2-Methyl-2-ethyl-oxetan | 23206-28-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧杂环丁烷
• 英文名称: 2-Methyl-2-ethyl-oxetan
• 英文别名: 2-Ethyl-2-methyl-oxetane；2-ethyl-2-methyloxetane
• CAS: 23206-28-2
• 化学式: C₆H₁₂O
• 分子量: 100.161
• InChiKey: KSDFCMCZNDNYSA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  7
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-Methyl-2-ethyl-oxetan 在 sodium hydroxide 、 硫酸 作用下， 以 四氯化碳 为溶剂， 生成 3-Methyl-3-amino-pentanol-1
  参考文献：
  名称：

  Portnyagin,Yu.M. et al., Journal of Organic Chemistry USSR (English Translation), 1974, vol. 10, p. 96 - 98

  摘要：

  DOI：
• 作为产物：
  描述：

  3-甲基戊烷 在 氧气 作用下， 351.84 ℃ 、106.0 kPa 条件下， 生成 聚合甲醛 、 丙酸 、 溶剂黄146 、 乙烯酮 、 乙烯 、 乙醛 、 环氧乙烷 、 乙炔 、 甲醇 、 乙烷 、 methyloxirane 、 2-丁烯 、 丁烯酮 、 丙炔 、 1,3-丁二烯 、 丁酮 、 2-Methyl-2-ethyl-oxetan 、 丙二烯 、 3-ethyl tetrahydrofuran 、 四氢-4-甲基-2H-吡喃 、 2beta,3beta,4alpha-三甲基氧杂环丁烷 、 2,3-dimethyltetrahydrofuran 、 methane
  参考文献：
  名称：

  Experimental Investigation of the Low Temperature Oxidation of the Five Isomers of Hexane

  摘要：

  The low-temperature oxidation of the five hexane isomers (n-hexane, 2-methyl-pentane, 3-methyl-pentane, 2,2-dimethylbutane, and 2,3-dimethylbutane) was studied in a jet-stirred reactor (JSR) at atmospheric pressure under stoichiometric conditions between 550 and 1000 K. The evolution of reactant and product mole fraction profiles were recorded as a function of the temperature using two analytical methods: gas chromatography and synchrotron vacuum ultraviolet photoionization mass spectrometry (SVUV-PIMS). Experimental data obtained with both methods were in good agreement for the five fuels. These data were used to compare the reactivity and the nature of the reaction products and their distribution. At low temperature (below 800 K), n-hexane was the most reactive isomer. The two methyl-pentane isomers have about the same reactivity, which was lower than that of n-hexane. 2,2-Dimethylbutane was less reactive than the two methyl-pentane isomers, and 2,3-dimethylbutane was the least reactive isomer. These observations are in good agreement with research octane numbers given in the literature. Cyclic ethers with rings including 3, 4, 5, and 6 atoms have been identified and quantified for the five fuels. While the cyclic ether distribution was notably more detailed than in other literature of JSR studies of branched alkane oxidation, some oxiranes were missing among the cyclic ethers expected from methyl-pentanes. Using SVUV-PIMS, the formation of C-2-C-3 monocarboxylic acids, ketohydroperoxides, and species with two carbonyl groups have also been observed, supporting their possible formation from branched reactants. This is in line with what was previously experimentally demonstrated from linear fuels. Possible structures and ways of decomposition of the most probable ketohydroperoxides were discussed. Above 800 K, all five isomers have about the same reactivity, with a larger formation from branched alkanes of some unsaturated species, such as allene and propyne, which are known to be soot precursors.

