soybean oil | 10542-42-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 甘油脂
• 英文名称: soybean oil
• 英文别名: 1-Linoleoyloxy-2-oleoyloxy-3-α-linolenoyloxypropan；Glycerin-1-linolat-2-oleat-3-linolenat；[1-[(9Z,12Z)-octadeca-9,12-dienoyl]oxy-3-[(9Z,12Z,15Z)-octadeca-9,12,15-trienoyl]oxypropan-2-yl] (Z)-octadec-9-enoate
• CAS: 10542-42-4
• 化学式: C₅₇H₉₈O₆
• 分子量: 879.402
• InChiKey: POGJAUDNOWLVNS-FIRLUSQXSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  20.3
• 重原子数：
  63
• 可旋转键数：
  50
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.74
• 拓扑面积：
  78.9
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  soybean oil 反应 2.0h， 生成
  参考文献：
  名称：

  WO2023/43593

  摘要：

  公开号：
• 作为产物：
  描述：

  甘油三油酸酯 、 甘油三亚油酸酯 、 三亚麻精 在 sodium methylate 作用下， 以 正己烷 为溶剂， 反应 0.5h， 生成 1-O-linolenoyl-2-O-linoleoyl-3-O-oleoyl glycerol 、 soybean oil 、 α-Linoleoyl-β-linolenoyl-α'-oleoyl-triglycerid
  参考文献：
  名称：

  Regioisomeric Characterization of Triacylglycerols Using Silver-Ion HPLC/MS and Randomization Synthesis of Standards

  摘要：

  银离子正相高效液相色谱（HPLC）为脂质提供了优越的分离选择性，这些脂质在脂肪酸链中双键的数量和位置上存在差异，包括在优化条件下对甘油三酯（TG）位置异构体的分辨。我们的银离子HPLC方法是基于三根总长度为75厘米的柱子耦合以及一个新的由己烷、乙腈和丙酮醇组成的移动相梯度，这相比于之前使用的移动相提供了更好的分辨率和重复性。在我们的工作中，利用单酸TG标准的化学酯交换（随机化）来生成TG的位置异构体系列，因为这可以在明确定义的浓度比下提供脂肪酸在TG中的随机分布。首次报道了含有最多三个双键的位置异构体TG对的基线分离以及含有四到七个双键的TG位置异构体的部分分离。我们的银离子高效液相色谱/质谱（HPLC/MS）方法应用于植物油和动物脂肪的复杂样品的位置异构体特性鉴定，结果清楚地展示了在植物（主要是不饱和脂肪酸）和动物脂肪（主要是饱和脂肪酸）中sn-2占位偏好的不同。

  DOI：

  10.1021/ac900150j

文献信息

• Certain metathesized natural oil triacylglycerol polyols for use in polyurethane applications and their related properties
  申请人：Trent University

  公开号：US10000442B2

  公开（公告）日：2018-06-19

  Metathesized triacylglycerol polyols derived from certain natural oils, including canola oil, and their related physical properties are disclosed. Such metathesized triacylglycerol polyols are also used as a component of polyurethane applications, including polyurethane foams.

  公开了从某些天然油（包括菜籽油）中提取的元化三酰甘油多元醇及其相关物理性质。此类偏聚三酰甘油多元醇还可用作聚氨酯应用（包括聚氨酯泡沫）的成分。
• MODIFIED NATURAL OILS AND PRODUCTS MADE THEREFROM
  申请人：Casati Francois M.

  公开号：US20110218264A1

  公开（公告）日：2011-09-08

  A modified natural oil made from reacting at least one natural oil or fat comprising at least one ene moiety with at least one of an enophile or dienophile mixture to form at least one modified natural oil, and reacting the at least one modified natural oil which may be used in a variety of processes.
• METATHESIS DEPOLYMERIZATION USING ACRYLATES
  申请人：UNIVERSITY OF FLORIDA RESEARCH FOUNDATION, INC.

  公开号：US20150232406A1

  公开（公告）日：2015-08-20

  Olefin metathesis between an acrylate monomer and a polyene comprising molecule or polymer is employed as a method of cross-metathesizing or depolymerizing the molecule. The metathesis reaction forms a telechelic acrylate molecule that is a monomer, oligomer or polymer. The telechelic acrylate molecule can be employed as a monomer for condensation polymerization.
• CERTAIN METATHESIZED NATURAL OIL TRIACYLGLYCEROL POLYOLS FOR USE IN POLYURETHANE APPLICATIONS AND THEIR RELATED PROPERTIES
  申请人：Trent University

  公开号：US20150299099A1

  公开（公告）日：2015-10-22

  Metathesized triacylglycerol polyols derived from certain natural oils, including canola oil, and their related physical properties are disclosed. Such metathesized triacylglycerol polyols are also used as a component of polyurethane applications, including polyurethane foams.
• SOLVENT-CONTAINING DRY FILM AND METHOD FOR APPLYING THE SAME ON A SUBSTRATE
  申请人：ETERNAL MATERIALS CO., LTD.

  公开号：US20160017105A1

  公开（公告）日：2016-01-21

  The present disclosure relates to a solvent-containing dry film and a method for applying a dry film on a substrate. The dry film includes a carrier and a resin layer. The resin layer contains a resin composition and a solvent and the solvent is present in a total amount of at least 5 wt % based on the total weight of the resin layer. The dry film of the present invention can be applied onto a substrate without the use of a prior art vacuum lamination apparatus. The application process is simple and is more cost-efficient than the prior art techniques.