双十二烷基苯 | 99948-83-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 双十二烷基苯
• 英文名称: 1,2-didodecyl benzene
• 英文别名: o-Didodecyl-benzol；bisdodecylbenzene；1,2-Didodecylbenzene
• CAS: 99948-83-1；39888-70-5
• 化学式: C₃₀H₅₄
• 分子量: 414.759
• InChiKey: WJECKFZULSWXPN-UHFFFAOYSA-N

物化性质

• 沸点：
  >241 °C(Press: 10 Torr)
• 密度：
  0.8761 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  14.3
• 重原子数：
  30
• 可旋转键数：
  22
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  双十二烷基苯 在 copper(l) iodide 、 四(三苯基膦)钯 、 periodic acid dihydrate 、 硫酸 、 四丁基氟化铵 、 碘 、 乙酸酐 、 三乙胺 作用下， 以 四氢呋喃 、 水 、 甲苯 为溶剂， 反应 34.0h， 生成 dibromotetra(dodecyl)diphenylethyne
  参考文献：
  名称：

  JP5716821

  摘要：

  公开号：
• 作为产物：
  描述：

  邻二氯苯 生成 双十二烷基苯
  参考文献：
  名称：

  OHTA, K.;JACQUEMIN, L.;SIRLIN, C.;BOSIO, L.;SIMON, J., NEW J. CHEM., 12,(1988) N 8-9, C. 751-754

  摘要：

  DOI：

文献信息

• 2D Networks of Rhombic-Shaped Fused Dehydrobenzo[12]annulenes: Structural Variations under Concentration Control
  作者：Kazukuni Tahara、Satoshi Okuhata、Jinne Adisoejoso、Shengbin Lei、Takumi Fujita、Steven De Feyter、Yoshito Tobe

  DOI：10.1021/ja904481j

  日期：2009.12.9

  rhombic-shaped bisDBA derivatives 1a-d, 2a, and 2b were synthesized for the purpose of the formation of porous networks at the 1,2,4-trichlorobenzene (TCB)/graphite interface. Depending on the alkyl-chain length and the solute concentration, bisDBAs exhibit five network structures, three porous structures (porous A, B, and C), and two nonporous structures (nonporous D and E), which are attributed to their rhombic

  为了在 1,2,4-三氯苯 (TCB)/石墨界面形成多孔网络，合成了一系列烷基和烷氧基取代的菱形双 DBA 衍生物 1a-d、2a 和 2b。根据烷基链长度和溶质浓度，双 DBA 表现出五种网络结构、三种多孔结构（多孔 A、B 和 C）和两种无孔结构（无孔 D 和 E），这归因于它们的菱形核形状和取代基的位置。具有较短烷基链的 BisDBA 1a 和 1b 有利于形成多孔结构，而具有较长烷基链的双 DBA 1c 和 1d 倾向于形成无孔结构。然而，稀释后，无孔结构通常会转化为多孔结构，这一趋势可以通过表面覆盖率、分子密度、和系统焓的分子间相互作用。此外，多孔结构通过溶剂分子的共吸附而稳定。至少在某种程度上，所有化合物都形成了最有趣的多孔结构 Kagome 模式，其三角形和六边形孔的大小可以通过烷基链长度进行调整。本研究证明，浓度控制是在液固界面构建多孔网络的强大而通用的工具。其三角形和六边
• HETEROACENE DERIVATIVE, TETRAHALOTERPHENYL DERIVATIVE, AND PROCESSES FOR PRODUCING THE SAME
  申请人：Watanabe Makoto

  公开号：US20090261300A1

  公开（公告）日：2009-10-22

  There are provided a heteroacene derivative having an excellent oxidation resistance and capable of forming a semiconductor active phase by a coating process, and an oxidation-resistant organic semiconductor material using the same, as well as an organic thin film. [Means for Resolution] A heteroacene derivative represented by the formula (1) is obtained by tetrametalation of a tetrahaloterphenyl derivative with a metalation agent and subsequent treatment of the resulting compound with reaction agents: wherein the substituents R 1 to R 4 are the same or different and each represents a hydrogen atom, a fluorine atom, a chlorine atom, an aryl group having 4 to 30 carbon atoms, an alkyl group having 3 to 20 carbon atoms, or a halogenated alkyl group having 1 to 20 carbon atoms; T 1 and T 2 are the same or different and each represents sulfur, selenium, tellurium, oxygen, phosphorus, boron, or aluminum; l and m each is an integer of 0 or 1; and rings A and B are the same or different and each has a structure represented by the following formulae (A- 1 ) or (A-2).

