二氯苯基锑 | 5035-52-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 二氯苯基锑
• 英文名称: dichlorophenylstibine
• 英文别名: PhSbCl₂；Phenylantimony dichloride；dichloro(phenyl)stibane
• CAS: 5035-52-9
• 化学式: C₆H₅Cl₂Sb
• 分子量: 269.762
• InChiKey: YKLQULRUZFJECG-UHFFFAOYSA-L

物化性质

• 熔点：
  69.5°C

计算性质

• 辛醇/水分配系数(LogP)：
  1.86
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  二氯苯基锑 在 Na₂CO₃ 作用下， 以 乙醇 、 水 为溶剂， 生成 二苯基汞
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sb: Org.Comp.2, 1.3.1.1.5.2, page 119 - 125

  摘要：

  DOI：
• 作为产物：
  描述：

  二羟基苯基氧化锑 在 potassium iodide 二氧化硫 作用下， 以 盐酸 、 水 为溶剂， 以60%的产率得到二氯苯基锑
  参考文献：
  名称：

  Issleib, K.; Balszuweit, A., Zeitschrift fur Anorganische und Allgemeine Chemie

  摘要：

  DOI：
• 作为试剂：
  描述：

  sodium 4-methylbenzenecarboselenoate 、 环己烯 在 三苯基锑 、 二氯苯基锑 、 diphenylantimony chloride 、 N-溴代丁二酰亚胺(NBS) 作用下， 以 乙醚 、 二氯甲烷 为溶剂， 反应 3.0h， 以74%的产率得到bis(4-methylbenzoyl) diselenide
  参考文献：
  名称：

  [（硫代酰基）硫代]-和（酰基硒基）锑和-铋衍生物（（RCSS）x MR和（RCOSe）x MR的合成，结构和某些反应，M = Sb，Bi和x  = 1-3）

  摘要：

  一系列[（硫代酰基）硫代]-和（酰基硒代）锑和[（硫代酰基）硫代]-和（酰基硒代）铋，即（RCSS）x MR和（RCOSe）x MR（M = Sb，Bi，R 通过用锑和卤化铋处理哌啶鎓或碳二硫代硫酸钠和-硒酸酯，可以中等至良好的产率合成1  =芳基，x = 1-3）。（4-MeC 6 H 4 CSS）2 Sb（4-MeC 6 H 4）（9b'），（4-MeOC 6 H 4 COSe）2 Sb（4-MeC 6 H 4）（12c'）的晶体结构），（4-MeOC 6 H 4 COS）2 Bi（4-MeC 6 H 4）（15c'）和（4-MeOC 6 H 4 CSS）2 BiPh（18c）以及（4-MeC 6 H 4确定了COS）2 SbPh（6b）和（4-MeC 6 H 4 COS）3 Sb（7b）（图1和2）。这些化合物具有扭曲的方形锥体结构，其中中心Sb-或Bi原子上的芳基或碳硫基（=酰基硫

  DOI：

  10.1002/hlca.200690070

文献信息

• Five membered zirconium,boron,thallium and gold heterocyclic compounds
  申请人：UNION CARBIDE CORPORATION