  DOI：

  10.1021/jp503772h

文献信息

• ISOQUINOLIN-3-YL CARBOXAMIDES AND PREPARATION AND USE THEREOF
  申请人：Samumed, LLC

  公开号：US20170313681A1

  公开（公告）日：2017-11-02

  Isoquinoline compounds for treating various diseases and pathologies are disclosed. More particularly, the present disclosure concerns the use of an isoquinoline compound or analogs thereof, in the treatment of disorders characterized by the activation of Wnt pathway signaling (e.g., cancer, abnormal cellular proliferation, angiogenesis, Alzheimer's disease, lung disease, inflammation, auto-immune diseases and osteoarthritis), the modulation of cellular events mediated by Wnt pathway signaling, as well as neurological conditions/disorders/diseases linked to overexpression of DYRK1A.

  揭示了用于治疗各种疾病和病理的异喹啉化合物。更具体地，本公开涉及使用异喹啉化合物或其类似物治疗由Wnt途径信号激活所特征的疾病（例如癌症、异常细胞增殖、血管生成、阿尔茨海默病、肺部疾病、炎症、自身免疫疾病和骨关节炎），以及通过Wnt途径信号介导的细胞事件的调节，以及与DYRK1A过表达相关的神经状况/疾病/疾病。
• RESIN COMPOSITION AND SEMICONDUCTOR DEVICE BOARD
  申请人：Osaku Yumi

  公开号：US20140087136A1

  公开（公告）日：2014-03-27

  A resin composition which contains a binder resin (A), radiation-sensitive compound (B), silane-modified resin (C), and antioxidant (D), wherein a content of the silane-modified resin (C) is 0.1 to 150 parts by weight with respect to 100 parts by weight of the binder resin (A), a content of the antioxidant (D) is 0.1 to 10 parts by weight with respect to 100 parts by weight of the binder resin (A), and an amount of warping is 14 μm or less when using the resin composition to form a thickness 2 to 3 μm resin film and baking the formed resin film at 230° C. is provided.

  一种树脂组合物，包含粘合剂树脂（A），辐射敏感化合物（B），硅改性树脂（C）和抗氧化剂（D），其中硅改性树脂（C）的含量相对于100份粘合剂树脂（A）为0.1至150份重量，抗氧化剂（D）的含量相对于100份粘合剂树脂（A）为0.1至10份重量，并且使用该树脂组合物形成2至3μm厚度的树脂膜并在230°C下烘烤形成的树脂膜翘曲量为14μm或以下。
• RESIN COMPOSITION FOR OPTICAL MATERIAL, RESIN FILM FOR OPTICAL MATERIAL, AND OPTICAL WAVEGUIDE USING THEM
  申请人：Hitachi Chemical Company, Ltd.

  公开号：EP2112181A1

  公开（公告）日：2009-10-28

  The present invention relates to a resin composition for an optical material comprising (A) a carboxylic acid-modified phenoxy resin, (B) a polymerizable compound and (C) a polymerization initiator, a resin film for an optical material comprising the above resin composition and an optical waveguide having a core part and/or a cladding layer formed by using the same. Provided are a resin composition for an optical material which is excellent in a heat resistance and a transparency and which is soluble in an alkaline aqueous solution, a resin film for an optical material comprising the above resin composition and an optical waveguide produced by using the same.

  本发明涉及一种光学材料用树脂组合物，该组合物由(A)羧酸改性苯氧树脂、(B)可聚合化合物和(C)聚合引发剂组成；还涉及一种光学材料用树脂膜，该膜由上述树脂组合物组成；还涉及一种光波导，该光波导具有由上述树脂组合物形成的芯部和/或包层。本发明提供了一种耐热性和透明性优良且可溶于碱性水溶液的光学材料用树脂组合物、一种由上述树脂组合物构成的光学材料用树脂膜和一种使用该树脂组合物生产的光波导。
• PHOTOSENSITIVE RESIN COMPOSITION, CURED PHOTOSENSITIVE RESIN PRODUCT, PHOTOSENSITIVE RESIN FILM, CURED PHOTOSENSITIVE RESIN FILM PRODUCT, AND OPTICAL WAVEGUIDE PRODUCED BY USING THOSE PRODUCTS
  申请人：Hitachi Chemical Company, Ltd.

