Co(II)(pyridine)2(diethyldithiocarbamato)2 | 872467-57-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: Co(II)(pyridine)2(diethyldithiocarbamato)2
• CAS: 872467-57-7
• 化学式: C₂₀H₃₀CoN₄S₄
• 分子量: 513.742
• InChiKey: WJQJMJJKVYMIMM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  吡啶 以 甲醇 为溶剂， 生成 Co(II)(pyridine)2(diethyldithiocarbamato)2
  参考文献：
  名称：

  Synthesis, Characterization and Thermal Studies of Bipyridine Metal Complexes Containing Different Substituted Dithiocarbamates

  摘要：

  Complexes of the type [Mpy(2)(dedtc)(2)], and [Mpy(2)(dpdtc)(2)], where M = Mn(II), Fe(II), Co(II), Ni( II), Cu(II), Zn(II), py = pyridine, dedtc = diethyldithiocarbamate and dpdtc = diphenyl-dithiocarbamate, have been synthesized and characterized by elemental analyses, magnetic susceptibility, TGA/DSC and IR in the solid-state, and electronic spectroscopy and conductivity measurement studies in solution. The dithiocarbamato moiety has been found to be symmetrically bonded to the metal. The complexes are proposed to have a distorted-octahedral structure. The ligand field parameters 10 Dq, B and beta have also been evaluated. The value of b indicates a considerable orbital overlap in the complexes. A two-stage decomposition pattern leading to the formation of respective metal sulfide as the end-product has been observed in all the complexes. Their molar conductance indicated them to be non-electrolyte in nitrobenzene.

  DOI：

  10.1081/sim-200066980