  公开号：US03426052A1

  公开（公告）日：1969-02-04

  Organic compounds comprising one or more R1C2R11 groups wherein R1 and R11 are the same or different and each represents hydrogen, halogen or an alkyl, aryl, cycloaliphatic, alkoxy or carboalkoxy group or a silyl group (see Division C3) and C2 represents a carbon-to-carbon bonding are prepared by reacting an organometallic complex, as defined below, with a hydrogenating agent, a halogenating agent, an oxidising agent, an alkylating agent, an alkyne, an element of Group VIa of the Periodic Table (as quoted on pages 392 and 393 of The Handbook of Chemistry and Physics, 37th edition, published by the Chemical Rubber Publishing Co.) or a reactive compound as defined below. The term "organo-metallic complex" is defined as a complex having the general formula Mx(CO)y (R1C2R11)z wherein M represents iron, nickel, ruthenium, rhodium, palladium, osmium, iridium, platinum, manganese, rhenium, chromium, molybdenum, or tungsten, CO represents a carbonyl group bonded to the said metal, to the R1C2R11 group, or to both, R1C2R11 is a group as defined above, x is from 1 to 4, y is from 1 to 10, z is from 1 to 6, prepared by the method described and claimed in Specification 885,514. The expression "reactive compound" is defined as a compound selected from nitrosyl chloride, nitrosobenzene, N,N-dichloro-p-toluenesulphonamide, phenyldichlorophosphine, benzyldichlorophosphine, benzyldibromophosphine, phenyldichloroarsine, polysulphides, mono- and di-halogeno-phosphines, -arsines or -stibines, polyselenides, sulphur dioxide, potassium selenocyanide (KSeCN), sulphur dichloride and triphenylphosphine selenide. Complexes in which the carbonyl group bonded to the metal is partially replaced by a nitronyl, a substituted stibine, a substituted arsine, or a substituted phosphine may also be used. Numerous suitable complexes and reactants of the above types are specified, some of the reactants falling into more than one of the specified classes. Many types of compound which may be obtained by the process of the invention are specified including ketones, phenols, esters, ethers, sulphonamides, halogen compounds and heterocyclic compounds containing nitrogen, phosphorus, arsenic, oxygen, sulphur or selenium as the hetero-atom. Some of the compounds produced are stated to be novel, in particular, 2,5-dimethyl-3,4-diphenylthiophene, tetraphenylselenophene, pentaphenylphosphole, P-benzyl-tetraphenylphosphole, pentaphenylarsole, tetraethylselenophene, tetraphenyl-g -pyrone tetraphenyl - 1 - thia - 4 - pyrone, tetraphenyl - 1 - selena-4-pyrone, 1,4-bis-(p-toluene-sulphonamido) 1, 2, 3, 4-tetraphenylbutadiene, 1,4-bis-(p-toluene-sulphonamido) 1, 4-dimethoxybutane, 1, 2, 3, 4-tetraphenyl-5, 6-bis-(p-chlorophenyl)-benzene and compounds of the formulae: <;FORM:0966131/C1/1>; and <;FORM:0966131/C1/2>; wherein the groups R may be identical or different and may take any of the values given above for R1 and R11, and wherein X represents phosphorus or arsenic. Examples are given. The examples also disclose the following reactions: (6) the isomerisation of cis-dibenzoyl-stilbene to the trans-isomer; (17) conversion of pentaphenylphosphole to the corresponding P-oxide, -sulphide or -selenide; (19) reaction of benzyldichlorophosphine with 1,4-dilithio-1,2,3,4-tetraphenylbutadiene to give P-benzyl-tetraphenyl-phosphole; (20) reaction of phenyldichloroarsine with 1,4-dilithio-1,2,3,4-tetraphenylbutadiene to give pentaphenylarsole; (23) heating hexyne-3 with sulphur to give tetraethylthiophene; (25) heating hexyne-3 with potassium polyselenide to give tetraethylselenophene. The compounds of formula (1) above may be converted to the corresponding phosphole or arsole oxides, sulphides or selenides or may undergo Diels-Alder reactions, for example with maleic anhydride. The compounds of formula (2) above, or the corresponding compounds in which the hetero-atom is a Group VIa (as defined above) other than selenium, may be reacted with ammonia to give g -pyridones. Some of the products of the process of the invention are stated to be useful as insecticides, fluorescent materials, chelating agents and polar solvents, and in the production of polymers. The Provisional Specification refers also to the use of complexes of the above type in which the metal is cobalt.ALSO:Organo-silicon compounds are prepared by reacting an organo-metallic complex, as defined below, with a silicon compound such as phenyltrimethylsilyl acetylene and bis-(trimethylsilyl) acetylene. The term "organo-metallic complex" is defined as a complex having the general formula Mx(CO)y(R1C2R11)z wherein M represents iron, nickel, ruthenium, rhodium, palladium, osmium, iridium, platinum, manganese, rhenium, chromium, molybdenum or tungsten, CO represents a carbonyl group bonded to the said metal, to the R1C2R11 group, or to both, R1C2R11 is a hydrocarbon group, x is from 1 to 4, y is from 1 to 10, z is from 1 to 6, prepared by the method described and claimed in Specification 885,514. Products of the formulae: <;FORM:0966131/C3/1>; wherein X represents phosphorus or arsenic and the groups R may be identical or different and may be a silyl group, are stated to be novel. Examples 19 and 20 of the Provisional Specification describe the preparation of 1,3-bis-(trimethylsilyl) - 2, 4, 5, 6 - tetraphenylbenzene, 1, 3, 5 - tris - (trimethylsilyl) - 2, 4, 6 - triphenylbenzene, trimethylsilyl - triphenyl - cyclopentadienones, 2, 5 - bis - (trimethylsilyl) - 3, 4-diphenylcyclopentadienone and 2, 4 - bis - (trimethylsilyl) - 3, 5 - diphenylcyclopentadienone, using complexes of the above type in which the metal is cobalt.ALSO:Hydrocarbons comprising one or more R1C2R11 groups wherein R1 and R11 ar the same or different and each represents hydrogen or an alkyl, aryl or cycloaliphatic group and C2 represents a carbon-to-carbon bonding are prepared by reacting an organo-metallic complex, as defined below, with a hydrogenating agent or an alkyne. The term "organo-metallic complex" comprises complexes having the general formula Mx(CO)y(R1C2R11)z wherein M represents iron, nickel, ruthenium, rhodium, palladium, osmium, iridium, platinum, manganese, rhenium, chromium, molybdenum or tungsten, CO represents a carbonyl group bonded to the said metal, to the R1C2R11 group, or to both, R1C2R11 is a group as defined above, x is from 1 to 4, y is from 1 to 10, z is from 1 to 6, prepared by the method described and claimed in Specification 885,514. Complexes in which the carbonyl group bonded to the metal is partially replaced by a nitrosyl, a substituted stibine, a substituted arsine, or a substituted phosphine may also be used. Numerous suitable complexes and reactants of the above types are specified. Examples describe the preparation of 1, 2, 3, 4-tetraphenyl-butadiene, 1,2,3,4-tetraphenylbut - 1 - ene, 1,2,3,4 - tetraphenylbutane, 1,2,3,4 - tetraphenylbutane, dibenzyl, stilbene, and an unidentified compound of the formula (C6H5.C2.C6H5)3H2, from complexes containing tetraphenylacetylene by reduction with lithium aluminium hydride or sodium and ethanol in liquid ammonia and of 1,2,3,4-tetraphenylbenzene and hexaphenylbenzene by reacting diphenyl-acetylene with Fe(CO)4(C6H5C2H)2. The Provisional Specification also refers to the use of complexes of the above type in which the metal is cobalt.

