zinc(II) phenylacetate

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: zinc(II) phenylacetate
• 英文别名: zinc phenylacetate；[Zn(phenylacetate)₂]
• 化学式: 2C₈H₇O₂*Zn
• 分子量: 335.675
• InChiKey: GNSFUMCOFJPCNW-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.02
• 重原子数：
  11.0
• 可旋转键数：
  2.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  40.13
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  zinc(II) phenylacetate 在 盐酸 作用下， 以 melt 、 二氯甲烷 、 水 、 N,N-二甲基甲酰胺 为溶剂， 反应 2.25h， 生成 palladium(II) 5,10,15,20-tetraphenyltetrabenzoporphyrinate
  参考文献：
  名称：

  锌（II）四苯基四苯并卟啉配合物作为三重态三重态an灭上转换的三重态光敏剂。

  摘要：

  Zn（II）四苯基四苯并卟啉（TPTBP）和游离碱H2TPTBP被用作三重态三重态an灭（TTA）上转换的三重态光敏剂，以取代历史悠久的贵金属络合物三重态光敏剂，例如含Pd（II）-Pt（ II）原子。

  DOI：

  10.1039/c3cc45843a
• 作为产物：
  描述：

  苯乙酸 在 sodium hydroxide 作用下， 以 水 为溶剂， 生成 zinc(II) phenylacetate
  参考文献：
  名称：

  锌（II）四苯基四苯并卟啉配合物作为三重态三重态an灭上转换的三重态光敏剂。

  摘要：

  Zn（II）四苯基四苯并卟啉（TPTBP）和游离碱H2TPTBP被用作三重态三重态an灭（TTA）上转换的三重态光敏剂，以取代历史悠久的贵金属络合物三重态光敏剂，例如含Pd（II）-Pt（ II）原子。

  DOI：

  10.1039/c3cc45843a

文献信息

• Electrochemistry of zinc tetraarylporphyrins containing fused butano and benzo groups. Effect of solvent and substituents on spectra, potentials and mechanism in nonaqueous media
  作者：Lina Ye、Yuanyuan Fang、Zhongping Ou、Liping Wang、Songlin Xue、Jing Sun、Karl M. Kadish

  DOI：10.1142/s1088424618501067

  日期：2018.12

  text],[Formula: see text]′-pyrrole fused butano or benzo groups were synthesized and characterized as to their electrochemical and spectroelectrochemical properties in nonaqueous media. The examined compounds are represented as butano(Ar)4PorZn and benzo(Ar)4PorZn, where Por is the porphyrin dianion and Ar is a [Formula: see text]-CH3Ph, Ph or [Formula: see text]-ClPh substitutent on [Formula: see text]-positions

  合成了两个系列的四芳基卟啉锌，含有四个[分子式：见正文]，[分子式：见正文]'-吡咯稠合丁氧基或苯并基团，并对其在非水介质中的电化学和光谱电化学性质进行了表征。检查的化合物表示为丁醇（Ar）4PorZn 和苯并 (Ar)4PorZn，其中 Por 是卟啉双阴离子，Ar 是 [公式：见正文]-CH3Ph、Ph 或 [公式：见正文]-ClPh 取代基在 [公式：见正文]-大环的位置。每个 Zn(II) 丁氧基和苯并卟啉经历两次单电子还原，在 CH 中产生 [公式：见正文]-阴离子自由基和二价阴离子2氯2. 相反，对于吡啶中的苯并卟啉衍生物，观察到了三个还原，其中第三个被指定为与双还原苯并卟啉产生的苯并卟啉阴离子的电子加成。对于 CH 中的丁卟啉，观察到两个重叠的单电子氧化2氯2，以前没有观察到任何其他锌卟啉的结果。苯并卟啉的电化学测量的 HOMO-LUMO 间隙在 CH 中的范围为 1.89 至
• H₂O₂-activated triplet–triplet annihilation upconversion via modulation of the fluorescence quantum yields of the triplet acceptor and the triplet–triplet-energy-transfer efficiency
  作者：Renjie Tao、Jianzhang Zhao、Fangfang Zhong、Caishun Zhang、Wenbo Yang、Kejing Xu

  DOI：10.1039/c5cc04325e

  日期：——

  H₂O₂-activatable TTA upconversion was achieved with non-fluorescent 9,10-bis(diphenylphosphino)anthracene as a triplet acceptor/emitter, which can be oxidized to a fluorescent product by H₂O₂.

