Ru₂(OAc)₄Cl

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Ru₂(OAc)₄Cl
• 英文别名: chlororuthenium(2+);tetraacetate
• 化学式: C₈H₁₂Cl₂O₈Ru₂
• 分子量: 509.224
• InChiKey: VJFVKLYKWCORIY-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Ru₂(OAc)₄Cl 、 sodium oxalate 在 氧气 作用下， 以 水 为溶剂， 生成
  参考文献：
  名称：

  Ti（III）还原二氧杂妥二酮合钌（III）时的球内电子转移

  摘要：

  DOI：

  10.1016/s0020-1693(00)82526-8

文献信息

• <i>tert</i>-Butyl Hydroperoxide Oxygenation of Organic Sulfides Catalyzed by Diruthenium(II,III) Tetracarboxylates
  作者：Leslie Villalobos、Julia E. Barker Paredes、Zhi Cao、Tong Ren

  DOI：10.1021/ic401588j

  日期：2013.11.4

  Diruthenium(II,III) carboxylates Ru2(esp)2Cl (1a), [Ru2(esp)2(H2O)2]BF4 (1b), and Ru2(OAc)4Cl (2) efficiently catalyze the oxygenation of organic sulfides. As noted in a previous work, 1a is active in oxygenation of organic sulfides with tert-butyl hydroperoxide (TBHP) in CH3CN. Reported herein in detail is the oxygenation activity of 1a, 1b, and 2, with the latter being highly selective in oxo-transfer

  钌（II，III）有效地使Ru 2（esp）2 Cl（1a），[Ru 2（esp）2（H 2 O）2 ] BF 4（1b）和Ru 2（OAc）4 Cl（2）羧酸化催化有机硫化物的氧化。如先前的工作所述，1a在CH 3 CN中用叔丁基氢过氧化物（TBHP）氧化有机硫化物方面具有活性。本文详细报道了1a，1b和2的氧合活性，后者在环境条件下使用TBHP对有机硫化物的羰基转移具有很高的选择性。通过将1a或1b直接溶于2当量的TBHP，可以实现无溶剂氧化反应，使用1b可以达到2056 h –1的TOF 。还检查了与催化剂1a和2反应的速率对催化剂和氧化剂浓度的依赖性。Ru 2（OAc）4 Cl可以被TBHP动力学饱和；但是Ru 2（esp）2Cl不显示饱和动力学。通过使用一系列对位取代的硫代茴香醚，对1a和2建立了线性自由能关系，其中反应常数（ρ）为负，而1a的反应常数约为2的一半。鉴于这些反应性
• Metal–Metal Bonded Diruthenium Unit Axial-Capped by Di-<i>tert</i>-butylphenolate: [Ru₂(O₂CCH₃)₂(<i>t</i>-Busal-R′py)₂]⁻(<i>t</i>-Busal-R′py²⁻=<i>N</i>-(R′-2-pyridyl)-2-oxido-3,5-di-<i>tert</i>-butylbenzylaminato; R′ = H, 4-Me, and 5-Me)
  作者：Hitoshi Miyasaka、Toru Izawa、Shinya Takaishi、Kunihisa Sugimoto、Ken-ichi Sugiura、Masahiro Yamashita

  DOI：10.1246/bcsj.79.612

  日期：2006.4

  2 CCH 3 ) 2 -(5-Rsalpy) 2 ] - (R = H. Me. Cl, Br, and NO 2 ); two acetate and two t-Busal-R'py 2- ligands are respectively located around the Ru 2 unit in a trans fashion, where the t-Busal-R'py 2- ligand acts as a tridentate ligand having both bridging and chelaling characters to form the M-M bridging/axial-chelating mode. Their Ru-Ru bonded core with an electronic configuration of σ 2 π 4 δ 2 (π*δ*