  您好！有什么可以帮助您的吗？
• Structural, Spectroscopic and Computational Examination of the Dative Interaction in Constrained Phosphine-Stibines and Phosphine-Stiboranes
  作者：Brian A. Chalmers、Michael Bühl、Kasun S. Athukorala Arachchige、Alexandra M. Z. Slawin、Petr Kilian

  DOI：10.1002/chem.201500281

  日期：2015.5.11

  computational methods. The P–Sb dative interactions in both series range from strongly bonding to non‐bonding as the Lewis acidity of the Sb acceptor is decreased. In the pentavalent antimony series, a significant change in the P–Sb distance is observed between SbClPh3 and SbCl2Ph2 derivatives 6 and 7, respectively, consistent with a change from a bonding to a non‐bonding interaction in response to relatively

  一系列膦-锑化氢和磷化氢-stiborane的周围取代苊含有五价基团的所有排列的SbCl Ñ博士4- Ñ（5 - 9），以及三价基团的SbCl 2，的Sb（R）Cl和灰飞虱2（2 - 4，R ＝ Ph，Mes）被合成并通过单晶衍射和多核NMR光谱充分表征。另外，通过DFT计算方法研究了这些物质中的键合。当Sb受体的Lewis酸度降低时，这两个系列中的P–Sb双向相互作用的范围从强键到非键。在五价锑系列，在P-Sb的距离的显著变化之间观察到 SbClPh 3和的SbCl 2博士2个衍生物6和7分别与从接合到非键合相互作用，以改变响应一致受体的路易斯酸度相对较小的修饰。在Sb中III系列，观察到两种几何形式。SbCl 2衍生物2中的P–Sb键长度与正常键（而非导数键）的预期一致。而出乎意料的是，膦stiborane络合物5 - 9表示σ的第一实施例4 P→σ 6 Sb的结构基序。
• Geminally Substituted Tris(acenaphthyl) and Bis(acenaphthyl) Arsines, Stibines, and Bismuthine: A Structural and Nuclear Magnetic Resonance Investigation
  作者：Brian A. Chalmers、Christina B. E. Meigh、Phillip S. Nejman、Michael Bühl、Tomáš Lébl、J. Derek Woollins、Alexandra M. Z. Slawin、Petr Kilian

