10-Acetoxy-anthron | 1705-94-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 10-Acetoxy-anthron
• 英文别名: (10-oxo-9H-anthracen-9-yl) acetate
• CAS: 1705-94-8
• 化学式: C₁₆H₁₂O₃
• 分子量: 252.269
• InChiKey: XQTNTWRDUQNCJL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  19
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  43.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  10-Acetoxy-anthron 在 potassium bromate 、 cerium(IV) oxide 作用下， 以 水 为溶剂， 生成 蒽醌
  参考文献：
  名称：

  Ceria nanoparticles as an efficient catalyst for oxidation of benzylic CH bonds

  摘要：

  Catalytic oxidation of benzylic C-H bonds with potassium bromate to carbonyl compounds was studied in the presence of ceria nanoparticles (NPs). Aldehydes and ketones in high yields were obtained when the oxidation was conducted in water/1,4-dioxane/acetic acid (AcOH) by ratio 5/1/1 (v/v/v). Benzyl esters were also yielded as the main products from the oxidation of benzylic C-H bonds with potassium bromate in the presence of ceria NPs in glacial acetic acid. In comparison with other methods reported in the literature, ceria NPs as an efficient catalyst in oxidation of benzylic C-H bonds have advantageous such as selectivity, recyclability, high reaction rate, and high yield of product because of their large specific surface area to volume ratio. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2012.01.020
• 作为产物：
  描述：

  乙酸9-蒽基酯 在 lead(IV) acetate 、 溶剂黄146 作用下， 生成 10-Acetoxy-anthron
  参考文献：
  名称：

  Rate of Oxidation of Aromatic Hydrocarbons by Lead Tetraacetate¹

  摘要：

  DOI：

  10.1021/ja01197a019

文献信息

• Anodic Oxidation of Active Methylene Groups in the Presence of Excess Carboxylic Acid
  作者：Jugo Koketsu、Masasi Kurita、Michiko Tamano、Yoshikazu Fujimura、Fumio Ando

  DOI：10.1246/bcsj.66.2767

  日期：1993.9

  anodic oxidation of anthrone, (9,(10H)-anthracenone), 9,10-dihydroanthracene and 1-tetralone in acetonitrile was studied under the presence of excess carboxylic acids. The oxidation of anthrone with acetic acid gave anthraquinone, 10-acetoxyanthrone and 10-methyl-10-acetoxyanthrone. A similar reaction of anthrone with propionic acid yielded 10-propionyloxyanthrone. The electronic oxidation of 9,10-dihydroanthracene

  在过量羧酸存在下研究了蒽酮、(9,(10H)-蒽酮)、9,10-二氢蒽和 1-四氢萘酮在乙腈中的阳极氧化。蒽酮用乙酸氧化得到蒽醌、10-乙酰氧基蒽酮和10-甲基-10-乙酰氧基蒽酮。蒽酮与丙酸的类似反应产生10-丙酰氧基蒽酮。在相同条件下，9,10-二氢蒽的电子氧化产生蒽醌、蒽酮和9-乙酰氧基蒽酮。此外，1-四氢萘酮在羰基的 4 位与乙酸和丙酸反应，分别得到 4-乙酰氧基-和 4-丙酰氧基-1-四氢萘酮。
• Oxidative Aromatization of 4,7-Dihydro-6-nitroazolo[1,5-a]pyrimidines: Synthetic Possibilities and Limitations, Mechanism of Destruction, and the Theoretical and Experimental Substantiation
  作者：Daniil N. Lyapustin、Evgeny N. Ulomsky、Ilya A. Balyakin、Alexander V. Shchepochkin、Vladimir L. Rusinov、Oleg N. Chupakhin

  DOI：10.3390/molecules26164719

  日期：——

  electron-donor substituent at position seven undergo decomposition during oxidation. The phenomenon was explained based on experimental data, electro-chemical experiment, and quantum-chemical calculation. The mechanism of oxidative degradation has been proposed.

  研究了3-氨基唑、1-吗啉代-2-硝基烯烃和醛之间多组分过程的反应耐受性。该反应的主要模式已经确定。选择4,7-二氢-6-硝基唑并[1,5-a]嘧啶的氧化条件。先前关于 4,7-二氢-6-硝基唑并[1,5-a]嘧啶不能芳构化的说法现已被驳斥。在七位具有电子给体取代基的化合物在氧化过程中会发生分解。基于实验数据、电化学实验和量子化学计算解释了这一现象。提出了氧化降解的机理。
• Polybutadiene composition
  申请人：——

  公开号：US20020032256A1

  公开（公告）日：2002-03-14

  A polybutadiene composition comprising a polybutadiene type polymer and a compound represented by the following formula (I): 1 wherein Ar 1 and Ar 2 each independently represent an aromatic ring, X and Y each independently represent an alkylene group having one or two carbon atoms, an oxygen atom or a carbonyl group, is provided; and thermal degradation of the polybutadiene type polymer can be prevented even in an air-free environment.

  一种聚丁二烯组合物，由聚丁二烯类聚合物和下式(I)所代表的化合物组成： 1 其中 Ar 1 和 Ar 2 分别独立地代表一个芳香环，X 和 Y 分别独立地代表一个或两个碳原子的亚烷基、一个氧原子或一个羰基；即使在无空气环境中，也能防止聚丁二烯型聚合物的热降解。
• Study of the Aqueous Esterification of Anthrahydroquinones
  作者：Mario Scalera、William B. Hardy、Elizabeth M. Hardy、Asa W. Joyce

  DOI：10.1021/ja01151a036

  日期：1951.7
• Regitz,M., Chemische Berichte, 1964, vol. 97, p. 2742 - 2754
  作者：Regitz,M.

  DOI：——

  日期：——