5-十三烷醇 | 58783-82-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 5-十三烷醇
• 英文名称: tridecanol-5-ol
• 英文别名: Tridecan-5-ol；5-tridecanol；Tridecanol-(5)
• CAS: 58783-82-7
• 化学式: C₁₃H₂₈O
• 分子量: 200.365
• InChiKey: GRDYSMCYPTWIPT-UHFFFAOYSA-N

物化性质

• 熔点：
  26.15°C (estimate)
• 沸点：
  268.11°C (estimate)
• 密度：
  0.7947 (estimate)
• 保留指数：
  1574

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  14
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

安全信息

• 危险性防范说明：
  P264,P280,P302+P352,P337+P313,P305+P351+P338,P362+P364,P332+P313
• 危险性描述：
  H315,H319
• 储存条件：
  存储条件：室温、密封且干燥环境中保存。

反应信息

• 作为反应物：
  描述：

  5-十三烷醇 在 铬酸 作用下， 以80%的产率得到5-十三烷酮
  参考文献：
  名称：

  Schmitz; Sonnenschein; Gruendemann, Journal fur praktische Chemie (Leipzig 1954), 1980, vol. 322, # 2, p. 261 - 272

  摘要：

  DOI：
• 作为产物：
  描述：

  5-十三烷酮 在 lithium aluminium tetrahydride 作用下， 生成 5-十三烷醇
  参考文献：
  名称：

  Baykut; Oezeris, Istanbul Universitesi Fen Fakultesi Mecmuasi, Seri C: [Astronomi-Fizik-Kimya], 1957, vol. 22, p. 32,37

  摘要：

  DOI：

文献信息

• Fluoropolymer compositions and method of use
  申请人：Peng Sheng

  公开号：US20080202384A1

  公开（公告）日：2008-08-28

  A composition comprising monomers copolymerized in the following percentages by weight: (a) from about 20% to about 95% of a monomer, or mixture of monomers, of formula (I): R f —(CH 2 CF 2 ) q (CH 2 CH 2 ) r -Z-C(O)—C(R)═CH 2 (I) wherein q and r are each independently integers of 1 to 3; R f is a linear or branched perfluoroalkyl group having 2 to 6 carbon atoms; Z is —O—, —NR 1 — or —S—; R is hydrogen, Cl, F or CH 3 ; R 1 is hydrogen, or a C 1 to C 4 alkyl; and (b) from about 5% to about 80% of at least one of: (i) an alkyl (meth)acrylate monomer having a linear, branched or cyclic alkyl group of 6 to 18 carbons; or (ii) a monomer of formula (II): (R 2 ) 2 N—R 3 —O—C(O)—C(R)═CH 2 (II) wherein R is as defined above; each R 2 is independently a C 1 to C 4 alkyl; and R 3 is a divalent linear or branched C 1 to C 4 alkylene; and wherein the nitrogen is from about 40% to 100% salinized; or (iii) a mixture thereof; said composition providing oil repellency, water repellency, and stain resistance to substrates contacted therewith; and a method for treating substrates with such copolymer compositions; are disclosed.

  本发明涉及一种组合物，其中单体按重量百分比共聚合，其中：(a)约20％至约95％的单体或单体混合物，其化学式为(I)：Rf—(CH2CF2)q(CH2CH2)r-Z-C(O)—C(R)═CH2(I)，其中inq和r分别是1至3的整数；Rf是具有2至6个碳原子的线性或支链全氟烷基；Z是—O—，—NR1—或—S—；R是氢、氯、氟或CH3；R1是氢或C1至C4烷基；以及(b)约5％至约80％的至少一种：(i)具有6至18个碳原子的线性、支链或环状烷基的烷基(甲基)丙烯酸酯单体；或(ii)化学式(II)的单体：(R2)2N—R3—O—C(O)—C(R)═CH2(II)，其中R如上所定义；每个R2独立地是C1至C4烷基；R3是双价的线性或支链C1至C4亚烷基；其中氮的盐化程度为约40％至100％；或(iii)其混合物；所述组合物使与其接触的基材具有抗油、抗水和防污性；以及使用这种共聚物组合物处理基材的方法。
• FLUOROPOLYMER COMPOSITIONS AND METHOD OF USE
  申请人：Peng Sheng

