1,4-双(4-吡啶甲基)苯 | 52469-20-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 中文名称: 1,4-双(4-吡啶甲基)苯
• 英文名称: 1,4-bis(4-pyridylmethyl)benzene
• 英文别名: 1,4-bis(pyridin-4-ylmethyl)benzene；4,4'-[1,4-Phenylenebis(methylene)]dipyridine；4-[[4-(pyridin-4-ylmethyl)phenyl]methyl]pyridine
• CAS: 52469-20-2
• 化学式: C₁₈H₁₆N₂
• 分子量: 260.338
• InChiKey: FFHRKYGEMWVANQ-UHFFFAOYSA-N

物化性质

• 沸点：
  433.9±35.0 °C(Predicted)
• 密度：
  1.109±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  20
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,4-双(4-吡啶甲基)苯 、 zinc(II) acetate dihydrate 以 乙醇 为溶剂， 以51%的产率得到[Zn₂(acetate)₂(μ-acetate)₂(1,4-bis(4-pyridylmethyl)benzene)]_n
  参考文献：
  名称：

  [Zn2Ac2(μ-Ac)2(bpymb)]n (Ac, acetate; bpymb, 1,4-bis(4-pyridylmethyl)benzene), a 2D coordination polymer obtained with a flexible N,N’-ditopic bipyridine linker

  摘要：

  DOI：

  10.1016/j.ica.2020.120132
• 作为产物：
  描述：

  4-氰基吡啶 、 1,4-苯二甲硫醇 在 三苯基膦 作用下， 以 二甲基亚砜 为溶剂， 以48 %的产率得到1,4-双(4-吡啶甲基)苯
  参考文献：
  名称：

  通过电子供体-受体配合物进行光诱导自由基脱硫 C(sp3)–C(sp2) 偶联

  摘要：

  在此，我们公开了用于合成4-烷基吡啶的自由基脱硫C-C偶联方案。苄基硫醇和 4-氰基吡啶上的各种取代基都是可以接受的。该反应在温和且不含光催化剂和过渡金属的条件下进行。初步机理研究表明，在碱性条件下，苄基硫醇和4-氰基吡啶之间形成电子供体-受体复合物。然后，通过C-S键的断裂形成各种以1°、2°和3°C(sp 3 )为中心的自由基，并通过与吡啶自由基的自由基-自由基偶联得到4-烷基吡啶。阴离子。

  DOI：

  10.1021/acs.orglett.4c00162

文献信息

• Photo-induced self-assembly of Pt(ii)-linked rings and cages via the photolabilization of a Pt(ii)–py bond
  作者：Ken-ichi Yamashita、Kei-ichi Sato、Masaki Kawano、Makoto Fujita

  DOI：10.1039/b817713a

  日期：——

  An inert Pt(II)–pyridine bond is considerably labilized upon UV irradiation. On the basis of this phenomenon, kinetically inert Pt(II)-linked coordination rings and cages are formed in high yields from their components by obtaining a kinetically distributed mixture and subsequently equilibrating the mixture into the thermodynamically stable structures upon temporary photolabilization. This method is applicable when the pyridine rings in the ligands are not conjugated with other aromatic rings, in good agreement with DFT calculations that indicate the dependency of the photolability on the π-conjugation of the ligand frameworks. Interruption of π-conjugation either by introducing an methylene linker or by twisting the aromatic rings are effective to accomplish the photo-induced self-assembly.

  惰性铂(II)-吡啶键在紫外线照射下会发生明显的唇化。根据这一现象，通过获得一种动力学分布的混合物，然后将混合物平衡为热力学上稳定的结构，就可以从其组分中高产率地形成动力学上惰性的铂(II)连接配位环和笼。这种方法适用于配体中吡啶环未与其他芳香环共轭的情况，这与 DFT 计算结果十分吻合，后者表明光稳定性取决于配体框架的Ï-共轭情况。通过引入亚甲基连接体或扭转芳香环来中断Ï-共轭，可有效实现光诱导自组装。
• Metallacycles and methods of making the same
  申请人：Lu Kuang-Lieh

  公开号：US20090082574A1

  公开（公告）日：2009-03-26

  The present invention provides for novel metallacycles and processes for making the same.

  本发明提供了一种新型金属环化合物和制备方法。
• WATER CAPTURE METHODS, DEVICES, AND COMPOUNDS
  申请人：University of Limerick

  公开号：US20200030737A1

  公开（公告）日：2020-01-30

  A method of capturing water from a gaseous composition comprising water vapour (e.g., air), the method comprising: (a) providing a metal-organic material; and (b) contacting the metal-organic material with water and/or water vapour; wherein upon contact with water and/or water vapour the material switches from a first state to a second state wherein the second state is able to retain a higher amount of water than the first state.

  一种从含水蒸气（例如空气）中捕获水的方法，包括以下步骤：(a) 提供金属有机材料；和(b) 将金属有机材料与水和/或水蒸气接触；其中，在接触水和/或水蒸气时，该材料从第一状态切换到第二状态，第二状态能够比第一状态更多地保留水。
• Self-assembled molecular ladders
  作者：Makoto Fujita、Osamu Sasaki、Ken-ya Watanabe、Katsuyuki Ogura、and Kentaro Yamaguchi

  DOI：10.1039/a708324f

  日期：——

  zene (1), with cadmium nitrate afforded an infinite ladder complex, the unit structure of which involves a T-shaped assembly of three pyridine rings about a heptacoordinated CdII atom. The ladder structure was found to expand its cavity volume by enclathrating p-dibromobenzene in the cavity. Nearly orthogonal interpenetration of infinite ladders was observed in the solid structure.

  吡啶基桥联配体1,4-双（4-吡啶甲基甲基）苯（1）与硝酸镉的配位提供了无限的梯形配合物，其单元结构涉及三个吡啶环的T形组装，围绕一个环。七配位的Cd II原子。发现梯形结构通过将对-二溴苯包封在空腔中来扩大其空腔体积。在实体结构中观察到无限梯子的几乎正交的互穿。
• Optical Film and Method for Manufacturing the Same
  申请人：Yamahara Motohiro

  公开号：US20090104378A1

  公开（公告）日：2009-04-23

  This invention provides an optical film, which can freely regulate the tilt angle and can easily be manufactured without simultaneously regulating polymerization and mixing, and a method for manufacturing the same. The optical film is a film having birefringence. The film has been produced by association through an intermolecular hydrogen bond between at least two compounds having a refractive index anisotropy-providing structure and a proton-receptive group and at least one compound having a refractive index anisotropy-providing structure and a proton-providing group. The method for manufacturing the optical film comprises mixing at least two compounds having a refractive index anisotropy-providing structure and a proton-receptive group with at least one compound having a refractive index anisotropy-providing structure and a proton-providing group and forming a film from the mixture on an aligning film.

  这项发明提供了一种光学膜，可以自由调节倾斜角度，并且可以轻松制造，而不需要同时调节聚合和混合，以及一种制造该膜的方法。该光学膜是一种具有双折射性的膜。该膜是通过至少两种具有折射率各向异性提供结构和质子接受基团的化合物与至少一种具有折射率各向异性提供结构和质子提供基团的化合物之间的分子间氢键缔合而产生的。制造该光学膜的方法包括将至少两种具有折射率各向异性提供结构和质子接受基团的化合物与至少一种具有折射率各向异性提供结构和质子提供基团的化合物混合，并从混合物中在定向膜上形成膜。