四苯砷氯单水合物 | 104170-16-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 四苯砷氯单水合物
• 中文别名: 四苯砷氯一水
• 英文名称: tetraphenylarsonium chloride monohydrate
• 英文别名: tetraphenylarsonium chloride hydrate；tetraphenylarsanium;chloride;hydrate
• CAS: 104170-16-3
• 化学式: C₂₄H₂₀As*Cl*H₂O
• 分子量: 436.813
• InChiKey: NGDWSDTZKCSLRK-UHFFFAOYSA-M

物化性质

• 熔点：
  258-260 °C(lit.)
• 稳定性/保质期：
  遵照规定使用和储存，则不会发生分解。

计算性质

• 辛醇/水分配系数(LogP)：
  -0.76
• 重原子数：
  27
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  2

安全信息

• 安全说明：
  S20/21,S28,S45,S60,S61
• 危险类别码：
  R50/53,R23/25
• 海关编码：
  2931900090
• 危险品运输编号：
  UN 3465 6.1/PG 3
• 储存条件：
  请将产品存放在阴凉干燥处以保持密闭状态。

SDS

Name:	Tetraphenylarsonium chloride monohydrate, p.a. Material Safety Data Sheet
Synonym:	None Known.
CAS:	104170-16-3

Section 1 - Chemical Product MSDS Name: Tetraphenylarsonium chloride monohydrate, p.a. Material Safety Data Sheet
Synonym: None Known.

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SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
104170-16-3	Tetraphenylarsonium Chloride Monohydra	ca. 100%	unlisted

+++++
Hazard Symbols: T N

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SECTION 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Toxic by inhalation and if swallowed. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.The toxicological properties of this material have not been fully investigated.Cancer suspect agent. Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Harmful if inhaled.
Chronic:
No information found.

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SECTION 4 - FIRST AID MEASURES
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:

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SECTION 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Containers may explode when heated. Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Do NOT get water inside containers. Do NOT use straight streams of water. For small fires, use dry chemical, carbon dioxide, or water spray. For large fires, use water spray, fog or regular foam.

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SECTION 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation.

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SECTION 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use only in a chemical fume hood.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

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SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 104170-16-3: United Kingdom, WEL - TWA: (listed as arsenic compounds, n.o.s.): mg/m3 TWA (except arsine, as As) United Kingdom, WEL - STEL: (listed as arsenic compounds, n.o.s.) 0.3 mg/m3 STEL (except arsine, as As)
Japan: (listed as arsenic compounds, n.o.s.): 3 g/m3 OEL (refere value, as As)
Spain: (listed as arsenic compounds, n.o.s.): 0.1 mg/m3 VLA-ED (a As) Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

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SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Crystalline powder
Color: very slightly beige
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 258 - 260 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: soluble in water
Specific Gravity/Density:
Molecular Formula: (C6H5)4AsCl.H2O
Molecular Weight: 436.82

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SECTION 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, oxides of arsenic.
Hazardous Polymerization: Has not been reported.

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SECTION 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 104170-16-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Tetraphenylarsonium Chloride Monohydrate -
IARC: Group 1 carcinogen (listed as Arsenic compounds, n.o.s.).

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SECTION 12 - ECOLOGICAL INFORMATION

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SECTION 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations.

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SECTION 14 - TRANSPORT INFORMATION IATA
Shipping Name: ORGANOARSENIC COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 3280
Packing Group: II IMO
Shipping Name: ORGANOARSENIC COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 3280
Packing Group: II RID/ADR
Shipping Name: ORGANOARSENIC COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 3280
Packing group: II

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SECTION 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives
Hazard Symbols: T N
Risk Phrases:
R 23/25 Toxic by inhalation and if swallowed. R 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Phrases:
S 20/21 When using do not eat, drink or smoke. S 28A After contact with skin, wash immediately with plenty of water. S 37 Wear suitable gloves. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 104170-16-3: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 104170-16-3 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 104170-16-3 is not listed on the TSCA inventory. It is for research and development use only.

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SECTION 16 - ADDITIONAL INFORMATION
MSDS Creation Date: 9/02/1997 Revision #4 Date: 3/18/2003 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no way shall the company be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if the company has been advised of the possibility of such damages.

