benzylmethylphenyloxonium ion

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: benzylmethylphenyloxonium ion
• 英文别名: Benzyl-methyl-phenyloxidanium；benzyl-methyl-phenyloxidanium
• 化学式: C₁₄H₁₅O
• 分子量: 199.273
• InChiKey: NKDFABYMBDHIIX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.78
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  1
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  苯甲醚 、 benzylmethylphenyloxonium ion 在 氯氟磺酰 、 五氟化锑 作用下， 以98%的产率得到4 -甲氧基二苯基甲烷
  参考文献：
  名称：

  苯甲醚的 Friedel-Crafts 烷基化及其与甲苯的比较。动力学条件下的主要邻位取代和热力学异构化的影响

  摘要：

  烷基化，催化剂 par AlCl 3 et BF 3 ainsi que par HPF 6 a 65%, de l'anisole par des haloures d'alkyle et des alcanols

  DOI：

  10.1021/ja00330a042
• 作为产物：
  描述：

  氟甲烷 、 (benzyloxy)benzene 在 氯氟磺酰 、 五氟化锑 作用下， 生成 benzylmethylphenyloxonium ion
  参考文献：
  名称：

  苯甲醚的 Friedel-Crafts 烷基化及其与甲苯的比较。动力学条件下的主要邻位取代和热力学异构化的影响

  摘要：

  烷基化，催化剂 par AlCl 3 et BF 3 ainsi que par HPF 6 a 65%, de l'anisole par des haloures d'alkyle et des alcanols

  DOI：

  10.1021/ja00330a042

文献信息

• Non-aqueous absorbent and use thereof
  申请人：Sumiya Takashi

  公开号：US20050136247A1

  公开（公告）日：2005-06-23

  A non-aqueous absorbent comprising a crosslinked polymer which contains a structural unit having a carboxyl group and/or a sulfonate group in an amount of 20 to 100% weight in its molecule and in which from 30 to 100% by mol of the protons in the carboxyl group and/or the sulfonate group have been substituted by onium cations; a non-aqueous gel made of this non-aqueous absorbent and an organic solvent; and a non-aqueous absorbent sheet and a non-aqueous absorbent agent containing the non-aqueous absorbent. Because of having excellent capabilities of absorbing and holding various organic solvents such as alcohols and gelating, these materials are usable for various purposes, for example, lithium batteries, alcohol-based bactericidal materials or alcohol-based bactericides, cold insulating materials or cold insulators, gel sheets for cooling, fuel compositions for solid fuels or solid fuels using the same, fragrance materials or fragrances, patch materials or patches, insecticidal compositions or insecticides, fuel stores for fuel batteries or fuel batteries using the same.

  一种非水吸收剂，包含交联聚合物，其分子中含有具有羧基和/或磺酸基的结构单元，其含量为20至100％重量，并且其中羧基和/或磺酸基中的30至100％摩尔的质子已被离子上离子替代物取代；由此制成的非水凝胶和有机溶剂；以及含有非水吸收剂的非水吸收剂片和非水吸收剂剂。由于具有吸收和保持各种有机溶剂（如醇类）的能力，以及凝胶化，这些材料可用于各种用途，例如锂电池，醇基杀菌材料或醇基杀菌剂，冷绝缘材料或冷绝缘材料，用于冷却的凝胶片，用于固体燃料的燃料组合物或使用相同的固体燃料，香料材料或香料，贴片材料或贴片，杀虫组合物或杀虫剂，燃料电池的燃料存储器或使用相同的燃料电池。
• NON-AQUEOUS ABSORBENT AND USE THEREOF
  申请人：SANYO CHEMICAL INDUSTRIES, LTD.

