1,1,2-chloro-3-fluoro-propene | 1221888-51-2

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: 1,1,2-chloro-3-fluoro-propene
• 英文别名: 1,1,2-trichloro-3-fluoropropene；1,1,2-Trichloro-3-fluoroprop-1-ene
• CAS: 1221888-51-2
• 化学式: C₃H₂Cl₃F
• 分子量: 163.406
• InChiKey: USGZHDAFCVBESP-UHFFFAOYSA-N

物化性质

• 沸点：
  133.3±35.0 °C(Predicted)
• 密度：
  1.473±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  7
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  四氯乙烯 、 氟甲烷 在 四氯化碳 作用下， 生成 1,1,2-chloro-3-fluoro-propene
  参考文献：
  名称：

  PROCESSES FOR THE PRODUCTION OF CHLORINATED AND/OR FLUORINATED PROPENES AND HIGHER ALKENES

  摘要：

  本发明提供了连续的气相自由基过程，用于从氯化和/或氟化烷烃和氯化和/或氟化烯烃的反应中生产氯化和/或氟化丙烯或更高烯烃，其中过程产生的任何中间锅炉副产物的至少一部分被从过程中移除。

  公开号：

  US20110087055A1

文献信息

• [EN] PROCESS FOR PRODUCING 2,3,3,3-TETRAFLUOROPROPENE<br/>[FR] PROCÉDÉ DE PRODUCTION DE 2,3,3,3-TÉTRAFLUOROPROPÈNE
  申请人：BEKTESEVIC SELMA

  公开号：WO2013067350A1

  公开（公告）日：2013-05-10

  The present invention relates, in part, to the discovery that, during the fluorination of certain fluoroolefin starting reagents, particularly, 1,1,2,3-tetrachloropropene (1230xa), oligomerization/polymerization of such starting reagents reduces the conversion process and leads to increased catalyst deactivation. The present invention also illustrates that providing one or more organic co-feed to the fluooolefin starting stream reduces such oligomerization/polymerization and improves catalystic stability.

  本发明部分涉及发现，在对某些氟烯烃起始试剂进行氟化过程中，特别是对1,1,2,3-四氯丙烯（1230xa）进行氟化时，这些起始试剂的寡聚化/聚合会降低转化过程并导致催化剂失活增加。本发明还说明，向氟烯烃起始流提供一个或多个有机共喂料可以减少这种寡聚化/聚合并提高催化剂稳定性。
• COMPOSITIONS OF CHROMIUM OXYFLUORIDE OR FLUORIDE CATALYSTS, THEIR PREPARATION AND THEIR USE IN GAS-PHASE PROCESSES
  申请人：Arkema France

  公开号：US20190169102A1

  公开（公告）日：2019-06-06

  The present invention relates to a process for modifying the fluorine distribution in a hydrocarbon compound in the presence of a catalyst, characterized by the use, as catalyst, of a solid composition comprising at least one component containing chromium oxyfluoride or fluoride of empirical formula Cr x M (1-x) O r F s , where 2r+s is greater than or equal to 2.9 and less than 6, M is a metal chosen from columns 2 to 12 of the Periodic Table of the Elements, x has a value from 0.9 to 1, s is greater than 0 and less than or equal to 6 and r is greater than or equal to 0 and less than 3, the said solid composition having a crystallinity of less than 20% by weight. The present invention also relates to the solid composition per se.

  本发明涉及一种在催化剂存在下修改碳氢化合物中氟分布的方法，其特征在于使用一种固体组合物作为催化剂，所述固体组合物包括至少一种含有铬氧氟化物或经验式为Cr x M (1-x) O r F s 的氟化物的组分，其中2r+s大于或等于2.9且小于6，M是从元素周期表的2至12列中选择的金属，x的值为0.9至1，s大于0且小于或等于6，r大于或等于0且小于3，所述固体组合物的结晶度重量百分比小于20%。本发明还涉及固体组合物本身。
• METHOD FOR PRODUCING 2-CHLORO-3,3,3-TRIFLUOROPROPENE (HCFC-1233xf)
  申请人：Merkel Daniel C.

