1,1,2,2,3,3,4,4,5,5,6,6,6-十三氟己烷-1-磺酰氯 | 55591-23-6

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 磺酰卤
• 中文名称: 1,1,2,2,3,3,4,4,5,5,6,6,6-十三氟己烷-1-磺酰氯
• 英文名称: 1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluorohexane-1-sulfonyl chloride
• 英文别名: perfluorohexanesulphonyl chloride；perfluorohexyl-sulphonyl chloride；1,1,2,2,3,3,4,4,5,5,6,6,6-Tridecafluorohexane-1-sulphonyl chloride
• CAS: 55591-23-6
• 化学式: C₆ClF₁₃O₂S
• 分子量: 418.563
• InChiKey: DVRQSALCLMEVIH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  23
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  42.5
• 氢给体数：
  0
• 氢受体数：
  15

反应信息

• 作为反应物：
  描述：

  1,1,2,2,3,3,4,4,5,5,6,6,6-十三氟己烷-1-磺酰氯 在 氨 作用下， 以75%的产率得到azane;1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluorohexane-1-sulfonamide
  参考文献：
  名称：

  Podol'skii, A. V.; Kachalkova, M. I.; Ilatovskii, R. E., Journal of general chemistry of the USSR, 1990, vol. 60, # 6.2, p. 1242 - 1244

  摘要：

  DOI：
• 作为产物：
  描述：

  全氟己基碘烷 以 N,N-二甲基甲酰胺 为溶剂， 以89%的产率得到1,1,2,2,3,3,4,4,5,5,6,6,6-十三氟己烷-1-磺酰氯
  参考文献：
  名称：

  DE2915800

  摘要：

  公开号：
• 作为试剂：
  描述：

  1-特-丁基吡咯 在 1,1,2,2,3,3,4,4,5,5,6,6,6-十三氟己烷-1-磺酰氯 、 dichlorotris(triphenylphosphine)ruthenium(II) 作用下， 以 正戊烷 为溶剂， 反应 24.0h， 以9%的产率得到1-(tert-butyl)-3-(tridecafluorohexyl)pyrrole
  参考文献：
  名称：

  Kamigata, Nobumasa; Ohtsuka, Takeshi; Fukushima, Takamasa, Journal of the Chemical Society. Perkin transactions I, 1994, # 10, p. 1339 - 1346

  摘要：

  DOI：

文献信息

• REACTIONS OF PERFLUOROALKANE-SULFONYL CHLORIDES WITH SILYL ENOL ETHERS CATALYZED BY A RUTHENIUM(II) PHOSPHINE COMPLEX
  作者：Nobumasa Kamigata、Kumiko Udodaira、Toshio Shimizu

  DOI：10.1080/10426509708031590

  日期：1997.10.1

  Abstract Reactions of trifluoromethane- and tridecafluorohexanesulfonyl chlorides with silyl enol ethers have been investigated in the presence of a ruthenium(II) phosphine complex. Perfluoroalkylation and chlorination occurred depending on the substituent of silyl enol ether; i.e. perfluoroalkylated compound was selectively obtained in the reactions with silyl enol ether possessing an electron-withdrawing

  摘要 在钌 (II) 膦配合物存在下，研究了三氟甲烷和十三氟己烷磺酰氯与甲硅烷基烯醇醚的反应。全氟烷基化和氯化反应的发生取决于甲硅烷基烯醇醚的取代基；即与具有吸电子基团的甲硅烷基烯醇醚反应选择性地得到全氟烷基化化合物，而与具有给电子基团的甲硅烷基烯醇醚反应选择性地生成氯化物。
• Preparation of perfluoroalkane carboxylic and sulphonic acid derivatives by the action of metallic couples on perfluoroalkyl iodides in dimethyl sulphoxide
  作者：Hubert Blancou、Patrice Moreau、Auguste Commeyras

  DOI：10.1039/c39760000885

  日期：——

  Perfluoroalkyl iodides react with carbon dioxide and sulphur dioxide, in the presence of zinc–copper type metallic couples in dimethyl sulphoxide, to give the corresponding carboxylic and sulphonic acids derivatives in 40–80% yields.

  在二甲基亚砜中存在锌铜型金属对的情况下，全氟烷基碘化物与二氧化碳和二氧化硫反应，以40％至80％的收率得到相应的羧酸和磺酸衍生物。
• AROMATIC IMIDE COMPOUND AND METHOD FOR PRODUCING SAME
  申请人：AZ ELECTRONIC MATERIALS (LUXEMBOURG) S.A.R.L.