  三种二钌化合物，|Na(18-crown-6)(thf) 2 ][Ru 2 (C) 2 CCH 3 ) 2 (t-Busalpy) 2 ] (1), |K(18-crown-6)( thf) 2 ]-[Ru 2 (O 2 CCH 3 ) 2 (t-Busal-4-Mepy) 2 ] (2)。[K(18-crown-6)(thf)(H 2 O)][K(18-crown-6)(thf)(MeO)][Ru 2 (O 2 CCH 3 ) 2 -(t-Busal) -5-Mepy) 2 ] (3) (18-crown-6 = 1.4.7.10.13.16-hexaoxocyclooctadecane; 18-crown-6-ether)，已通过Ru 2 (O 2 CCH 3 ) 4 Cl 与新制备的三齿桥接/螯合配体。N-(2-pyridyl)-2-oxido-3,5-di-tert-butylbenzy]aminato
• Preparation and structural characterization of Os(II) and Ru(II) complexes, MCl2(vdpp)2 [M = Os or Ru, vdpp = 1,1-bis(diphenylphosphino)ethene]
  作者：F.A. Cotton、M.P. Diebold、M. Matusz

  DOI：10.1016/s0277-5387(00)80966-3

  日期：——

  group P21/c with these cell dimensions: a = 11.046(2)Å, b = 18.168(3)Å, c = 12.678(3)Å, β = 110.24(2)° and V = 2387(2)Å3 for1 and a = 11.055(1)Å, b = 18.199(3)Å, c = 12.693(2)Å, β = 110.16(1)°, V = 2392(1)Å3 for2. The molecules of1 and2 are isostructural. Metal atoms reside on inversion centers relating the two halves of the molecules. The complexes are six-coordinate with two four-membered chelate

  研究了OS 2（O 2 CCH 3）4 Cl 2与vdpp [vdpp ＝ 1，1-双（二苯基膦基）乙烯]之间的反应。当反应物，在氯化锂的存在下，在甲苯中加热OSCL 2（vdpp）2，1，被形成了。在相似的反应的Ru 2（O 2 CCH 3）4 Cl可vdpp得到的RuCl 2（vdpp）2，2。使用X射线晶体学阐明了1和2的分子结构。1和1的单晶从二氯甲烷己烷中生长的2在空间群P 2 1 / c中具有以下晶胞尺寸结晶：a = 11.046（2）Å，b = 18.168（3）Å，c = 12.678（3）Å，β= 110.24（2）°和V = 2387（2）埃3为1和一个= 11.055（1）埃，b = 18.199（3）埃，c ^ = 12.693（2）埃，β= 110.16（1）°，V = 2392（1）埃3为2。1和2的分子是同构的。金属原子位于与分子的两个半部分相关的反转中心上。
• A neutral paddlewheel-type diruthenium(III) complex with benzamidinato ligands: Synthesis, crystal structure, magnetism, and electrochemical and absorption properties
  作者：Yusuke Kataoka、Saki Mikami、Hiroshi Sakiyama、Minoru Mitsumi、Tatsuya Kawamoto、Makoto Handa

  DOI：10.1016/j.poly.2017.03.005

  日期：2017.11

  A new neutral diruthenium(III) complex coordinated with benzamidinato (bam) ligands, [Ru-2(bam)(4)Cl-2]center dot H2O (1), was synthesized and characterized, and its electronic structure was closely investigated via magnetic susceptibility, absorption spectrum, cyclic voltammetry, and density functional theory (DFT) calculations. Single crystal X-ray diffraction analysis revealed that complex 1 has a typical paddlewheel-type structure with a Ru-Ru bond (bond length: 2.342(1) angstrom), in which the diruthenium (Ru-2) core is coordinated by four equatorially mu-bridging barn ligands and two axial Cl- ions. The magnetic study and DFT calculations proved that complex 1 has a triplet spin state (S = 1) and a unique electronic structure (pi(4)delta(2)pi*(2)sigma(2)). Absorption spectral feature and electrochemical property of complex 1 were also carefully investigated both experimentally and theoretically in this study. (C) 2017 Elsevier Ltd. All rights reserved.
• Reaction of binuclear carboxylate complexes of molybdenum, rhenium, ruthenium, and rhodium with tert-butyl isocyanide: metal-metal bond cleavage vs. bond retention
  作者：Gregory S. Girolami、Richard A. Andersen

  DOI：10.1021/ic50221a022

  日期：1981.7