9,10-bis-(4-bromo-phenyl)-9,10-dihydro-anthracene-9,10-diol | 55517-98-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 9,10-bis-(4-bromo-phenyl)-9,10-dihydro-anthracene-9,10-diol
• 英文别名: 9.10-Dihydroxy-9.10-bis-(4-brom-phenyl)-9.10-dihydro-anthracen；9,10-Bis-(4-brom-phenyl)-9,10-dihydro-anthracen-9,10-diol；9,10-Anthracenediol, 9,10-bis(4-bromophenyl)-9,10-dihydro-, cis-；9,10-bis(4-bromophenyl)anthracene-9,10-diol
• CAS: 55517-98-1
• 化学式: C₂₆H₁₈Br₂O₂
• 分子量: 522.236
• InChiKey: AQWVAHZMUGOYEB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  30
• 可旋转键数：
  2
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  9,10-bis-(4-bromo-phenyl)-9,10-dihydro-anthracene-9,10-diol 在 溶剂黄146 、 potassium iodide 作用下， 生成 9,10-bis(4-bromophenyl)anthracene
  参考文献：
  名称：

  Dufraisse; Morgoulis-Molho, Bulletin de la Societe Chimique de France, 1940, vol. <5> 7, p. 928

  摘要：

  DOI：
• 作为产物：
  描述：

  1,4-二溴苯 、 蒽醌 在 正丁基锂 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 3.25h， 生成 9,10-bis-(4-bromo-phenyl)-9,10-dihydro-anthracene-9,10-diol
  参考文献：
  名称：

  An Anthracene-Incorporated [8]Cycloparaphenylene Derivative as an Emitter in Photon Upconversion

  摘要：

  The anthracene-incorporated [8] cycloparaphenylene 2 has been synthesized and its optoelectronic properties studied by UV vis spectroscopy, cyclic voltammetry, and DFT calculations. NMR and computational studies indicate that the new cycloparaphenylene derivative possesses a C, point group symmetry. The new CPP 2 exhibits peculiar optoelectronic properties: (i) fluorescence emission is blue-shifted with respect to [8]cycloparaphenylene 1, and its quantum yield is higher; (ii) in the presence of an octaethylporphyrin Pd complex, as sensitizer, it undergoes a visible light upconversion. This is the first case in which a cycloparaphenylene derivative is involved as an emitter in low power light frequency conversion.

  DOI：

  10.1021/acs.joc.7b02590

文献信息

• CONJUGATED POLYMER, INSOLUBILIZED POLYMER, ORGANIC ELECTROLUMINESCENT DEVICE MATERIAL, COMPOSITION FOR ORGANIC ELECTROLUMINESCENT DEVICE, METHOD FOR PRODUCING POLYMER, ORGANIC ELECTROLUMINESCENT DEVICE, ORGANIC EL DISPLAY, AND ORGANIC EL ILLUMINATOR
  申请人：Mitsubishi Chemical Corporation

  公开号：EP2270069A1

  公开（公告）日：2011-01-05

  An object of the present invention is to provide a conjugated polymer which has a high hole transportability and is excellent in solubility and depositability. Another object of the present invention is to provide an organic electroluminescence element which is capable of low voltage driving and has a high luminous efficiency and drive stability. The conjugated polymer of the present invention is a conjugated polymer containing a specific structure as the repeating unit, where the conjugated polymer contains an insolubilizing group as a substituent, the weight average molecular weight (Mw) is 20,000 or more and the dispersity (Mw/Mn) is 2.40 or less.