  公开号：US20150299132A1

  公开（公告）日：2015-10-22

  [Problem] to provide an aromatic imide compound wherein the sensitivity for visible light such as g-line, h-line etc. is increased and solubility is also improved. [Means for solving problem] The aromatic imide compound of the invention is a compound represented by the formula (1) below (in the formula, R 1 represents a haloalkyl group having 1 to 7 carbon atoms or a haloaryl group, R 2 represents a group containing a substituted or unsubstituted, aliphatic or aromatic group which may have a heteroatom, and adjacent R 2 s may form an imido group by connecting each other, R 3 represent a halogen atom or a hydrocarbon group, m is zero or an integer of 1 or more, n is zero or an integer of 1 or more, and a sum of n and m is 1 to 6). These compounds are obtained by following processes. A halogenated naphtharic anhydride is reacted with an aromatic group-containing hydrocarbon such as ethynylbenzene to prepare a naphthalic anhydride substituted by an aromatic group-containing group. The obtained compound is then reacted with hydroxylamine hydrochloride to be made N-hydoxyimidization. Finally, the resultant compound is reacted with a sulfonyl halide such as trifluoromethylsulfonyl chloride to obtain the objective compound.

  [问题] 提供一种芳香酰亚胺化合物，其中对于可见光如g线、h线等的敏感性增加，溶解度也得到改善。 [解决问题的方法] 本发明的芳香酰亚胺化合物是以下式(1)所表示的化合物(在该式中，R1表示具有1至7个碳原子的卤代烷基或卤代芳基，R2表示含有取代或未取代的脂肪族或芳香族基团，该基团可能具有杂原子，相邻的R2可以通过连接形成亚胺基团，R3表示卤素原子或碳氢基团，m为0或1或更多的整数，n为0或1或更多的整数，n和m的总和为1至6)。这些化合物是通过以下过程获得的。将卤代萘酐与含芳香族基团的烃类化合物如乙炔基苯反应，制备出被芳香族基团取代的萘酐。然后将获得的化合物与盐酸羟胺反应，得到N-羟基亚胺。最后，将所得化合物与三氟甲磺酰卤如三氟甲磺酰氯反应，得到目标化合物。
• A Novel Perfluoroalkylation of Pyrroles with Perfluoroalkanesulfonyl chloride Catalyzed by a Ruthenium(II) Phosphine Complex
  作者：Nobumasa Kamigata、Takeshi Ohtsuka、Masato Yoshida、Toshio Shimizu

  DOI：10.1080/00397919408010214

  日期：1994.7

  Abstract Direct perfluoroalkylation of N-substituted pyrroles with tridecafluorohexanesulfonyl chloride catalyzed by a ruthenium(II) phosphine complex proceeds regioselectively in high yield.

  摘要 在钌 (II) 膦配合物催化下，N-取代吡咯与十三氟己烷磺酰氯的直接全氟烷基化反应以高产率进行区域选择性。
• Fluoroalkyl derivative and process for preparing the same
  申请人：Nippon Oil and Fats Co., Ltd.

  公开号：US05118879A1

  公开（公告）日：1992-06-02

  Fluoroalkyl derivatives which are novel compounds represented by the following general formula (I) or (II) of: ##STR1## or R.sub.1 --CH.dbd.CR.sub.2 (CF.sub.2).sub.n F (II) (wherein R.sub.1 stands for ##STR2## (where X stands for a hydrogen atom, a chlorine atom, a bromine atom, a fluorine atom, an iodine atom, a methyl group, an ethyl group, a methoxy group, an ethoxy group or a nitro group), an aroyloxy group, or an alkyl or alkoxycarbonyl group having 1 to 20 carbon atoms, and R.sub.2 stands for a hydrogen atom or a methyl group; and n stands for an integer of from 1 to 20.) A process for the preparation of the derivative is a process comprising reacting an olefin compound and a fluoroalkanesulfonyl chloride in the presence of a metal catalyst, or a process comprising an additional alkali treatment step which follows the aforementioned process.

  以下是一种新型化合物的通式（I）或（II）所代表的氟烷基衍生物：##STR1## 或 R.sub.1 --CH.dbd.CR.sub.2 (CF.sub.2).sub.n F（II）（其中R.sub.1代表##STR2##（其中X代表氢原子、氯原子、溴原子、氟原子、碘原子、甲基基团、乙基基团、甲氧基基团、乙氧基基团或硝基基团）、芳酰氧基团或具有1至20个碳原子的烷基或烷氧羰基团，R.sub.2代表氢原子或甲基基团；n代表1至20的整数。一种制备衍生物的方法是在金属催化剂的存在下反应烯烃化合物和氟烷磺酰氯，或者是在上述过程后进行碱处理步骤的过程。