  提供了一种具有优异氧化抗性并能够通过涂层工艺形成半导体活性相的杂环芳烃衍生物以及使用该衍生物的抗氧化有机半导体材料，以及有机薄膜。[解决方案] 通过使用金属化试剂四甲基化四卤代苯衍生物并随后用反应试剂处理所得化合物，获得了由式（1）表示的杂环芳烃衍生物：其中取代基R1至R4相同或不同，每个代表氢原子、氟原子、氯原子、具有4至30个碳原子的芳基、具有3至20个碳原子的烷基或具有1至20个碳原子的卤代烷基；T1和T2相同或不同，每个代表硫、硒、碲、氧、磷、硼或铝；l和m各自为0或1的整数；环A和环B相同或不同，每个具有以下式（A-1）或（A-2）所表示的结构。
• Heteroacene derivative, tetrahaloterphenyl derivative, and processes for producing the same
  申请人：Tosoh Corporation

  公开号：US08138355B2

  公开（公告）日：2012-03-20

  There are provided a heteroacene derivative having an excellent oxidation resistance and capable of forming a semiconductor active phase by a coating process, and an oxidation-resistant organic semiconductor material using the same, as well as an organic thin film. A heteroacene derivative represented by the formula (1) is obtained by tetrametalation of a tetrahaloterphenyl derivative with a metalation agent and subsequent treatment of the resulting compound with reaction agents: wherein the substituents R1 to R4 are the same or different and each represents a hydrogen atom, a fluorine atom, a chlorine atom, an aryl group having 4 to 30 carbon atoms, an alkyl group having 3 to 20 carbon atoms, or a halogenated alkyl group having 1 to 20 carbon atoms; T1 and T2 are the same or different and each represents sulfur, selenium, tellurium, oxygen, phosphorus, boron, or aluminum; l and m each is an integer of 0 or 1; and rings A and B are the same or different and each has a structure represented by the following formulae (A-1) or (A-2).

  提供了一种具有出色氧化抗性并能够通过涂覆工艺形成半导体活性相的杂芴衍生物，以及使用该杂芴衍生物的耐氧化有机半导体材料和有机薄膜。通过将四卤代苯基衍生物与金属化试剂四次金属化并随后用反应试剂处理，得到式（1）所表示的杂芴衍生物：其中取代基R1至R4相同或不同，每个代表氢原子、氟原子、氯原子、具有4至30个碳原子的芳基基团、具有3至20个碳原子的烷基基团或具有1至20个碳原子的卤代烷基基团；T1和T2相同或不同，每个代表硫、硒、碲、氧、磷、硼或铝；l和m各自为0或1的整数；环A和B相同或不同，每个具有以下式（A-1）或（A-2）所表示的结构。
• HETEROACENE DERIVATIVE, TETRAHALOTERPHENYL DERIVATIVE, AND THEIR PRODUCTION METHODS
  申请人：Tosoh Corporation

  公开号：EP2067782B2

  公开（公告）日：2018-06-27
• Synthesis of Diacetylene Macrocycles Derived from 1,2-Diethynyl Benzene Derivatives: Structure and Reactivity of the Strained Cyclic Dimer
  作者：Qin Zhou、Patrick J. Carroll、Timothy M. Swager

  DOI：10.1021/jo00085a016

  日期：1994.3

  Diacetylene macrocycles 2-4 (n = 1-3) (R = H, C4H9, C6H13, C10H21, C12H25, OC10H21) have been prepared from the oxidative coupling of 1,2-diethynylbenzene derivatives. These compounds can be produced in useful quantities and are of interest as precursors to novel conjugated organic polymers. The reported results indicate that when the R groups are large the dimeric macrocycle (n = 1) can be prepared in as high as 74% yield from the corresponding 1,2-diethynylbenzene in a one-step procedure. An alternate multistep procedure was found to produce the tetrameric macrocycle (n = 3, R = C6H13) in 45 % yield. The highly strained dimeric macrocycle was characterized by an X-ray structure and was found to be very reactive. The dimers undergo a rapid very exothermic polymerization at 100-125-degrees-C, indicative of a chain reaction. Reaction of the dimeric macrocycles with iodine results in intramolecular cyclization and a new 20pi electron tetraiodide fused ring system. Reaction of the tetraiodide with oxygen produces a related compound in which two of the iodides have been converted to ketones.