  使用非荧光性的9,10-双(二苯基膦基)蒽作为三重态受体/发射体，可以通过H₂O₂氧化为荧光产物，实现了H₂O₂可激活的TTA上转换。
• Cobalt Tetrabutano- and Tetrabenzotetraarylporphyrin Complexes: Effect of Substituents on the Electrochemical Properties and Catalytic Activity of Oxygen Reduction Reactions
  作者：Lina Ye、Yuanyuan Fang、Zhongping Ou、Songlin Xue、Karl M. Kadish

  DOI：10.1021/acs.inorgchem.7b02405

  日期：2017.11.6

  product. Each porphyrin was also examined as a catalyst for oxygen reduction reactions (ORRs) when adsorbed on a graphite electrode in 1.0 M HClO4. The number of electrons transferred (n) during ORRs is 2.0 for the butano(TpYPP)CoII derivatives, consistent with only H2O2 being produced as a product for the reaction with O2. However, the reduction of O2 using the cobalt benzoporphyrins as catalysts gave n

  合成了三系列的四芳基钴卟啉，并通过电化学和光谱电化学对其进行了表征。所研究的化合物具有通式（T p YPP）Co，丁醇（T p YPP）Co II和苯并（T p YPP）Co II，其中T p YPP代表内消旋卟啉的二价阴离子，Y为在四个苯环的对位上的CH 3，H或Cl取代基以及丁酸和苯并分别是在化合物的四个吡咯环上的β-和β'-取代的基团。根据内消旋取代基和所用溶剂的不同，每种卟啉都会经历一两次还原反应。对于（T p在含有0.1M四正丁基高氯酸铵的CH 2 Cl 2中的YPP）Co II和丁烷（T p YPP）Co II；首先导致形成高反应性的钴（I）卟啉，然后它可以与溶剂快速反应，生成Co III CH 2 Cl作为产物。在相同的溶液条件下，苯并（T p YPP）Co II只能看到一个可逆的还原，并且单电子还原产物被指定为钴（II）卟啉π阴离子自由基。对于CH 2 Cl 2中的每种受检
• Formation of tetrabenzoporphine skeleton by the reactions of phthalimide with zinc carbonates
  作者：Kunihiro Ichimura、Masako Sakuragi、Hisayuki Morii、Madoka Yasuike、Yasumasa Toba、Masaru Fukui、Osamu Ohno

  DOI：10.1016/s0020-1693(00)87937-2

  日期：1991.8

  The high temperature reactions of phthalimide potassium salt (PIK) with various zinc carbonates were carried out. The reaction of PIK with zinc acetate yielded tetrabenzoporphinato zinc (ZnTBP). Tetra-tert-butyltetrabenzoporphinato zinc (ZntBu4TBP), whose four tert-butyl substituents were positioned on the TBP periphery, was also prepared in a similar way using the 4-tert-butylphthalimide potassium salt (4-tBuPIK). These results were explained on the basis of the function of zinc acetate as the meso-methine carbon source of the TBP structure. The use of zinc phenylacetate instead of zinc acetate in the reaction of PIK led to the production of meso-phenyl substituted ZnTBPs, although they were different in the number of meso-phenyl substituent(s). The attempt to introduce alkyl residues at the meso-position(s) by the reaction of PIK in the presence of zinc alkylacetate having a long alkyl chain was not successful, except for the substitution of the methyl group using zinc propionate.
• N-heterocyclic carbene complexes of Zn(II): synthesis, X-ray structures and reactivity
  作者：Dongren Wang、Klaus Wurst、Michael R. Buchmeiser

  DOI：10.1016/j.jorganchem.2004.03.039

  日期：2004.6

  The synthesis of six novel zinc (II) mono(N-heterocyclic carbene) complexes is described. 1,3-Bis(mesityl)-imidazol-2-ylidene was reacted with the zinc salts ZnX2 (X = Cl, CH3COO, PhCOO, and PhCH2COO) to yield the corresponding monomeric Zn-NHC complex ZnCl2(NHC)(THF) (1) and dimeric [Zn(OOCCH3)(2)(NHC)](2) (2), [Zn(OOCPh)(2)(NHC)](2) (3), [Zn(OOCCH2Ph)(2)(NHC)](2) (4) (NHC = 1,3-bis(mesityl)-imidazol-2-ylidene). Reaction of 1 with 2 equivalents of silver trifluoromethanesulfonate yielded monomeric Zn(O3SCF3)(2)(NHC)(THF) (5), reaction of 1 with sodium [R(+)-alpha-2-(1-phenyl-ethylimino)-methyl]-phenolate} yielded monomeric ZnCl(OC6H4-2-CH=N(CHPhCH3)(NHC) (6). Compounds 1, 4-6 were structurally characterized by X-ray analysis. Selected compounds were investigated for their activity in the copolymerization of carbon dioxide with cyclohexene oxide as well as in the ring-opening polymerization of cyclohexene oxide and epsilon-caprolactone. (C) 2004 Published by Elsevier B.V.