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1,8-bis[(hydroxyethyl)oxy]anthraquinone | 880758-62-3

中文名称
——
中文别名
——
英文名称
1,8-bis[(hydroxyethyl)oxy]anthraquinone
英文别名
1,8-bis(2-hydroxyethoxy)anthraquinone;1,8-Bis(2-hydroxyethoxy)anthracene-9,10-dione
1,8-bis[(hydroxyethyl)oxy]anthraquinone化学式
CAS
880758-62-3
化学式
C18H16O6
mdl
——
分子量
328.321
InChiKey
VGBFJIMBMGKBOH-UHFFFAOYSA-N
BEILSTEIN
——
EINECS
——
  • 物化性质
  • 计算性质
  • ADMET
  • 安全信息
  • SDS
  • 制备方法与用途
  • 上下游信息
  • 反应信息
  • 文献信息
  • 表征谱图
  • 同类化合物
  • 相关功能分类
  • 相关结构分类

计算性质

  • 辛醇/水分配系数(LogP):
    1.4
  • 重原子数:
    24
  • 可旋转键数:
    6
  • 环数:
    3.0
  • sp3杂化的碳原子比例:
    0.22
  • 拓扑面积:
    93.1
  • 氢给体数:
    2
  • 氢受体数:
    6

上下游信息

  • 上游原料
    中文名称 英文名称 CAS号 化学式 分子量
  • 下游产品
    中文名称 英文名称 CAS号 化学式 分子量

反应信息

  • 作为反应物:
    描述:
    1,8-bis[(hydroxyethyl)oxy]anthraquinone正丁基锂对甲苯磺酸 作用下, 以 四氢呋喃正己烷二氯甲烷 为溶剂, 反应 2.5h, 生成 2,2'-((((9,10-bis(4,5-bis(methylthio)-1,3-dithiol-2-ylidene)-9,10-dihydroanthracene-1,8-diyl)bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(tetrahydro-2H-pyran)
    参考文献:
    名称:
    Novel 9,10-Bis(1,3-dithiol-2-ylidene)-9,10- dihydroanthracene Derivatives Bridged by a Crown Ether Unit at the 1,8-Positions: A New Type of Redox-switchable Hosts Undergoing Reversible Structural Changes
    摘要:
    Novel redox-switchable host molecules (2) composed of a 9,10-bis(1,3-dithiol-2-ylidene)-9,10-dihydroanthracene unit and a crown ether moiety bridging the 1,8-positions have been synthesized. Cyclic voltammetry and X-Ray analyses revealed that the molecules undergo a significant structural change upon oxidation. 'H-NMR titration experiments on the neutral and dication states show that the binding abilities of the dication states for alkali metal cations (Li+, Na+, K+) are considerably lower than those of the neutral molecules. The binding properties of 2 were also investigated by cyclic voltammetry.
    DOI:
    10.3987/com-05-s(t)55
  • 作为产物:
    描述:
    参考文献:
    名称:
    Novel 9,10-Bis(1,3-dithiol-2-ylidene)-9,10- dihydroanthracene Derivatives Bridged by a Crown Ether Unit at the 1,8-Positions: A New Type of Redox-switchable Hosts Undergoing Reversible Structural Changes
    摘要:
    Novel redox-switchable host molecules (2) composed of a 9,10-bis(1,3-dithiol-2-ylidene)-9,10-dihydroanthracene unit and a crown ether moiety bridging the 1,8-positions have been synthesized. Cyclic voltammetry and X-Ray analyses revealed that the molecules undergo a significant structural change upon oxidation. 'H-NMR titration experiments on the neutral and dication states show that the binding abilities of the dication states for alkali metal cations (Li+, Na+, K+) are considerably lower than those of the neutral molecules. The binding properties of 2 were also investigated by cyclic voltammetry.
    DOI:
    10.3987/com-05-s(t)55
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文献信息

