(9-bromo-2,6-di-tert-butylanthracene) | 62337-63-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: (9-bromo-2,6-di-tert-butylanthracene)
• 英文别名: 9-bromo-2,6-di-tert-butylanthracene；9-bromo-2,6-di-tert-butylanthrcene；9-Bromo-2,6-di-tert-butyl-anthracene；Anthracene, 9-bromo-2,6-bis(1,1-dimethylethyl)-；9-bromo-2,6-ditert-butylanthracene
• CAS: 62337-63-7
• 化学式: C₂₂H₂₅Br
• 分子量: 369.344
• InChiKey: IRFLSURAOCXUAX-UHFFFAOYSA-N

物化性质

• 沸点：
  460.7±14.0 °C(Predicted)
• 密度：
  1.202±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.5
• 重原子数：
  23
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  (9-bromo-2,6-di-tert-butylanthracene) 在 正丁基锂 、 ammonium acetate 、 sodium hydride 、 溶剂黄146 作用下， 以 N,N-二甲基甲酰胺 、 mineral oil 为溶剂， 反应 22.5h， 生成 (2-(2,6-di-tert-butylanthracen-9-yl)-1-methyl-1H-imidazo-[4,5-f][1,10] phenanthroline)
  参考文献：
  名称：

  Blue light-emitting and electron-transporting materials based on dialkyl-functionlized anthracene imidazophenanthrolines

  摘要：

  Two novel blue light-emitting materials based on bis(tert-butyl)anthracenyl-imidazophenanthrolines (BAIPs) have been synthesized and extensively characterized. Both materials exhibited a non-aggregate feature with high fluorescent quantum efficiency and excellent thermal stability. They can serve both as emissive and electron-transporting materials used in electroluminescence (EL) device for blue emission with high luminescence and external quantum efficiency. This study demonstrates that they are potentially useful for a wide range of applications in EL technology. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2010.12.059
• 作为产物：
  描述：

  2,6-二-叔丁基蒽 在 iron(III) chloride 、 N-溴代丁二酰亚胺(NBS) 作用下， 以 氯仿 为溶剂， 反应 3.0h， 以92%的产率得到(9-bromo-2,6-di-tert-butylanthracene)
  参考文献：
  名称：

  掺硼三（9,10-蒽）s：合成，结构表征和光电性质

  摘要：

  9,10-二溴-9,10-二氢-9,10-二硼蒽蒽（9,10-二溴-DBA，3）与两个当量的9-lithio-2,6-或9-lithio-2的反应， 7-二叔丁基蒽生成了相应的9,10-二蒽基DBA，具有两个（4）或四个（5）内向叔丁基。由于绕环外BC键的旋转受阻，化合物4以两个阻转异构体4和4'的形式存在。X射线晶体学图5表明，面对的叔丁基之间的整体相互作用是吸引而不是排斥的。即使在解决方案中，4 /4′和5对空气和湿气稳定几个小时。用带有苯基（R = Ph），二聚三甲基叔丁基（R = Mes 2 B）或N，N- di（对甲苯基）氨基的10-硫代-9-R-2,7-二叔丁基蒽处理3（R =托尔2 N）基团，得到相应的9,10- dianthryl-DBA衍生物9 - 11在中度至良好的产率。在这些分子中，所有四个可溶解的叔丁基均朝外。的固态结构4，5，9，和10揭示了环外BC键的扭曲构

  DOI：

  10.1002/chem.201202280

文献信息

• Electroluminescent Device
  申请人：Tanabe Junichi

  公开号：US20090131673A1

  公开（公告）日：2009-05-21

  Disclosed are electroluminescent devices that comprise organic layers that contain dibenzofuran compounds. The compounds are suitable components of, for example, blue-emitting, durable, organo-electroluminescent layers. The electroluminescent devices may be employed for full color display panels in, for example, mobile phones, televisions and personal computer screens.

