[Zn(H2O)(1.3-propanediylbis(2-iminomethylene-6-methoxyphenolato))] | 1214254-71-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: [Zn(H2O)(1.3-propanediylbis(2-iminomethylene-6-methoxyphenolato))]
• 英文别名: [Zn(H2O)(o-vanillin-2H)]
• CAS: 1214254-71-3
• 化学式: C₁₉H₂₂N₂O₅Zn
• 分子量: 423.784
• InChiKey: YYWDIWFERDWGIJ-ZOTBWGAJSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  neodymium(III) nitrate hexahydrate 、 [Zn(H2O)(1.3-propanediylbis(2-iminomethylene-6-methoxyphenolato))] 以 乙腈 为溶剂， 生成 [Zn(H2O)(o-vanillin-2H)Nd(O2NO)3]
  参考文献：
  名称：

  Study of the Luminescent and Magnetic Properties of a Series of Heterodinuclear [Zn^IILn^III] Complexes

  摘要：

  Herein, we report the synthesis, structural investigation, and magnetic and photophysical properties of a series of 13 [Zn(II)Ln(III)] heterodinuclear complexes, which have been obtained employing a Schiff-base compartmental ligand derived from o-vanillin [H(2)valpn = 1,3-propanediylbis(2-iminomethylene-6-methoxy-phenol)]. The complexes have been synthesized starting from the [Zn(valpn)(H2O)] mononuclear compound and the corresponding lanthanide nitrates. The crystallographic investigation indicated two structural types: the first one, [Zn(H2O)(valpn)Ln(III)(O2NO)(3)], contains 10-coordinated Ln(III) ions, while in the second one, [Zn(ONO2)(valpn)Ln(III)(H2O)(O2NO)(2)] center dot 2H(2)O, the rare earth ions are nine-coordinated. The Zn-II ions always display a square-pyramidal geometry. The first structural type encompasses the larger Ln ions (4f(0)-4f(9)), while the second is found for the smaller ions (4f(8)-4f(11)). The dyskrosium derivative crystallizes in both forms. Luminescence studies for the heterodinuclear compounds containing Nd-III, Sm-III, Tb-III, Dy-III, and Yb-III revealed that the [Zn(valpn)(H2O)] moiety acts as an antenna. The magnetic properties for the paramagnetic [Zn(II)Ln(III)] complexes have been investigated.

  DOI：

  10.1021/ic200426w
• 作为产物：
  描述：

  zinc(II) nitrate hexahydrate 、 N,N'-bis(3-methoxysalicylidene)-1,3-propanediamine 在 1,3-diaminopropane 、 triethylamine 作用下， 以 四氢呋喃 、 水 为溶剂， 以75%的产率得到[Zn(H2O)(1.3-propanediylbis(2-iminomethylene-6-methoxyphenolato))]
  参考文献：
  名称：

  Study of the Luminescent and Magnetic Properties of a Series of Heterodinuclear [Zn^IILn^III] Complexes

  摘要：

  Herein, we report the synthesis, structural investigation, and magnetic and photophysical properties of a series of 13 [Zn(II)Ln(III)] heterodinuclear complexes, which have been obtained employing a Schiff-base compartmental ligand derived from o-vanillin [H(2)valpn = 1,3-propanediylbis(2-iminomethylene-6-methoxy-phenol)]. The complexes have been synthesized starting from the [Zn(valpn)(H2O)] mononuclear compound and the corresponding lanthanide nitrates. The crystallographic investigation indicated two structural types: the first one, [Zn(H2O)(valpn)Ln(III)(O2NO)(3)], contains 10-coordinated Ln(III) ions, while in the second one, [Zn(ONO2)(valpn)Ln(III)(H2O)(O2NO)(2)] center dot 2H(2)O, the rare earth ions are nine-coordinated. The Zn-II ions always display a square-pyramidal geometry. The first structural type encompasses the larger Ln ions (4f(0)-4f(9)), while the second is found for the smaller ions (4f(8)-4f(11)). The dyskrosium derivative crystallizes in both forms. Luminescence studies for the heterodinuclear compounds containing Nd-III, Sm-III, Tb-III, Dy-III, and Yb-III revealed that the [Zn(valpn)(H2O)] moiety acts as an antenna. The magnetic properties for the paramagnetic [Zn(II)Ln(III)] complexes have been investigated.

  DOI：

  10.1021/ic200426w

文献信息

• Ascorbic acid decomposition into oxalate ions: a simple synthetic route towards oxalato-bridged heterometallic 3d–4f clusters
  作者：Alina S. Dinca、Sergiu Shova、Adrian E. Ion、Catalin Maxim、Francesc Lloret、Miguel Julve、Marius Andruh

  DOI：10.1039/c5dt00778j

  日期：——

  Dodecanuclear and hexanuclear heterometallic 3d–4f clusters have been obtained by connecting the lanthanide ions through oxalato bridges arising from the slow decomposition of the l-ascorbic acid.