  • Copolymerizable methine and anthraquinone compounds and articles containing them
    申请人:Pearson Clay Jason
    公开号:US20060115516A1
    公开(公告)日:2006-06-01
    This invention relates to polymerizable ultraviolet light absorbers and yellow colorants and their use in ophthalmic lenses. In particular, this invention relates to polymerizable ultraviolet light absorbing methine compounds and yellow compounds of the methine and anthraquinone classes that block ultraviolet light and/or violet-blue light transmission through ophthalmic lenses.
    这项发明涉及可聚合的紫外光吸收剂和黄色染料,以及它们在眼镜镜片中的应用。具体而言,这项发明涉及可聚合的紫外光吸收亚甲基化合物和亚甲基和蒽醌类化合物,这些化合物通过眼镜镜片阻挡紫外光和/或紫蓝光的透射。
  • Anthraquinones as Artificial DNA Building Blocks
    作者:Nicolas Bouquin、Vladimir L. Malinovskii、Robert Häner
    DOI:10.1002/ejoc.200800080
    日期:2008.5
    Synthesis and properties of oligodeoxynucleotides containing anthraquinone-derived building blocks with flexible linkers are described. Starting from the 1,4-, 1,5-, 1,8- and 2,6-dihydroxyanthraquinone isomers, the corresponding phosphoramidites were prepared and incorporated into oligonucleotides. The site of linker attachment was found to be of critical importance for hybrid stability. Whereas the
    描述了含有蒽醌衍生结构单元和柔性接头的寡脱氧核苷酸的合成和性质。从 1,4-、1,5-、1,8- 和 2,6- 二羟基蒽醌异构体开始,制备相应的亚磷酰胺并将其掺入寡核苷酸中。发现接头附着位点对于杂交稳定性至关重要。虽然 2,6-异构体导致显着的稳定性,但所有其他异构体对双链体的稳定性有负面影响。光谱研究表明蒽醌类具有荧光猝灭剂的作用。提出了蒽醌修饰的双链杂种模型。(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
  • COPOLYMERIZABLE METHINE AND ANTHRAQUINONE COMPOUNDS AND ARTICLES CONTAINING THEM
    申请人:Abbott Medical Optics Inc.
    公开号:EP1815274B1
    公开(公告)日:2011-09-21
  • US8360576B2
    申请人:——
    公开号:US8360576B2
    公开(公告)日:2013-01-29
  • US8501890B2
    申请人:——
    公开号:US8501890B2
    公开(公告)日:2013-08-06
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齐斯托醌 黄决明素 马普替林杂质E(N-甲基马普替林) 马普替林杂质D 马普替林 颜料黄199 颜料黄147 颜料黄123 颜料黄108 颜料红89 颜料红85 颜料红251 颜料红177 颜料紫27 顺式-1-(9-蒽基)-2-硝基乙烯 阿美蒽醌 阳离子蓝3RL 长蠕孢素 镁蒽四氢呋喃络合物 镁蒽 锈色洋地黄醌醇 锂钠2-[[4-[[3-[(4-氨基-9,10-二氧代-3-磺基-1-蒽基)氨基]-2,2-二甲基-丙基]氨基]-6-氯-1,3,5-三嗪-2-基]氨基]苯-1,4-二磺酸酯 锂胭脂红 链蠕孢素 铷离子载体I 铝洋红 铂(2+)二氯化1-({2-[(2-氨基乙基)氨基]乙基}氨基)蒽-9,10-二酮(1:1) 钾6,11-二氧代-6,11-二氢-1H-蒽并[1,2-d][1,2,3]三唑-4-磺酸酯 钠6,11-二氧代-6,11-二氢-1H-蒽并[1,2-d][1,2,3]三唑-4-磺酸酯 钠4-({4-[乙酰基(乙基)氨基]苯基}氨基)-1-氨基-9,10-二氧代-9,10-二氢-2-蒽磺酸酯 钠2-[(4-氨基-9,10-二氧代-3-磺基-9,10-二氢-1-蒽基)氨基]-4-{[2-(磺基氧基)乙基]磺酰基}苯甲酸酯 钠1-氨基-9,10-二氢-4-[[4-(1,1-二甲基乙基)-2-甲基苯基]氨基]-9,10-二氧代蒽-2-磺酸盐 钠1-氨基-4-[(3-{[(4-甲基苯基)磺酰基]氨基}苯基)氨基]-9,10-二氧代-9,10-二氢-2-蒽磺酸酯 钠1-氨基-4-[(3,4-二甲基苯基)氨基]-9,10-二氧代-9,10-二氢-2-蒽磺酸酯 钠1-氨基-4-(1,3-苯并噻唑-2-基硫基)-9,10-二氧代蒽-2-磺酸盐 醌茜隐色体 醌茜素 酸性蓝127:1 酸性紫48 酸性紫43 酸性兰62 酸性兰25 酸性兰182 酸性兰140 酸性兰138 酸性兰 129 透明蓝R 透明蓝AP 透明红FBL 透明紫BS