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SECTION 16 - ADDITIONAL INFORMATION
N/A

反应信息

• 作为反应物：
  描述：

  四苯砷氯单水合物 在 HBr 作用下， 以 乙醇 、 乙腈 为溶剂， 生成 (Ph4As)RhBr4 * acetonitrile
  参考文献：
  名称：

  关于金属羧酸盐的研究。十五[1]。乙酸铑（II）与气态卤化氢的溶液反应。铑（III）配合物的形成

  摘要：

  摘要乙酸铑（II）Rh2（O2CCH3）4在丙酮或乙醇中与气态Hcl和HBr反应生成不溶的铑金属残渣和含铑（III）的溶液，经Ph4AsCl·nH2O处理后生成盐（Ph4As）RhCl4（H2O）和（Ph4As）RhBr4（H2O）。它们可以被用作合成多种新型铑（III）物种的起始原料。本文中制备的络合物为（Ph4As）RhX4（CH3CN），RhX3（PPh3）2（CH3CN）和[RhX2（LL）2] X·2EtOH，其中LL = 1,2-双（二苯基膦基）乙烷和1， 2-双（二苯基砷基）乙烷。描述了它们的合成和光谱表征的细节。[RhX2（LL）2] X·2EtOH的X射线光电子能谱（XPS）表明，内层和外层卤素环境的Cl 2p和Br 3p结合能相差1.3至1.7 eV。

  DOI：

  10.1016/s0020-1693(00)89485-2

文献信息

• Synthesis and characterisation of an alumina–supported RuOs₃cluster catalyst
  作者：John R. Budge、Joseph P. Scott、Bruce C. Gates

  DOI：10.1039/c39830000342

  日期：——

  The alumina-supported anion cluster Al+[H3RuOs3(CO)12]– was formed by heating [H2RuOs3(CO)13] absorbed on γ-Al2O3 to 373–473 K under an H2+ CO atmosphere; the material is catalytically active for ethylene hydrogenation at 340 K and for but-1-ene isomerization at 330 K.

  的氧化铝负载的阴离子簇的Al + [H 3个RuOs 3（CO）12 ] -通过加热形成[H 2个RuOs 3（CO）13 ]上吸收的γ-Al 2 ö 3的H下373-473ķ 2 + CO气氛；该材料具有催化活性，可在340 K下进行乙烯加氢和在330 K下进行丁-1-烯异构化。
• Carbon–nitrogen bond cleavage in 1-dimethylaminobut-2-yne and derived ligands in triruthenium and triosmium clusters
  作者：Silvio Aime、Giorgio Jannon、Domenico Osella、Alejandro J. Arce、Antony J. Deeming

  DOI：10.1039/dt9840001987

  日期：——

  obtained similarly from [Os3(CO)12] but [Os3(CO)10-(MeCN)2] reacts at room temperature with the alkyne giving [Os3H(CO)9(µ3-MeCCCH2)] by C–N bond cleavage. Rotation about the C–N bond in complex (1) in chloroform solution is restricted but the rate is accelerated by the addition of small amounts of CF3CO2H while, in neat CF3CO2H, compound (1) is protonated to give [Ru3H2(CO)9(MeCCCHNMe2)]+ for which the

  十二碳三钌在环己烷中与1-二甲基氨基丁-2-炔（MeC CCH 2 NMe 2）反应，得到高产率的异构体[Ru 3 H（CO）9（µ 3 -MeCCCHNMe 2）]（1）和[Ru 3 H（CO）9-（µ 3 -MeCCHCNMe 2）]（2），其化学计量关系（尽管可能不是结构上的）与包含µ 3-烯基（R 1 C C CHR 2）或被os取代的µ的已知配合物有关3-烯丙基（R 1 CCHCR 2）配体。络合物（1）的analogue类似物类似地从[Os 3（CO）12 ]获得，但是[Os 3（CO）10-（MeCN）2 ]在室温下与炔反应，得到[Os 3 H（CO）9（µ 3 -MeC C CH 2）]通过C–N键断裂。在氯仿溶液中，配合物（1）中C–N键的旋转受到限制，但是通过添加少量的CF 3 CO 2 H可以加快速率，而在纯CF 3 CO 2 H中，化合物（1）可以质子化给出[Ru 3
• Phenylimido Complexes of Technetium and Rhenium with Maleonitriledithiolate
  作者：Bernd Kuhn、Ulrich Abram

  DOI：10.1002/zaac.201000359

  日期：2010.12.27

  2-dicyanoethene-1,2-dithiolate) with formation of anionic complexes of the composition [M(NPh)(mnt)2]–. The products can be isolated as large red blocks of their AsPh4+ salts. The complex anions contain square-pyramidal coordinated metal atoms with the phenylimido ligands in apical positions. The M–N–C bonds are almost linear. A similar phenylimido complex with an additional amino group was synthesized from

