trans,trans-Nona-3,6-dien-1,9-dicarbonsaeuredimethylester | 36615-33-5

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: trans,trans-Nona-3,6-dien-1,9-dicarbonsaeuredimethylester
• 英文别名: dimethyl (3E,6E)-nona-3,6-dienedioate
• CAS: 36615-33-5
• 化学式: C₁₁H₁₆O₄
• 分子量: 212.246
• InChiKey: GAZZBOUXCNKUDK-YDFGWWAZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  15
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  壬二酸 以 正己烷 为溶剂， 生成 trans,trans-Nona-3,6-dien-1,9-dicarbonsaeuredimethylester
  参考文献：
  名称：

  Solution photochemistry. X. Effects of double-bond geometry and of increasing double-bond separation on the photochemical reactions of acyclic nonconjugated dienes

  摘要：

  DOI：

  10.1021/jo00799a021

文献信息

• Ring opening cross-metathesis reaction of cyclic olefins with seed oils and the like
  申请人：Lee Woo Choon

  公开号：US20080064891A1

  公开（公告）日：2008-03-13

  This invention relates generally to olefin metathesis, and more particularly relates to the ring-opening, ring insertion cross-metathesis of cyclic olefins with internal olefins such as seed oils and the like. In one embodiment, a method is provided for carrying out a catalytic ring-opening cross-metathesis reaction, comprising contacting at least one olefinic substrate with at least one cyclic olefin as a cross metathesis partner, in the presence of a ruthenium alkylidene olefin metathesis catalyst under conditions effective to allow ring insertion cross metathesis whereby the cyclic olefin is simultaneously opened and inserted into the olefinic substrate. The invention has utility in the fields of catalysis, organic synthesis, and industrial chemistry.
• US8067623B2
  申请人：——

  公开号：US8067623B2

  公开（公告）日：2011-11-29
• Solution photochemistry. X. Effects of double-bond geometry and of increasing double-bond separation on the photochemical reactions of acyclic nonconjugated dienes
  作者：John R. Scheffer、Rockford A. Wostradowski

  DOI：10.1021/jo00799a021

  日期：1972.7.29