| 1401622-40-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1401622-40-9
• 化学式: C₂₅H₂₆N₂O₄
• 分子量: 418.492
• InChiKey: MYZVFLBQOBJAOO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.46
• 重原子数：
  31.0
• 可旋转键数：
  8.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  83.64
• 氢给体数：
  2.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  [ruthenium(II)(hydride)(chloride)(carbonyl)(triphenylarsine)3] 、 以 苯 为溶剂， 以71%的产率得到
  参考文献：
  名称：

  Ruthenium(II) Carbonyl Complexes Containing Unsymmetrical Schiff Bases: Synthesis, Characterization, and Catalytic Applications

  摘要：

  Unsymmetrical Schiff base complexes of general formula [Ru(CO)(B)(L)] (B = PPh3, AsPh3, or Py; L = dianion of unsymmetrical Schiff base ligand) have been synthesized from the reaction of [RuHCl(CO)(EPh3)(2)(B)] (E = P or As; B = PPh3, AsPh3, or Py) with unsymmetrical Schiff bases. The new synthesized complexes were characterized by using elemental analysis, IR spectra, electronic spectra, H-1-NMR, C-13-NMR, and P-31-NMR spectra. All the complexes were tentatively assigned an octahedral geometry. The catalytic activities of the synthesized complexes have been studied and found that the complexes showed efficient catalytic activity for oxidation of alcohols and reduction of ketones.

  DOI：

  10.1080/15533174.2011.614992
• 作为产物：
  描述：

  丹皮酚 、 紫外线吸收剂 UV-9 、 乙二胺 以 乙醇 为溶剂， 反应 5.0h， 生成
  参考文献：
  名称：

  Ruthenium(II) Carbonyl Complexes Containing Unsymmetrical Schiff Bases: Synthesis, Characterization, and Catalytic Applications

  摘要：

  Unsymmetrical Schiff base complexes of general formula [Ru(CO)(B)(L)] (B = PPh3, AsPh3, or Py; L = dianion of unsymmetrical Schiff base ligand) have been synthesized from the reaction of [RuHCl(CO)(EPh3)(2)(B)] (E = P or As; B = PPh3, AsPh3, or Py) with unsymmetrical Schiff bases. The new synthesized complexes were characterized by using elemental analysis, IR spectra, electronic spectra, H-1-NMR, C-13-NMR, and P-31-NMR spectra. All the complexes were tentatively assigned an octahedral geometry. The catalytic activities of the synthesized complexes have been studied and found that the complexes showed efficient catalytic activity for oxidation of alcohols and reduction of ketones.

  DOI：

  10.1080/15533174.2011.614992