  公开号：US20110178260A1

  公开（公告）日：2011-07-21

  A composition comprising monomers copolymerized in the following percentages by weight: (a) from about 20% to about 95% of a monomer, or mixture of monomers, of formula (I): R f —(CH 2 CF 2 ) q (CH 2 CH 2 ) r —Z—C(O)—C(R)═CH 2 (I) wherein q and r are each independently integers of 1 to 3; R f is a linear or branched perfluoroalkyl group having 2 to 6 carbon atoms; Z is —O—, —NR 1 — or —S—; R is hydrogen, Cl, F or CH 3 ; R 1 is hydrogen, or a C 1 to C 4 alkyl; and (b) from about 5% to about 80% of at least one of: (i) an alkyl (meth)acrylate monomer having a linear, branched or cyclic alkyl group of 6 to 18 carbons; or (ii) a monomer of formula (II): (R 2 ) 2 N—R 3 —O—C(O)—C(R)═CH 2 (II) wherein R is as defined above; each R 2 is independently a C 1 to C 4 alkyl; and R 3 is a divalent linear or branched C 1 to C 4 alkylene; and wherein the nitrogen is from about 40% to 100% salinized; or (iii) a mixture thereof; said composition providing oil repellency, water repellency, and stain resistance to substrates contacted therewith; and a method for treating substrates with such copolymer compositions; are disclosed.

  本发明涉及一种由以下重量百分比的单体共聚而成的组合物：(a)约20%至约95%的式(I)的单体或单体混合物：Rf—(CH2CF2)q(CH2CH2)r—Z—C(O)—C(R)═CH2，其中inq和r分别是1至3的整数；Rf是具有2至6个碳原子的线性或支链全氟烷基；Z是—O—、—NR1—或—S—；R是氢、氯、氟或甲基；R1是氢或C1至C4烷基；以及(b)约5%至约80%的至少一种：(i)具有6至18个碳原子的线性、支链或环状烷基的烷基（甲基）丙烯酸酯单体；或(ii)式(II)的单体：(R2)2N—R3—O—C(O)—C(R)═CH2，其中R如上所定义；每个R2独立地是C1至C4烷基；R3是双价线性或支链C1至C4亚基；其中氮被盐化约40%至100%；或(iii)其混合物；所述组合物为接触到其上的基材提供油、水和污渍防护性能；以及用这种共聚物组合物处理基材的方法。
• Microencapsulated aqueous polymerization catalyst
  申请人：THE GOODYEAR TIRE & RUBBER COMPANY

  公开号：EP0106779A2

  公开（公告）日：1984-04-25

  The present invention discloses an aqueous polymerization medium comprising (1) a catalyst composition which contains (a) an organometallic compound and (b) a transition metal compound wherein said catalyst composition is microencapsulated in a polyene product; and (2) water. This invention also discloses an aqueous polymerization medium comprising (1) a catalyst composition which is prepared by dissolving in an inert organic solvent containing at least one polyene (a) a transition metal compound, and (b) an organometallic compound; and (2) water. This aqueous polymerization medium is very useful in the polymerization of unsaturated hydrocarbon monomers. It is of greatest value in the polymerization of conjugated diolefin monomers into stereo-regulated polymers. This invention reveals a very useful process for producing polybutadiene composed essentially of syndiotactic 1,2-polybutadiene in an aqueous medium comprising polymerizing 1,3-butadiene in said aqueous medium in the presence of (1) a catalyst composition microencapsulated in a polyene product which contains (a) at least one cobalt compound selected from the group consisting of (i) ß-diketone complexes of cobalt, (ii) ß-keto acid ester complexes of cobalt, (iii) cobalt salts of organic carboxylic acids having 6 to 15 carbon atoms, and (iv) complexes of halogenated cobalt compounds of the formula CoXn, wherein X represents a halogen atom and n represents 2 or 3, with an organic compound selected from the group consisting of tertiary amine alcohols, tertiary phosphines, ketones and N,N-dialkylamides, and (b) at least one organoaluminum compound of the formula AIR3, wherein R represents a hydrocarbon radical of 1 to 6 carbon atoms; and (2) carbon disulfide.