  公开号：EP2182410A1

  公开（公告）日：2010-05-05

  Provided are a photosensitive resin composition which is soluble in an alkaline aqueous solution and which has a good propagation loss in a visible light wavelength region, a photosensitive resin cured matter, a photosensitive resin film, a photosensitive resin film cured matter and an optical waveguide obtained by using the same. Provided are, to be specific, a photosensitive resin composition comprising (A) a vinyl polymer having at least one chain-polymerizable functional group in a molecule, (B) a polymerizable compound and (C) a polymerization initiator, wherein the component (C) is at least one selected from the group consisting of 2-[2-oxo-2-phenylacetoxyethoxy]ethyl oxyphenylacetate, 2-(2-hydroxyethoxy)ethyl oxyphenylacetate and oligo2-hyroxy-2-methyl-1-[4-(1-methylvinyl)phenyl]}propanone, a photosensitive resin cured matter, a photosensitive resin film, a photosensitive resin film cured matter and an optical waveguide obtained by using the same.

  本发明提供了一种可溶于碱性水溶液且在可见光波长区域具有良好传播损耗的光敏树脂组合物、光敏树脂固化物、光敏树脂薄膜、光敏树脂薄膜固化物以及使用该组合物获得的光波导。 具体地说，提供了一种光敏树脂组合物，该组合物包含（A）分子中至少有一个可链聚官能团的乙烯基聚合物，（B）可聚合化合物和（C）聚合引发剂，其中组分（C）至少选自由 2-[2-氧代-2-苯乙酰氧基乙氧基]氧代苯乙酸乙酯组成的组中的一种、2-(2-羟基乙氧基)乙基氧苯乙酸酯和低聚2-羟基-2-甲基-1-[4-(1-甲基乙烯基)苯基]}丙酮、光敏树脂固化物、光敏树脂薄膜、光敏树脂薄膜固化物和光导波导中的至少一种。
• HYDROPHILIC FILM
  申请人：Mitsui Chemicals, Inc.

  公开号：EP2256153A1

  公开（公告）日：2010-12-01

  The present invention provides a hydrophilic film that has high adhesion to inorganic materials and is safer and excellent in transparency and also exhibits both very high hydrophilicity and abrasion resistance, and also provides a laminate including the hydrophilic film. The hydrophilic film is produced by applying a specific hydrophilic compound (c) having an acryloyl group and a potassium sulfonate group or the like to a surface of a layer formed from a mixture containing a silane compound (a) including one silicon atom, a mercapto group or the like, and at least one silicon-bonded group selected from the group consisting of an alkoxy group, a halogen group, and a hydroxy group, and a silane compound (b) including at least four silicon-bonded groups selected from the group consisting of an alkoxy group, a halogen group, and a hydroxy group and not including groups reactive with a carbon-carbon double bond, and allowing a reaction between at least a part of acryloyl groups contained in the hydrophilic compound (c) and at least a part of mercapto groups derived from the compound (a).

  本发明提供了一种亲水薄膜，它与无机材料有很高的附着力，而且更安全，透明度极佳，同时还具有很高的亲水性和耐磨性，本发明还提供了一种包括该亲水薄膜的层压板。亲水膜是通过在由硅烷化合物（a）（包括一个硅原子、一个巯基或类似基团，以及至少一个从烷氧基、卤素基团和羟基组成的组中选出的硅键合基团）和硅烷化合物（b）的混合物形成的层的表面上涂敷具有丙烯酰基和磺酸钾基团或类似基团的特定亲水化合物（c）而制成的、硅烷化合物（b），包括至少四个硅键合基团，这些基团选自由烷氧基、卤素基和羟基组成的组，但不包括与碳碳双键反应的基团，并允许亲水性化合物（c）中所含的至少一部分丙烯酰基与来自化合物（a）的至少一部分巯基发生反应。