  公开号：US20090030244A1

  公开（公告）日：2009-01-29

  The present invention relates to an improved method for manufacturing 2-chloro-3,3,3,-trifluoropropene (HCFC-1233xf) by reacting 1,1,2,3-tetrachloropropene, 1,1,1,2,3-pentachloropropane, and/or 2,3,3,3-tetrachloropropene with hydrogen fluoride, in a vapor phase reaction vessel in the presence of a vapor phase fluorination catalyst and stabilizer. HCFC-1233xf is an intermediate in the production of 2,3,3,3-tetrafluoropropene (HFO-1234yf) which is a refrigerant with low global warming potential.

  本发明涉及一种改进的方法，通过在蒸汽相反应器中，在蒸汽相氟化催化剂和稳定剂的存在下，将1,1,2,3-四氯丙烯、1,1,1,2,3-五氯丙烷和/或2,3,3,3-四氯丙烯与氟化氢反应，制造2-氯-3,3,3-三氟丙烯（HCFC-1233xf）。HCFC-1233xf是生产2,3,3,3-四氟丙烯（HFO-1234yf）的中间体，后者是一种具有低全球变暖潜力的制冷剂。
• [EN] PROCESS FOR PRODUCING 2,3,3,3-TETRAFLUOROPROPENE<br/>[FR] PROCÉDÉ DE FABRICATION DU 2,3,3,3-TÉTRAFLUOROPROPÈNE
  申请人：WANG HAIYOU

  公开号：WO2013067356A1

  公开（公告）日：2013-05-10

  The present invention relates, in part, to the discovery that, during the fluorination of certain fluoroolefin starting reagents, oligomerization/polymerization of such reagents reduces the conversion process and leads to increased catalyst deactivation. The present invention also illustrates that vaporizing such starting reagents in the presence of one or more organic co-feed reduces such oligomerization/polymerization and improves catalytic stability.

  本发明部分涉及发现，在对某些氟烯烃起始试剂进行氟化过程中，这些试剂的寡聚化/聚合会降低转化过程并导致催化剂失活增加。本发明还说明，在存在一种或多种有机共喂料的情况下蒸发这些起始试剂可以减少这种寡聚化/聚合并提高催化稳定性。
• [EN] METHOD FOR PURIFYING 2,3,3,3-TETRAFLUOROPROPENE<br/>[FR] PROCÉDÉ DE PURIFICATION DE 2,3,3,3-TÉTRAFLUOROPROPÈNE
  申请人：DAIKIN IND LTD

  公开号：WO2011059078A1

  公开（公告）日：2011-05-19

  The present invention provides a method for purifying HFO-1234yf, comprising the steps of (1) cooling a liquid mixture containing HFO-1234yf and HF to separate the mixture into a upper liquid phase having a high concentration of HF and a lower liquid phase having a high concentration of 2,3,3,3-tetrafluoropropene; and (2) subjecting the lower liquid phase obtained in step (1) to a distillation operation to withdraw a mixture containing HFO-1234yf and HF from a top of a distillation column, thereby obtaining substantially HF-free HFO-1234yf from a bottom of the distillation column. According to the present invention, HF and HFO-1234yf contained in a mixture containing HF and HFO-1234yf can be separated under simple and economically advantageous conditions.

  本发明提供了一种用于纯化HFO-1234yf的方法，包括以下步骤：(1)冷却含有HFO-1234yf和HF的液体混合物，将混合物分离成具有高浓度HF的上液相和具有高浓度2,3,3,3-四氟丙烯的下液相；(2)将步骤(1)中获得的下液相进行蒸馏操作，从蒸馏塔顶部提取含有HFO-1234yf和HF的混合物，从蒸馏塔底部获得基本无HF的HFO-1234yf。根据本发明，在简单且经济有利的条件下，可以将含有HF和HFO-1234yf的混合物中的HF和HFO-1234yf分离。