy)ethoxy)ethoxy)ethoxy)ethoxy>benzene；1,4-Bis[2-(2-{2-[2-(4-hydroxyphenoxy)-ethoxy]ethoxy}ethoxy)ethoxy]benzol
• CAS: 134940-40-2
• 化学式: C₃₄H₄₆O₁₂
• 分子量: 646.732
• InChiKey: OFROZJPZCXGYNP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.11
• 重原子数：
  46.0
• 可旋转键数：
  28.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.47
• 拓扑面积：
  132.76
• 氢给体数：
  2.0
• 氢受体数：
  12.0

反应信息

• 作为反应物：
  描述：

  1,4-Bis<2-<2-<2-<2-(4-hydroxyphenoxy)-ethoxy>ethoxy>ethoxy>ethoxy>benzol 在 sodium hydride 、 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 8.0h， 生成 1,4-bis<2-<2-<2-<2-<<2-<2-<2-<2-(4-benzyloxyphenoxy)ethoxy>ethoxy>ethoxy>ethoxy>phenoxy>ethoxy>ethoxy>ethoxy>ethoxy>benzene
  参考文献：
  名称：

  Amabilino, David B.; Anelli, Pier-Lucio; Ashton, Peter R., Journal of the American Chemical Society, 1995, vol. 117, # 45, p. 11142 - 11170

  摘要：

  DOI：
• 作为产物：
  描述：

  2,2'-[1,4-亚苯基二(氧基-2,1-乙二基氧基)]二乙醇 在 palladium on activated charcoal 氢气 、 sodium hydride 作用下， 以 甲醇 、 氯仿 为溶剂， 反应 25.0h， 生成 1,4-Bis<2-<2-<2-<2-(4-hydroxyphenoxy)-ethoxy>ethoxy>ethoxy>ethoxy>benzol
  参考文献：
  名称：

  Amabilino, David B.; Anelli, Pier-Lucio; Ashton, Peter R., Journal of the American Chemical Society, 1995, vol. 117, # 45, p. 11142 - 11170

  摘要：

  DOI：

文献信息

• Molecular Meccano. 2. Self-Assembly of [n]Catenanes
  作者：David B. Amabilino、Peter R. Ashton、Christopher L. Brown、Emilio Cordova、Luis A. Godinez、Timothy T. Goodnow、Angel E. Kaifer、Simon P. Newton、Marek Pietraszkiewicz

  DOI：10.1021/ja00109a011

  日期：1995.2

  The mutual molecular recognition between different: structural components in large rings has led to the template-directed synthesis of a wide range of catenanes composed of from two to five interlocked rings, The molecular self-assembly processes rely upon the recognition between (i) pi-electron rich and pi-electron deficient aromatic units and (ii) hydrogen bond donors and accepters, in the different components. In order to increase Our knowledge of the factors involved in such molecular self-assembly processes, a homologous series of [2]catenanes has been constructed using macrocyclic polyethers of the bis(p-phenylene)-(3n+4)-crown-n (n = 9-14) type as templates for the formation of the tetracationic cyclophane, cyclobis(paraquat-p-phenylene). Increasing the size of the tetracationic cyclophane to cyclobis(paraquat-4,4'-bitolyl) allows the simultaneous entrapment of two hydroquinone ring-containing macrocyclic polyethers affording a series of [3]catenanes, and one [4]catenane incorporating a cyclic dimer of the expanded cyclophane and three bis(p-phenylene)-34-crown-10 components. By analogy; increasing the number of hydroquinone rings in the macrocyclic polyether permits the self-assembly of more than one tetracationic cyclophane around the templates present in the macrocyclic polyether. In this context, the template-directed synthesis of two [3]catenanes, incorporating two cyclobis(paraquat-p-phenylene) components and either (i) tris(p-phenylene)51-crown-15 or (ii) tetrakis (p-phenylene)-68-crown-20, has been achieved and is reported. A combination of these two approaches has led to the successful self-assembly, in two steps, of a linear [4]catenane, together with a small amount of a [5]catenane: The creation of these intricate molecular compounds lends support to the contention that self-assembly is a viable paradigm for the construction of nanometer-scale molecular architectures incorporating a selection of simple components.
• Ashton, Peter R.; Brown, Christopher L.; Chrystal, Ewan J. T., Angewandte Chemie, 1991, vol. 103, # 8, p. 1058 - 1061
  作者：Ashton, Peter R.、Brown, Christopher L.、Chrystal, Ewan J. T.、Parry, Keith P.、Pietraszkiewicz, Marek、et al.

  DOI：——

  日期：——
• Amabilino, David B.; Ashton, Peter R.; Reder, Anatoli S., Angewandte Chemie, 1994, vol. 106, # 4, p. 450 - 453
  作者：Amabilino, David B.、Ashton, Peter R.、Reder, Anatoli S.、Spencer, Neil、Stoddart, J. Fraser

  DOI：——

  日期：——