  通过将镧系离子通过源自l-抗坏血酸的缓慢分解产生的草酸桥连接起来，得到了十二核和六核异核3d–4f团簇。
• Single-Molecule Magnet Behavior of 1D Coordination Polymers Based on DyZn₂(salen)₂ Units and Pyridin-<i>N</i>-Oxide-4-Carboxylate: Structural Divergence and Magnetic Regulation
  作者：Cai-Ming Liu、De-Qing Zhang、Jing-Bu Su、Yi-Quan Zhang、Dao-Ben Zhu

  DOI：10.1021/acs.inorgchem.8b01653

  日期：2018.9.4

  anions. Complex 2 with the formula [Dy3Zn7(Lb)6(POC)6](OH)3(ClO4)2}·9H2O [H2Lb] = N,N′-bis(3-methoxysalicylidene)-1,2-diaminoethane] is also an ionic compound containing isolated hydroxide and perchlorate anions, but its cation shows a novel nanowire structure, in which six-coordinate zinc(II) ions with C3 symmetry act as the axis and [DyZn2(Lb)2(POC)]2+ structural units as spiral leaves. Complex 1 shows

  通过溶剂热反应制备了由DyZn 2（salen）2单元和吡啶-N-氧化物-4-羧酸酯组成的两种一维配位聚合物。复杂1与式[DyZn 2（L一）2（POC）]（OH）（CLO 4）}·H 2 O·MeOH中[H 2大号一个] = Ñ，Ñ ' -双（3- methoxysalicylidene） -1,3-二氨基丙烷，POC – =吡啶-N-氧化物-4-羧酸盐]由之字形链阳离子[DyZn 2（L a）2（POC）] n组成2 n +以及分离的氢氧根和高氯酸根阴离子。复杂2与式[镝3的Zn 7（L b）6（POC）6 ]（OH）3（CLO 4）2 }·9H 2 ö[H 2大号b ] = Ñ，Ñ ' -双（3- [-甲氧基水杨基] -1,2-二氨基乙烷]也是一种离子化合物，包含离析的氢氧根和高氯酸根阴离子，但其阳离子显示出新颖的纳米线结构，其中具有C 3对称性的六配位锌（II）离子充当轴， [DyZn2（L
• Transition-metal Schiff-base complexes as ligands in tin chemistry Part 6. Reactions of diorganotin(IV) dinitrates with M(3MeO-sal1,3pn) [M = Ni, Co or Zn; H23MeO-sal1,3pn = N,N′-bis(3-methoxysalicylidene)-propane-1,3-diamine]
  作者：Mary Boyce、Brenda Clarke、Desmond Cunningham、John F. Gallagher、Tim Higgins、Patrick McArdle、Máire NíCholchúin、Margaret O'Gara

  DOI：10.1016/0022-328x(95)05523-r

  日期：1995.8

  Reactions of diorganotin(IV) dinitrates with M(3MeO-sal1,3pn) · H2O (M = Ni, Co or Zn; H23MeO-sal1,3pn = N,N′-bis(3-methoxysalicylidene)propane-1,3-diamine) leads to nitrate migration from tin to the transition metal or zinc and the formation of intimate ion-paired bimetallic addition complexes. In each of these complexes the tin atom is located in the plane of the Schiff-base oxygens and is coordinated

  二硝酸二有机锡（IV）与M（3MeO-sal1,3pn）·H 2 O（M = Ni，Co或Zn; H 2 3MeO-sal1,3pn = N，N'-双（3-甲氧基水杨基）丙烷-的反应1,3-二胺）导致硝酸盐从锡迁移到过渡金属或锌，并形成紧密的离子对双金属加成络合物。在这些络合物中的每一个中，锡原子都位于席夫碱氧的平面中，并且由所有四个原子配位。络合物[SnBz 2（NO 3）]·[M（3MeO-sal1,3pn）（NO 3）]（M = Co或Zn）是同构的，并且在五边形双锥体环境中每个都包含锡，其中四个席夫碱氧和硝酸盐氧定义了赤道面。在[SnMe 2 ]·[Ni（3MeO-sal1,3pn）（NO 3）（H 2 O）]} NO 3的情况下，锡是六配位的，但还有一个弱的分子间SnO涉及硝酸盐的氧与镍配位的相互作用。络合物[SnMe 2（H 2 O）]·[Co（3MeO-sal1,3pn）（NO