  揭示了包含二苯并呋喃化合物的有机层的电致发光器件。这些化合物适用于例如蓝光发射、耐用的有机电致发光层的组分。这些电致发光器件可以用于例如手机、电视和个人电脑屏幕的全彩显示面板。
• Electroluminescent device
  申请人：BASF SE

  公开号：US07989644B2

  公开（公告）日：2011-08-02

  Disclosed are electroluminescent devices that comprise organic layers that contain dibenzofuran compounds. The compounds are suitable components of, for example, blue-emitting, durable, organo-electroluminescent layers. The electroluminescent devices may be employed for full color display panels in, for example, mobile phones, televisions and personal computer screens.

  公开了包含二苯并呋喃化合物的有机层的电致发光器件。这些化合物是适合用作蓝色发光、耐久、有机电致发光层的组分。这些电致发光器件可以用于全彩色显示面板，例如移动电话、电视和个人电脑屏幕。
• ELECTROLUMINESCENT DEVICE
  申请人：TANABE JUNICHI

  公开号：US20110248217A1

  公开（公告）日：2011-10-13

  Disclosed are electroluminescent devices that comprise organic layers that contain dibenzofuran compounds. The compounds are suitable components of, for example, blue-emitting, durable, organo-electroluminescent layers. The electroluminescent devices may be employed for full color display panels in, for example, mobile phones, televisions and personal computer screens.

  本发明公开了包含二苯并呋喃化合物的有机层的电致发光器件。这些化合物是可用于例如蓝色发光，耐久性好的有机电致发光层的合适组分。这些电致发光器件可用于移动电话、电视和个人电脑屏幕等全彩色显示面板。
• Olefin polymerization catalyst systems and methods of use thereof
  申请人：Dow Global Technologies LLC

  公开号：US10968289B2

  公开（公告）日：2021-04-06

  Olefin polymerization catalyst systems are provided that include a procatalyst component having a metal-ligand complex of Formula (I): [formula] (I) where each X is a neutral, monoanionic, or dianionic, monodentate or polydentate ligand such that the complex of Formula (I) is neutral; each R1 and R10 is a (C6-C40)aryl, substituted (C6-C40)aryl, (C3-C40)heteroaryl, or substituted (C3-C40)heteroaryl; each R2, R3, R4, R7, R8, and R9 is a hydrogen; (C1-C40)hydrocarbyl; substituted (C1-C40)hydrocarbyl; (C1-C40)heterohydrocarbyl; substituted (C1-C40)heterohydrocarbyl; halogen; or nitro (NO2) group; and each R5 and R6 is a (C1-C)alkyl; substituted (C1-C40)alkyl; or [(Si)1—(C+Si)40] substituted organosilyl. Additionally, olefin-based polymers and processes for polymerizing one or more olefin-based polymers in the presence of the olefin polymerization catalyst systems are also provided.

  提供了烯烃聚合催化剂体系，该体系包括具有式（I）金属配体络合物的原催化剂组分：[式](I) 其中每个 X 是中性、单阴离子或二阴离子、单齿或多齿配体，使式 (I) 的络合物为中性；每个 R1 和 R10 是 (C6-C40)aryl 、取代的 (C6-C40)aryl 、(C3-C40)杂芳基或取代的 (C3-C40)heteroaryl ；每个 R2、R3、R4、R7、R8 和 R9 是氢；(C1-C40)烃基；取代的(C1-C40)烃基；(C1-C40)杂烃基；取代的(C1-C40)杂烃基；卤素；或硝基（NO2）；以及每个 R5 和 R6 是(C1-C)烷基；取代的(C1-C40)烷基；或[(Si)1-(C+Si)40]取代的有机硅基。此外，还提供了烯烃基聚合物和在烯烃聚合催化剂体系存在下聚合一种或多种烯烃基聚合物的工艺。
• Müller, Uwe; Baumgarten, Martin, Journal of the American Chemical Society, 1995, vol. 117, # 21, p. 5840 - 5850
  作者：Müller, Uwe、Baumgarten, Martin

  DOI：——

  日期：——