  [Tc(NPh)Cl3(PPh3)2] 或 [Re(NPh)Cl3(PPh3)2] 与两当量的 Na2mnt（mnt2– = 1,2-二氰基乙烯-1,2-二硫醇盐）反应，形成阴离子配合物组成 [M(NPh)(mnt)2]–。产物可以作为其 AsPh4+ 盐的大红色块分离。复合阴离子包含方形锥体配位金属原子，在顶端位置带有苯基亚氨基配体。M-N-C 键几乎是线性的。从 [Re(NC6H4-4-NH2)Cl3(PPh3)2] 合成了一个类似的带有额外氨基的苯基亚氨基复合物。此类取代基的存在可允许金属络合物与生物分子如肽、蛋白质或糖偶联，条件是M=N键对水解足够稳定。
• Chemistry of Thiobenzoates: Syntheses, Structures, and NMR Spectra of Salts of [M(SOCPh)₃]^- (M = Zn, Cd, Hg)
  作者：Jagadese J. Vittal、Philip A. W. Dean

  DOI：10.1021/ic9514298

  日期：1996.1.1

  The salts (Ph(4)E)[M(SOCPh)(3)] (M = Zn, Cd, or Hg; E = P or As) are produced by the reaction of Zn(NO(3))(2).6 H(2)O, Cd(NO(3))(2).4H(2)O or HgCl(2) with Et(3)NH(+)PhCOS(-) and (Ph(4)E)X (E = P, X = Br; E = As, X = Cl) in aqueous MeOH in the ratios M(II):PhCOS(-):Ph(4)E(+) = 1:>/=3:>/=1. The crystal structures of (Ph(4)P)[Zn(SOCPh)(3)] (1), (Ph(4)As)[Cd(SOCPh)(3)] (2) and (Ph(4)P)[Hg(SOCPh)(3)] (3)

  盐（Ph（4）E）[M（SOCPh）（3）]（M = Zn，Cd或Hg； E = P或As）是通过Zn（NO（3））（2）反应生成的.6 H（2）O，Cd（NO（3））（2）.4H（2）O或HgCl（2）与Et（3）NH（+）PhCOS（-）和（Ph（4）E） X（E = P，X = Br; E = As，X = Cl）在MeOH水溶液中的比例为M（II）：PhCOS（-）：Ph（4）E（+）= 1：> / = 3： > / = 1。（Ph（4）P）[Zn（SOCPh）（3）]（1），（Ph（4）As）[Cd（SOCPh）（3）]（2）和（Ph（4）P ）[Hg（SOCPh）（3）]（3）已通过单晶X射线衍射实验确定。1的晶体数据：三斜晶；空间群P＆onemacr ;; Z = 2；a = 10.819（2）Å，b = 13.219（3）Å，c = 15.951（3）Å; alpha = 101
• [Cr(phen)(ox)2]-: a versatile bis-oxalato building block for the design of heteropolymetallic systems. Crystal structures and magnetic properties of AsPh4[Cr(phen)(ox)2]·H2O, [NaCr(phen)(ox)2(H2O)]·2H2O and {[Cr(phen)(ox)2]2[Mn2(bpy)2(H2O)2(ox)]}·6H2O
  作者：Gabriela Marinescu、Marius Andruh、Rodrigue Lescouëzec、Mari Carmen Muñoz、Juan Cano、Francesc Lloret、Miguel Julve

  DOI：10.1039/b002246m

  日期：——

  through bridging oxalate in 2 are 5.560(4) and 3.643(8) Å, respectively. The structure of 3 consists of neutral tetranuclear Cr2IIIMn2II units in which two terminal [Cr(phen)(ox)2]− entities act as monodentate ligands towards a central oxalato-bridged manganese(II) dimer. Each manganese atom is six-coordinated as MnN2O4: two nitrogen atoms of a chelating bpy, one aqua ligand and three oxalate oxygens

  分子式为AsPh 4 [Cr（phen）（ox）2 ]·H 2 O（1），[NaCr（phen）（ox）2（H 2 O）]·2H 2 O（2）和[ Cr（phen）（ox）2 ] 2 [Mn 2（bpy）2（H 2 O）2（ox）]·6H 2 O（3）（AsPh 4 =四苯基phenyl阳离子； phen = 1,10-菲咯啉；制备了草酸二氧杂酸酯（草酸二氧杂酸； bpy ＝ 2，2′-联吡啶），并通过单晶X射线衍射对其进行了表征。1的结构由离散的[Cr（phen）（ox）2 ] -阴离子，四苯基ar阳离子和未配位的水分子。在铬环境1 被扭曲的八面体以Cr-O键距离1.959（3）和1.947（3）的2.083（4）和2.072（4）和Cr-N键之间。两种草酸盐在铬原子上的夹角分别为83.6（2）和83.3（1）°，而N–Cr–N夹角为79.9（2）°。[Cr（phen）（ox） 2 ]