nickel(II)(salicylaldoximate)2 | 54515-04-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: nickel(II)(salicylaldoximate)2
• 英文别名: nickel bis(salicylaldoxime)；Bis[2-(hydroxyiminomethyl)phenolato]nickel(II)；2-[(E)-hydroxyiminomethyl]phenolate;nickel(2+)
• CAS: 54515-04-7
• 化学式: C₁₄H₁₂N₂NiO₄
• 分子量: 330.95
• InChiKey: MEMBSOVYBWSPRG-SCMMKMJHSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  1.13
• 重原子数：
  21
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  111
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  nickel(II)(salicylaldoximate)2 以>99的产率得到
  参考文献：
  名称：

  Bobtelsky, M.; Jungreis, E., Journal of Inorganic and Nuclear Chemistry, 1956, vol. 3, p. 38 - 48

  摘要：

  DOI：
• 作为产物：
  描述：

  在 H₂O 作用下， 以 水 为溶剂， 生成 nickel(II)(salicylaldoximate)2
  参考文献：
  名称：

  Rani, I.; Pandeya, K. B.; Singh, R. P., Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1981, vol. 11, p. 221 - 230

  摘要：

  DOI：

文献信息

• Solid State Reactions of Coordination Compounds at Low Heating Temperatures
  作者：Xin-Quan Xin、Li-Min Zheng

  DOI：10.1006/jssc.1993.1305

  日期：1993.10

  A review of solid state reactions related to the coordination compounds is presented. Eight types of reaction are listed for the multicomponent systems, and factors influencing the reactions are discussed.

  介绍了与配位化合物有关的固态反应。列出了用于多组分系统的八种反应类型，并讨论了影响反应的因素。
• Catalytic performance of a square planar nickel complex for electrochemical‐ and photochemical‐driven hydrogen evolution from water
  作者：Chun-Li Wang、Hao Yang、Juan Du、Shu-Zhong Zhan

  DOI：10.1016/j.inoche.2021.108780

  日期：2021.9

  A square planar nickel complex bearing salicylketoxime (SAO), Ni-SAO has been synthesized and well characterized by ESI-MS and single-crystal X-ray diffraction, etc. Ni-SAO exhibits good activity in both electrocatalytic and photocatalytic hydrogen evolution reaction (HER). Under an overpotential (OP) of 837.6 mV, Ni-SAO can electrocatalyze hydrogen evolution from a neutral aqueous buffer with a turnover

  合成了一种带有水杨酮肟（SAO）的方形平面镍络合物，Ni-SAO 已被合成并通过 ESI-MS 和单晶 X 射线衍射等进行了很好的表征。Ni-SAO 在电催化和光催化析氢反应 (HER) 中均表现出良好的活性。在 837.6 mV 的过电势 (OP) 下，Ni-SAO 可以电催化中性水性缓冲液析氢，周转频率 (TOF) 为每小时每摩尔催化剂 1428 摩尔氢（mol H 2 /mol 催化剂/h） . 此外，在蓝光 (λ = 469 nm) 下，包含 Ni-SAO 作为催化剂、CdS 纳米棒 (CdS NRs) 作为光敏剂和抗坏血酸 (H 2A) 作为牺牲电子供体还可以在 48 小时辐射期间提供每摩尔催化剂（催化剂的摩尔数-1 的摩尔数）的转换数（TON）为 8138 mol H 2 的氢。469 nm 处的最高表观量子产率 (AQY) 约为 16.5%。
• Formation and properties of Ziegler systems based on nickel bis(dimethylglyoximate) in catalysis of hydrogenation reactions
  作者：Yu. Yu. Titova、L. B. Belykh、F. K. Shmidt

  DOI：10.1134/s1070363214120111

  日期：2014.12

  of the product of C-alkylation as a result of addition of AlEt3 to the C=N bond, and the reduction of Ni(II) to Ni(0) complexes. The absence of nickel clusters and a low concentration of coordinatively unsaturated Ni(0) complexes is the most probable reason of low catalytic activity of the studied system in hydrogenation catalysis.