  DOI：10.1021/acs.inorgchem.6b01079

  日期：2016.7.18

  pnictogens (iPr2P-Ace)3E (2–4) (E = As, Sb, or Bi; Ace = acenaphthene-5,6-diyl) and (iPr2P-Ace)2EPh (5 and 6) (E = As or Sb) were synthesized and fully characterized by multinuclear nuclear magnetic resonance (NMR), high-resolution mass spectrometry, elemental analysis, and single-crystal X-ray diffraction. The molecules adopt propeller-like geometries with the restricted rotational freedom of the

  三（ac基）-和双（ac基）取代的光气原（i Pr 2 P-Ace）3 E（2-4）（E = As，Sb或Bi; Ace = ena-5,6-二基）和（我镨2 P-ACE）2 EPH（5和6）（E = As或Sb）的合成，并通过多核核磁共振（NMR），高分辨率质谱，元素分析，单晶完全表征X-射线衍射。这些分子采用螺旋桨状的几何形状，且空间受限的i Pr 2的旋转自由度受到限制P-Ace基团具有明显的NMR特征。在三（ac）类（2-4）中，磷原子在31 P 1 H} NMR光谱中是等时的，并且三个基部分围绕E–C ipso键的旋转被锁定。另一方面，双（ac基）物质表现出通量行为，在31 P 1 H}可变温度NMR光谱中导致AX转变为A 2自旋系统。这可以阐明显着的11.5 Hz（对于5）和25.8 Hz（对于6的通孔耦合（8TS J PP））在低温下。另外，在中间温度区域以及在合并时
• A versatile synthesis of the group 15 and 16 3-benzoheteroepines involving the first isolated examples of several C-unsubstituted 3-benzoheteroepines
  作者：Shuji Yasuike、Tsutomu Kiharada、Jyoji Kurita、Takashi Tsuchiya

  DOI：10.1039/cc9960002183

  日期：——

  Group 15 (P, As, Sb and Bi) and group 16(S, Se and Te) 3-benzoheteroepines 2, involving the first isolated examples of several C-unsubstituted fully unsaturated 3-benzoheteroepines, are prepared in two steps from (Z,Z)-o-bis(β-bromovinyl)benzene 4 and their thermal stabilities examined.

  第15族元素(P、As、Sb、Bi)和第16族元素(S、Se、Te)的三价苯并杂环化合物2，其中包含多个首个被分离出的无碳取代的全不饱和三价苯并杂环化合物，通过两步法从(Z,Z)-邻双(溴乙烯基)苯4制备而得，并对其热稳定性进行了检验。
• Size Matters: Synthesis of Group 13 Metal‐Substituted Dipnictanes by E‐C Bond Homolysis
  作者：Christoph Helling、Christoph Wölper、Stephan Schulz

  DOI：10.1002/ejic.202000747

  日期：2020.11.30

  diyls LM (M = Al, Ga, In; L = HC[C(Me)N(Dip)]2, Dip = 2,6‐iPr2C6H3) with oxidative addition of the E‐Cl bond to a unique series of metalylpnictanes [L(Cl)M](Ph)ECp* (E = As, M = Al 3, Ga 4, In 5; E = Sb, M = Al 6, Ga 7, In 8). Thermal treatment of 4 and 6–8 results in homolytic E‐C bond scission with Cp* radical liberation, yielding the corresponding dipnictanes [L(Cl)M](Ph)E}2 (E = As, M = Ga 9; E =

  Pnictanes Cp *（Ph）ECl（E = As 1，Sb 2 ; Cp * = C 5 Me 5）与基团13 diyls LM（M = Al，Ga，In; L = HC [C（Me）N（Dip） ）] 2，Dip = 2,6 ‐ i Pr 2 C 6 H 3），同时将E‐Cl键氧化成独特的一系列金属甲氧烷[L（Cl）M]（Ph）ECp *（E = As， M ＝ Al 3，Ga 4，In 5； E ＝ Sb，M ＝ Al 6，Ga 7，In 8。热处理4和6 – 8导致具有Cp *自由基释放的均质E-C键断裂，产生相应的二茂铁L（Cl）M]（Ph）E} 2（E = As，M = Ga 9 ; E = Sb，M = Al 10，Ga 11，In 12）。化合物1 - 12由NMR（进行了表征1 H，13 C）和IR光谱，元素分析，和单晶X射线衍射（3 - 12）。