  本发明公开了一种水性聚合介质，其包含(1)催化剂组合物，该催化剂组合物包含(a)有机金属化合物和(b)过渡金属化合物，其中所述催化剂组合物被微囊化在聚烯产品中；以及(2)水。本发明还公开了一种水性聚合介质，该介质包含(1)催化剂组合物，该催化剂组合物是通过将(a)过渡金属化合物和(b)有机金属化合物溶解在含有至少一种聚烯的惰性有机溶剂中制备的；和(2)水。这种水性聚合介质对不饱和烃类单体的聚合非常有用。在将共轭二烯烃单体聚合成立体调节聚合物方面，它的价值最大。本发明揭示了一种非常有用的在水介质中生产主要由对位 1，2-聚丁二烯组成的聚 丁二烯的工艺，该工艺包括在所述水介质中，在以下物质存在的情况下聚合 1，3-丁二烯：(1) 微囊化在聚烯产品中的催化剂组合物，该催化剂组合物含有 (a) 至少一种选自以下组别的钴化合物：(i) β-二酮钴络合物，(ii) β-酮酸钴酯络合物，(iii) 钴盐，(iv) β-二酮钴络合物，(v) β-酮酸钴络合物，(viii) β-酮酸钴络合物、(iii) 具有 6 至 15 个碳原子的有机羧酸的钴盐，以及 (iv) 式 CoXn（其中 X 代表卤素原子，n 代表 2 或 3）的卤代钴化合物与选自由叔胺 醇、叔膦、酮和 N,N-二烷基酰胺组成的有机化合物的络合物；以及 (b) 至少一种式 AIR3（其中 R 代表具有 1 至 6 个碳原子的烃基）的有机铝化合物；(2) 二硫化碳。
• Direct method for preparing syndiotactic 1,2-polybutadiene
  申请人：THE GOODYEAR TIRE & RUBBER COMPANY

  公开号：EP0231143A1

  公开（公告）日：1987-08-05

  Short fibers of syndiotactic 1,2-polybutadiene are utilized in making tires that have improved resistance against heat build-up and improved wear characteristics. The preparation of syndiotactic 1,2-polybutadiene in fibrous form has traditionally involved an extrusion and stretching step. However, the technique of the present invention circumvents the necessity of hot mill flexing and/or extrusion in making fibrous syndiotactic 1,2-polybutadiene. The present invention more specifically involves a process for preparing syndiotactic 1,2- polybutadiene fibers directly comprising polymerizing 1,3-butadiene monomer in the presence of (1) a catalyst composition which is comprised of (a) a cobalt compound and (b) an organoaluminum compound; (2) carbon disulfide; and (3) at least one member selected from the group consisting of liquid polymers and naphthenic oils.

  辛二烯-1,2-聚丁二烯短纤维可用于制造耐热性和耐磨性更好的轮胎。传统上，制备纤维状的辛二烯-1,2-聚丁二烯需要经过挤压和拉伸步骤。然而，本发明的技术避免了在制造纤维状辛迪加 1,2 聚丁二烯时进行热磨弯曲和/或挤压的必要性。本发明更具体地涉及一种直接制备 1,2-聚丁二烯联合纤维的工艺，该工艺包括在以下条件下聚合 1,3-丁二烯单体：(1) 催化剂组合物，该催化剂组合物由(a) 钴化合物和(b) 有机铝化合物组成；(2) 二硫化碳；(3) 至少一种选自液态聚合物和环烷油的成员。
• Syndiotactic 1,2-polybutadiene latex
  申请人：THE GOODYEAR TIRE & RUBBER COMPANY

  公开号：EP0357535A1

  公开（公告）日：1990-03-07

  This invention reveals a technique for preparing syndiotactic 1,2-polybutadiene latex. It more specifically discloses a process for synthesizing syndiotactic 1,2-polybutadiene latex by polymerizing 1,3-butadiene in an aqueous medium in the presence of (1) at least one emulsifier, (2) a catalyst emulsion composition which is prepared by a microfluidization or microemulsification process, and (3) at least one member selected from the group consisting of carbon disulfide and phenyl isothiocyanate. Such syndiotactic 1,2-polybutadiene latices can be utilized in preparing blends of syndiotactic 1,2-polybutadiene with rubbers which are prepared by emulsion polymerization.

  本发明揭示了一种制备聚对二甲苯-1,2-聚丁二烯胶乳的技术。更具体地说，它公开了一种在水介质中聚合 1，3-丁二烯，合成辛二聚 1，2-聚丁二烯胶乳的工艺，该工艺存在以下物质：(1) 至少一种乳化剂；(2) 通过微流化或微乳化工艺制备的催化剂乳液组合物；(3) 至少一种选自二硫化碳和异硫氰酸苯酯的成员。这种辛二烯-1,2-聚丁二烯乳液可用于制备辛二烯-1,2-聚丁二烯与通过乳液聚合法制备的橡胶的混合物。

表征谱图