  定性地表征了镍前体中酸性配体的性质对烯烃加氢中齐格勒体系活性的影响。通过IR，NMR和ESR光谱法确定的双（二甲基乙二肟酸镍）镍与三乙基铝反应的关键步骤包括AlEt 3与二甲基乙二肟酸配体的OH基团之间的反应，C-烷基化产物的形成将AlEt 3添加到C = N键中，以及将Ni（II）还原为Ni（0）络合物的结果。缺乏镍簇和低浓度的配位不饱和Ni（0）配合物是加氢催化研究体系催化活性低的最可能原因。
• Binuclear complexes of silicon(IV) chloride with nickel(II) salicylaldoximates
  作者：N.S. Biradar、V.L. Roddabasanagoudar、T.M. Aminabhavi

  DOI：10.1016/s0277-5387(00)88095-x

  日期：1984.1

  Abstract Some binuclear complexes of silicon(IV) chloride and nickel(II) salicylaldoximates were synthesized and characterised by elemental analyses, conductivity measurements, magnetic and spectral data. The complexes were proved to be 1:1 SiCl4 adducts. The resulting complexes were amorphous in nature and electrolytes in solution.

  摘要合成了一些氯化硅（IV）和水杨醛肟酸镍（II）的双核配合物，并通过元素分析，电导率测量，磁性和光谱数据进行了表征。配合物被证明是1：1的SiCl4加合物。所得的络合物本质上是无定形的，溶液中是电解质。
• Nanocrystalline Mixed Ligand Complexes of Cu (II), Ni (II), Co (II) with N, O Donor Ligands: Synthesis, Characterization, and Antimicrobial Activity
  作者：Kolhe H、Jadhav S、Shaikh H、Takate J、Aware J

  DOI：10.13005/ojc/320620

  日期：2016.12.25

  In present investigation nanocrystalline mixed ligand complexes were synthesized using 8-hydroxyquinoline, salicylaldoxime with metals like Cu (II), Ni (II) and Co (II). The metal: ligand ratio was found to be 1:1:1. These complexes were characterized using electronic spectra, FTIR spectra, elemental analysis, magnetic susceptibility, thermogravimetric analysis, conductivity measurement, powder X-ray diffraction and Scanning Electron Microscopy with electron dispersive spectroscopic methods.  The electronic spectra of complexes suggest that they have square planer geometries. In FTIR analysis characteristic bands of ν (M-N) and  ν (M-O).The Co (II) and Cu (II) complexes are paramagnetic in nature and these had square planer geometry. While Ni (II) complexes are diamagnetic nature and having square planer geometry. The thermal analysis of complexes was studied in an attempt to assign intermediate compounds. Low molar conductance values indicate non – electrolytic nature of the complexes. The Powder X-ray diffraction study shows formation of nanocrystalline phase as well as the grain size of complexes is less than 10 nm. The EDS study is shows  good agreement for formation of mixed ligand metal complexes  . Complex: [C16H12CuN2O2], [C14H12N2NiO4 ], [C16H12NiN2O2] and [C16H12CoN2O2]   had antimicrobial activity against four bacteria tested. Bacteria were resistant to other five complexes.

  本研究使用 8-羟基喹啉、水杨醛肟与 Cu (II)、Ni (II) 和 Co (II) 等金属合成了纳米晶混合配体复合物。金属与配体的比例为 1:1:1。使用电子光谱、傅立叶变换红外光谱、元素分析、磁感应强度、热重分析、电导率测量、粉末 X 射线衍射和扫描电子显微镜以及电子色散光谱方法对这些配合物进行了表征。 复合物的电子能谱表明它们具有正方形平面几何结构。在傅立叶变换红外光谱分析中，ν（M-N）和ν（M-O）为特征谱带。钴（II）和铜（II）配合物具有顺磁性，它们的几何形状为方形平面。钴（II）和铜（II）络合物具有顺磁性，其几何形状为方形平面，而镍（II）络合物具有二磁性，其几何形状为方形平面。对配合物的热分析进行了研究，试图找出中间化合物。低摩尔电导值表明络合物具有非电解性质。粉末 X 射线衍射研究表明，络合物形成了纳米晶相，晶粒尺寸小于 10 纳米。EDS 研究表明，混合配体金属配合物的形成与 EDS 研究结果十分吻合。复合物：[C16H12CuN2O2]、[C14H12N2NiO4 ]、[C16H12NiN2O2]和[C16H12CoN2O2]对测试的四种细菌具有抗菌活性。细菌对其他五种复合物具有抗药性。