  公开号：EP1462460A1

  公开（公告）日：2004-09-29

  A non-aqueous absorbent comprising a crosslinked polymer which contains a structural unit having a carboxyl group and/or a sulfonate group in an amount of 20 to 100% weight in its molecule and in which from 30 to 100% by mol of the protons in the carboxyl group and/or the sulfonate group have been substituted by onium cations; a non-aqueous gel made of this non-aqueous absorbent and an organic solvent; and a non-aqueous absorbent sheet and a non-aqueous absorbent agent containing the non-aqueous absorbent. Because of having excellent capabilities of absorbing and holding various organic solvents such as alcohols and gelating, these materials are usable for various purposes, for example, lithium batteries, alcohol-based bactericidal materials or alcohol-based bactericides, cold insulating materials or cold insulators, gel sheets for cooling, fuel compositions for solid fuels or solid fuels using the same, fragrance materials or fragrances, patch materials or patches, insecticidal compositions or insecticides, fuel stores for fuel batteries or fuel batteries using the same.

  一种非水性吸水剂，包含一种交联聚合物，其分子中含有羧基和/或磺酸基的结构单元，羧基和/或磺酸基中30-100%（摩尔）的质子被鎓阳离子取代；一种由该非水性吸水剂和有机溶剂制成的非水性凝胶；以及一种非水性吸水片材和一种含有该非水性吸水剂的非水性吸水剂。由于这些材料具有出色的吸收和保持各种有机溶剂（如醇类）和凝胶的能力，因此可用于各种用途，例如锂电池、醇基杀菌材料或醇基杀菌剂、冷绝缘材料或冷绝缘体、冷却用凝胶片、固体燃料或使用相同物质的固体燃料的燃料组合物、香料材料或香料、贴片材料或贴片、杀虫组合物或杀虫剂、燃料电池或使用相同物质的燃料电池的燃料储存。
• FUEL FOR FUEL CELL, FUEL CELL AND APPLICATION THEREOF
  申请人：Kurita Water Industries Ltd.

  公开号：EP1705740A1

  公开（公告）日：2006-09-27

  A fuel cell fuel contains an organic fuel used as a fuel for a fuel cell. The organic fuel is in a form of a solid molecular compound, such as an inclusion compound. The molecular compound can be prepared by contact catalytic reaction of a compound for forming the molecular compound and the organic fuel, and allows a liquid organic fuel to be in a solid compound to store the organic fuel stably in a relatively lightweight form. The molecular compound easily releases the organic fuel by, for example, heating, and the organic fuel is supplied to the fuel electrode of a fuel cell. Thus, the handleability of the fuel cell fuel containing the organic fuel can be improved, and the problems of corrosion, freezing of the fuel, crossover, and so forth can be solved.

  燃料电池燃料包含一种用作燃料电池燃料的有机燃料。有机燃料以固体分子化合物的形式存在，例如包合物。该分子化合物可通过一种化合物的接触催化反应制备，该化合物用于形成分子化合物和有机燃料，可将液态有机燃料置于固体化合物中，从而以相对较轻的形式稳定地储存有机燃料。通过加热等方式，分子化合物很容易释放出有机燃料，然后将有机燃料供应给燃料电池的燃料电极。这样，含有有机燃料的燃料电池燃料的可操作性就能得到改善，腐蚀、燃料冻结、交叉等问题也能得到解决。
• Fuel for fuel cell, fuel cell and application thereof
  申请人：Yagi Minoru

  公开号：US20080233438A1

  公开（公告）日：2008-09-25

  A fuel cell fuel contains an organic fuel used as a fuel for a fuel cell. The organic fuel is in a form of a solid molecular compound, such as an inclusion compound. The molecular compound can be prepared by contact catalytic reaction of a compound for forming the molecular compound and the organic fuel, and allows a liquid organic fuel to be in a solid compound to store the organic fuel stably in a relatively lightweight form. The molecular compound easily releases the organic fuel by, for example, heating, and the organic fuel is supplied to the fuel electrode of a fuel cell. Thus, the handleability of the fuel cell fuel containing the organic fuel can be improved, and the problems of corrosion, freezing of the fuel, crossover, and so forth can be solved.
• US7470738B2
  申请人：——

  公开号：US7470738B2

  公开（公告）日：2008-12-30