  本发明的一个目的是提供一种共轭聚合物，该聚合物具有较高的空穴传输性，并具有出色的可溶性和沉积性。本发明的另一个目的是提供一种有机电致发光元件，它能够低压驱动，并具有高发光效率和驱动稳定性。本发明的共轭聚合物是一种含有特定结构作为重复单元的共轭聚合物，其中共轭聚合物含有不溶解基团作为取代基，重量平均分子量（Mw）为 20,000 或以上，分散度（Mw/Mn）为 2.40 或以下。
• POLYMER COMPOUND, RETICULATED POLYMER COMPOUND PRODUCED BY CROSSLINKING THE POLYMER COMPOUND, COMPOSITION FOR ORGANIC ELECTROLUMINESCENT ELEMENT, ORGANIC ELECTROLUMINESCENT ELEMENT, ORGANIC EL DISPLAY, AND ORGANIC EL LIGHTING
  申请人：Mitsubishi Chemical Corporation

  公开号：EP2272894A1

  公开（公告）日：2011-01-12

  An object of the invention is to provide a polymer compound having a high hole transport capacity, excellent in electrochemical stability, and suitable to film formation according to a wet film formation method. Another object of the invention is to provide an organic electroluminescence element having a high current efficiency, a low drive voltage, and a long derive lifetime. The polymer compound has a crosslinking group bonding to the arylamine moiety in the repeating unit via at least one single bond therebetween.

  本发明的一个目的是提供一种具有高空穴传输能力、优异的电化学稳定性并适合于按照湿法成膜的聚合物化合物。本发明的另一个目的是提供一种具有高电流效率、低驱动电压和长衍生寿命的有机电致发光元件。该聚合物化合物具有交联基团，通过至少一个单键与重复单元中的芳基胺分子结合。
• CONJUGATED POLYMER FOR ORGANIC ELECTROLUMINESCENCE ELEMENT
  申请人：Mitsubishi Chemical Corporation

  公开号：EP3182479A1

  公开（公告）日：2017-06-21

  An object of the present invention is to provide a conjugated polymer which has a high hole transportability and is excellent in solubility and depositability. Another object of the present invention is to provide an organic electroluminescence element which is capable of low voltage driving and has a high luminous efficiency and drive stability. The conjugated polymer of the present invention is a conjugated polymer containing a specific structure as the repeating unit, where the conjugated polymer contains an insolubilizing group as a substituent, the weight average molecular weight (Mw) is 20,000 or more and the dispersity (Mw/Mn) is 2.10 or less.

  本发明的一个目的是提供一种共轭聚合物，该聚合物具有较高的空穴传输性，并具有出色的可溶性和沉积性。本发明的另一个目的是提供一种有机电致发光元件，它能够低压驱动，并具有高发光效率和驱动稳定性。本发明的共轭聚合物是一种含有特定结构作为重复单元的共轭聚合物，其中共轭聚合物含有不溶解基团作为取代基，重量平均分子量（Mw）为 20,000 或以上，分散度（Mw/Mn）为 2.10 或以下。
• Ingold; Marshall, Journal of the Chemical Society, 1926, p. 3087
  作者：Ingold、Marshall

  DOI：——

  日期：——
• CONJUGATED POLYMER, INSOLUBILIZED POLYMER, ORGANIC ELECTROLUMINESCENCE ELEMENT MATERIAL, COMPOSITION FOR ORGANIC ELECTROLUMINESCENCE ELEMENT, POLYMER PRODUCTION PROCESS, ORGANIC ELECTROLUMINESCENCE ELEMENT, ORGANIC EL DISPLAY AND ORGANIC EL LIGHTING
  申请人：Endo Kyoko

  公开号：US20110042661A1

  公开（公告）日：2011-02-24

  An object of the present invention is to provide a conjugated polymer which has a high hole transportability and is excellent in solubility and depositability. Another object of the present invention is to provide an organic electroluminescence element which is capable of low voltage driving and has a high luminous efficiency and drive stability. The conjugated polymer of the present invention is a conjugated polymer containing a specific structure as the repeating unit, where the conjugated polymer contains an insolubilizing group as a substituent, the weight average molecular weight (Mw) is 20,000 or more and the dispersity (Mw/Mn) is 2.40 or less.