(2-(2,6-di-tert-butylanthracen-9-yl)-1-methyl-1H-imidazo-[4,5-f][1,10] phenanthroline) | 1268621-93-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: (2-(2,6-di-tert-butylanthracen-9-yl)-1-methyl-1H-imidazo-[4,5-f][1,10] phenanthroline)
• 英文别名: 2-(2,6-Ditert-butylanthracen-9-yl)-3-methylimidazo[4,5-f][1,10]phenanthroline；2-(2,6-ditert-butylanthracen-9-yl)-3-methylimidazo[4,5-f][1,10]phenanthroline
• CAS: 1268621-93-7
• 化学式: C₃₆H₃₄N₄
• 分子量: 522.693
• InChiKey: RGIUZSBGYUGAOP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.5
• 重原子数：
  40
• 可旋转键数：
  3
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  43.6
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  (9-bromo-2,6-di-tert-butylanthracene) 在 正丁基锂 、 ammonium acetate 、 sodium hydride 、 溶剂黄146 作用下， 以 N,N-二甲基甲酰胺 、 mineral oil 为溶剂， 反应 22.5h， 生成 (2-(2,6-di-tert-butylanthracen-9-yl)-1-methyl-1H-imidazo-[4,5-f][1,10] phenanthroline)
  参考文献：
  名称：

  Blue light-emitting and electron-transporting materials based on dialkyl-functionlized anthracene imidazophenanthrolines

  摘要：

  Two novel blue light-emitting materials based on bis(tert-butyl)anthracenyl-imidazophenanthrolines (BAIPs) have been synthesized and extensively characterized. Both materials exhibited a non-aggregate feature with high fluorescent quantum efficiency and excellent thermal stability. They can serve both as emissive and electron-transporting materials used in electroluminescence (EL) device for blue emission with high luminescence and external quantum efficiency. This study demonstrates that they are potentially useful for a wide range of applications in EL technology. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2010.12.059

文献信息

• Blue light-emitting and electron-transporting materials based on dialkyl-functionlized anthracene imidazophenanthrolines
  作者：Jiann-Fong Lee、Yung-Chung Chen、Jiann-T’suen Lin、Chung-Chih Wu、Chien-Yu Chen、Chi-An Dai、Chi-Yang Chao、Hsuen-Li Chen、Wen-Bin Liau

  DOI：10.1016/j.tet.2010.12.059

  日期：2011.3

  Two novel blue light-emitting materials based on bis(tert-butyl)anthracenyl-imidazophenanthrolines (BAIPs) have been synthesized and extensively characterized. Both materials exhibited a non-aggregate feature with high fluorescent quantum efficiency and excellent thermal stability. They can serve both as emissive and electron-transporting materials used in electroluminescence (EL) device for blue emission with high luminescence and external quantum efficiency. This study demonstrates that they are potentially useful for a wide range of applications in EL technology. (C) 2010 Elsevier Ltd. All rights reserved.